Search results for "Malyngolide"

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ChemInform Abstract: A Stereoselective Synthesis of (+)-Malyngolide via a Ring-Closing Olefin Metathesis.

2000

Abstract A very short and stereoselective synthesis of the non-natural enantiomer of malyngolide from l -erythrulose is described. Key features of the synthesis are the Felkin–Anh diastereoselective allylation of a polyoxygenated ketone and the allylation/metathesis/allylic oxidation protocol recently described by our group.

chemistry.chemical_classificationchemistry.chemical_compoundAllylic rearrangementKetoneChemistryStereochemistryStereoselectivityMalyngolideErythruloseGeneral MedicineEnantiomerRing (chemistry)MetathesisChemInform

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