Search results for "MINERALOGY"
showing 10 items of 1516 documents
Geochemical Interactions of Plutonium with Opalinus Clay Studied by Spatially Resolved Synchrotron Radiation Techniques
2017
Plutonium plays an important role within nuclear waste materials because of its long half-life and high radiotoxicity. The aim of this study was to investigate with high spatial resolution the reactivity of the more oxidized forms of Pu(V,VI) within Opalinus Clay (OPA) rock, a heterogeneous, natural argillaceous rock considered as a potential repository host. A combination of synchrotron based X-ray microprobe and bulk techniques was used to study the spatial distribution and molecular speciation of Pu within OPA after diffusion and sorption processes. Microscopic chemical images revealed a pronounced impact of geochemical heterogeneities concerning the reactivity of the natural barrier mat…
Missions to Mars: Characterization of Mars analogue rocks for the International Space Analogue Rockstore (ISAR)
2013
International audience; Instruments for surface missions to extraterrestrial bodies should be cross-calibrated using a common suite of relevant materials. Such work is necessary to improve instrument performance and aids in the interpretation of in-situ measurements. At the CNRS campus in Orléans, the Observatoire des Sciences de l'Univers en région Centre (OSUC) has created a collection of well-characterised rocks and minerals for testing and calibrating instruments to be flown in space missions. The characteristics of the analogue materials are documented in an accompanying online database. In view of the recent and upcoming rover missions to Mars (NASA's 2011 Mars Science Laboratory (MSL…
?Short Distance?-Variabilit�t der Na-Gehalte niedrigmetamorpher mit Albit ber�hrungsparagenetisch koexistierender Hellglimmer
1973
White micas coexisting with albite, quartz, chlorite, and clinozoisite in low-grade schists of the Beaume Valley (Massif Central, France) have been analyzed by standard microprobe techniques. As the micas of an albite-rich thin section show significantly higher Na-contents than those of an albite-poor one of the same rock sample, the application of the muscovite-albite-geothermometer results in inconsistent temperature values. Thus the analyses may indicate that the distribution of sodium between coexisting white micas and albite not only depends on temperature and pressure but also on the chemical potentials of the alkalies in the metamorphic fluid phase.
On the True Indium Content of In-Filled Skutterudites
2015
The incongruently melting single-filled skutterudite InxCo4Sb12 is known as a promising bulk thermoelectric material. However, the products of current bulk syntheses contain always impurities of InSb, Sb, CoSb, or CoSb2, which prevent an unbiased determination of its thermoelectric properties. We report a new two-step synthesis of high-purity InxCo4Sb12 with nominal compositions x = 0.12, 0.15, 0.18, and 0.20 that separates the kieftite (CoSb3) formation from the topotactic filler insertion. This approach allows conducting the reactions at lower temperatures with shorter reaction times and circumventing the formation of impurity phases. The synthesis can be extended to other filled skutteru…
The “chessboard” classification scheme of mineral deposits: Mineralogy and geology from aluminum to zirconium
2010
Abstract Economic geology is a mixtum compositum of all geoscientific disciplines focused on one goal, finding new mineral depsosits and enhancing their exploitation. The keystones of this mixtum compositum are geology and mineralogy whose studies are centered around the emplacement of the ore body and the development of its minerals and rocks. In the present study, mineralogy and geology act as x - and y -coordinates of a classification chart of mineral resources called the “chessboard” (or “spreadsheet”) classification scheme. Magmatic and sedimentary lithologies together with tectonic structures (1 - D/pipes, 2 - D/veins) are plotted along the x -axis in the header of the spreadsheet dia…
Effect of the TiO2 nanoparticles on the selected physical properties of mineral trioxide aggregate
2017
Background Some of the efforts to improve the properties of Mineral Trioxide Aggregate (MTA) include incorporation of some nanoparticles such as Titanium dioxide (TiO2). The aim of this study was to evaluate the effect of TiO2 nanoparticles on the setting time, working time, push-out bond strength and compressive strength of MTA. Material and methods The physical properties to be evaluated were determined using the ISO 6786:2001 and 9917 specifications. Fifteen samples of each material (MTA or MTA with 1% weight ratio of TiO2 Nanoparticles) were prepared for any evaluated physical property. Data were analyzed using descriptive statistics and T-test. Statistical significance was set at P Res…
The effect of Mn on mineral stability in metapelites revisited: new a -x relations for manganese-bearing minerals
2014
The a-x relations recently presented in White et al. (, Journal of Metamorphic Geology, 32, 261-286) are extended to include MnO. This provides a set of internally consistent a-x relations for metapelitic rocks in the MnO-Na2O-CaO-K2O-FeO-MgO-Al2O3-SiO2-H2O-TiO2-O2 (MnNCKFMASHTO) system. The mixing parameters for the Mn-bearing minerals were estimated using the micro-ϕ{symbol} approach of Powell et al. (, Journal of Metamorphic Geology, 32, 245-260). Then the Mn-end-member thermodynamic properties were calibrated using a database of co-existing minerals involving literature data from rocks and from experiments on natural materials. Mn-end-members were calibrated for orthopyroxene, cordierit…
Atmospheric Mineral Dust - Properties and Source Markers
1989
Mineral dust particles from arid regions of the earth are a substantial fraction of the atmospheric aerosol. Due to long range transport mineral dust is found in all types of airmasses and thus in remote regions too. Physical and chemical properties allow to distinguish mineral aerosols easily from other types of aerosols. Many characteristic features are similar to those of global average crust. Only major deviations from this mean composition are reflected by the mineral aerosol composition. In order to derive source characteristic features from mineral dust samples advanced statistical methods coupled with various analytical tools from the mineralogy and chemistrymust be applied.
Mineral and trace element composition of the Lokpanta oil shales in the Lower Benue Trough, Nigeria
2011
Abstract The concentrations of minerals and trace elements in the Lokpanta oil shale from the Lower Benue Trough, Nigeria have been determined by X-ray diffraction (XRD) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS), respectively. X-ray diffraction data were evaluated using the SIROQUANT™ interactive data processing system based on Rietveld interpretation methods. A new method of trace element determination in oil shale, involving LA-ICP-MS analysis of glass beads prepared by fusing oil shale ash on an iridium strip heater was used, and the accuracy of the method was assessed by including a standard shale reference material (SGR-1b) in the analysis program. The…
Eine Subfaziesfolge der Grünschieferfazies in den Mittleren Cévennen (Dép. Ardèche) mit Pyrophyllit aufweisenden Mineralparagenesen
1969
In the middle part of the Cevennes, situated at the south-eastern border of the Massif Central, there are outcrops of micaschists, gneisses and granites in which the increase of metamorphic grade was investigated along the river Beaume. This paper presents the results of the petrographic-geochemical analysis of the micaschists of the greenschist facies. Chemical analyses of the micaschist-samples examined petrographically show their nearly constant composition, a fact which e.g., is expressed by similar CaO/Na2O- and MgO/FeO-proportions. As the average values of the determined oxides approach the respective average values of analyses of graywackes recorded by Pettijohn (1957) the original s…