Search results for "Magnetic resonance spectroscopy"

showing 2 items of 1362 documents

1H NMR Urinary Metabolomic Analysis in Older Adults after Hip Fracture Surgery May Provide Valuable Information for Patient Profiling : A Preliminary…

2022

In these times of precision and personalized medicine, profiling patients to identify their needs is crucial to providing the best and most cost-effective treatment. In this study, we used urine metabolomics to explore the characterization of older adults with hip fractures and to explore the forecasting of patient outcomes. Overnight urine specimens were collected from 33 patients (mean age 80 ± 8 years) after hip fracture surgery during their stay at a rehabilitation hospital. The specimens were analyzed with 1H NMR spectroscopy. We performed a metabolomics study regarding assessments of frailty status, Functional Independence Measure (FIM), and Short Physical Performance Battery (SPPB). …

suorituskykyEndocrinology Diabetes and MetabolismFIM-toimintakykymittarifyysinen toimintakykyfrailtyBiochemistrymetabolomicslonkkaleikkaushoitohip fracture; frailty; functioning; metabolomics; nuclear magnetic resonance spectroscopyfunctioningmurtumathip fractureaineenvaihduntatuotteetNMR-spektroskopiavirtsaMolecular Biologyikääntyneetnuclear magnetic resonance spectroscopy
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Acid–base properties of functionalised tripodal polyamines and their interaction with nucleotides and nucleic acids

2010

Novel, highly positively charged tripodal polyamines with appended heterocyclic moieties revealed an intriguing panel of protonation species within the biologically relevant range. Studied compounds bind nucleotide monophosphates by mostly electrostatic interactions but only the imidazole analogue showed selectivity toward UMP in respect to other nucleotides. Strong binding of all the studied compounds to both ds-DNA and ds-RNA is to some extent selective toward the latter, showing rather rare RNA over DNA preference.

tripodal polyamines; DNA and RNA interactions; RNA selectivity; nucleotidesMagnetic Resonance SpectroscopyStereochemistryProtonation010402 general chemistry01 natural sciencesBiochemistrychemistry.chemical_compoundNucleic AcidsPolyaminesImidazoleNucleotidePhysical and Theoretical Chemistrychemistry.chemical_classificationMolecular StructureNucleotides010405 organic chemistryOrganic ChemistryWaterRNANuclear magnetic resonance spectroscopyHydrogen-Ion Concentration0104 chemical sciencesSolutionsChemistrychemistryNucleic acidThermodynamicsProtonsSelectivityDNAOrganic & Biomolecular Chemistry
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