Search results for "Mass Transfer"

Synthesis of Hyperbranched Polyglycerol in a Continuous Flow Microreactor

2007

Hyperbranched polymers have been synthesized in a microreactor for the first time, employing the known ring-opening multibranching polymerization of glycidol. Microreactors are well-known to be beneficial for highly exothermic reactions because of their capability to enhance mass and heat transfer due to short diffusion pathways and large interfacial areas per volume. The characteristics of the microstructured reaction system were utilized to engineer a continuous flow process for the preparation of well-defined hyperbranched polyglycerols with molecular weights up to 1,000 g/mol. Increased flow rates, as well as the use of highly polar solvents, led to the partial formation of very narrowl…

Expanded micro-particles by supercritical antisolvent precipitation: Interpretation of results

2008

Abstract Supercritical antisolvent (SAS) micronization has been used to obtain nanoparticles and micro-particles of several kinds of materials. Sometimes hollow expanded micro-particles have also been obtained. This work is focused on the analysis of this last morphology. We organized literature data and our previous experiments and we added new experiments on previously tested compounds and on compounds never tested before. As a result, expanded micro-particles using several compounds belonging to different categories and precipitated from different solvents in laboratory and pilot scale plants were obtained with diameters between about 10 and 180 μm. They also showed different sub-structu…

Formalisation and methods of analysis of the fast xenobiotic mass transfer in the body

2009

Ozone absorption in aqueous phenol solutions

1977

Abstract The rate of ozone absorption in aqueous solutions of phenol was measured in a wetted-wall laboratory absorber. The liquid and gas flow rates were fixed as well as the pH and temperature. The phenol concentration was varied in the range 2–300 ppm and the ozone partial pressure over an eight fold range. The gas phase resistance to mass transfer was determined by absorbing SO2 from an SO2N2 mixture in KOH aqueous solutions. The results have been interpreted by means of a simple kinetic assumption.

Influence of temperature on mass transfer in an incomplete trapping single hollow fibre supported liquid membrane extraction of triazole fungicides.

2008

The influence of temperature in a single hollow fibre supported liquid membrane extraction of triazole fungicides with a stagnant acceptor phase was investigated. The mass transfer parameters such as diffusion coefficient, flux and apparent viscosity were determined at temperature ranging from 278 K to 313 K. Increase in temperature led to an increase in diffusion coefficient and flux. The apparent viscosity also decreased with an increase in temperature. The degree of trapping in the acceptor phase influenced the mass transfer at higher temperature. At lower temperature, the transport of analytes from the donor solution through the donor-membrane interface and through the membrane mainly a…

Pressure-Induced Deformation of Pillar-Type Profiled Membranes and Its Effects on Flow and Mass Transfer

2019

In electro-membrane processes, a pressure difference may arise between solutions flowing in alternate channels. This transmembrane pressure (TMP) causes a deformation of the membranes and of the fluid compartments. This, in turn, affects pressure losses and mass transfer rates with respect to undeformed conditions and may result in uneven flow rate and mass flux distributions. These phenomena were analyzed here for round pillar-type profiled membranes by integrated mechanical and fluid dynamics simulations. The analysis involved three steps: (1) A conservatively large value of TMP was imposed, and mechanical simulations were performed to identify the geometry with the minimum pillar density…

kLa MEASUREMENT IN BIOREACTORS

2010

For accurately measuring kLa in bioreactors the dynamic pressure method (DPM) was introduced by Linek et al. (1993). In this work a simplified version of the same method is discussed. With respect to the original DPM, the simplified version greatly simplifies data treatment. In fact final constant slope observable in the usual semi-log diagram of residual driving force versus time may be simply corrected to obtain the real kLa value with negligible inaccuracy. Experimental data obtained on a lab-size stirred tank reactor confirm all model predictions, including the feature that the adoption of large pressure changes may lead to a better accuracy.

Liquid Phase Micro-Extraction of Linear Alkylbenzene Sulfonate Anionic Surfactants in Aqueous Samples

2011

Hollow fiber liquid phase micro-extraction (LPME) of linear alkylbenzene sulfonates (LAS) from aqueous samples was studied. Ion pair extraction of C10, C11, C12 and C13 homologues was facilitated with trihexylamine as ion-pairing agent, using di-n-hexylether as solvent for the supported liquid membrane (SLM). Effects of extraction time, acceptor buffer concentration, stirring speed, sample volume, NaCl and humic acids were studied. At 10–50 µg L−1 linear R2-coefficients were 0.99 for C10 and C11 and 0.96 for C12. RSD was typically ~15%. Three observations were especially made. Firstly, LPME for these analytes was unusually slow with maximum enrichment observed after 15–24 h (depending on sa…

Modeling Heterogeneous copolymerization in scCO2

2008

Gas-liquid-solid operation of a Long Draft Tube Self-ingesting Reactor (LDTSR)

2008

Gas-liquid stirred vessels are widely employed to carry out chemical reactions involving a gas reagent and a liquid phase. The usual way for introducing the gas stream into the liquid phase is through suitable distributors placed below the impeller. An interesting alternative is that of using “self ingesting” vessels where the headspace gas phase is injected and dispersed into the vessel through suitable surface vortices. In this work the performance of a Long Draft Tube Self-ingesting Reactor dealing with gas-liquid-solid systems, is investigated. Preliminary experimental results on the effectiveness of this contactor for particle suspension and gas-liquid mass transfer performance in pres…