Search results for "Mass Transfer"
showing 10 items of 171 documents
Scale-up and viscosity effects on gas–liquid mass transfer rates in unbaffled stirred tanks
2018
Abstract The interest in the process industry on unbaffled stirred tanks has greatly expanded in the last years because they may bring about significant advantages in a number of applications, including biochemical, food and pharmaceutical processes where the presence of baffles is undesirable for several reasons. Despite their application potential, unbaffled vessels still lack fundamental information, due to the fact that only recently their capabilities have started being dug out. The lack of information on scale up effects is possibly the main reason hindering practical applications. In this work the influence of vessel size and liquid viscosity on the mass transfer performance in unbaf…
Modeling of a continuous photocatalytic reactor for isovaleraldehyde oxidation: Effect of different operating parameters and chemical degradation pat…
2013
International audience; An investigation of isovaleraldehyde (ISOV) photocatalytic oxidation was conducted at initial concentrations ranging from 25 to 150 mg/m3 and different relative humidities (5-90% RH) in order to characterize the process performances close to indoor air conditions. Experiments were carried out in two different reactors: cylinder and flat-plate photoreactor (planar reactor) at different air gap (20-60 mm) and gas residence times (0.67-5.0 s). A plug flow reactor system was developed in order to perform kinetic studies of (i) isovaleraldehyde removal, (ii) selectivity of CO2, (iii) byproducts formation and removal. It appears that ISOV removal efficiencies increased wit…
Oxidation of organics in water in microfluidic electrochemical reactors: Theoretical model and experiments
2011
The electrochemical oxidation of organics in water performed in micro reactors on boron doped diamond (BDD) anode was investigated both theoretically and experimentally in order to find the influence of various operative parameters on the conversion and the current efficiency CE of the process. The electrochemical oxidation of formic acid (FA) was selected as a model case. High conversions for a single passage of the electrolytic solution inside the cell were obtained by operating with proper residence times and low distances between cathode and anode. The effect of initial concentration, flow rate and current density was investigated in detail. Theoretical predictions were in very good agr…
Electrochemical treatment of aqueous solutions containing one or many organic pollutants at boron doped diamond anodes. Theoretical modeling and expe…
2012
The electrochemical oxidation of organics in water at boron doped diamonds (BDD) was experimentally investigated with the aim to discuss the correlations among the conversion of the pollutants and the instantaneous current efficiency ICE with the operative conditions. A simple theoretical model previously developed for the oxidation of oxalic acid accounting for the cases of mass transfer control, oxidation reaction control and mixed kinetic regimes was adopted and extended to challenge its predictive capability in the case of organics of different nature and in systems with more pollutants. A quite good agreement, between theoretical predictions and experimental data pertaining to the elec…
Extraction of glyphosate by a supported liquid membrane technique.
2000
The possible application of the supported liquid membrane (SLM) technique for the extraction of glyphosate is presented. For the extraction of this compound the SLM system has been applied with utilisation of Aliquat 336 as a cationic carrier incorporated into the membrane phase. The extraction efficiency of glyphosate [N-(phosphonomethyl)glycine] is dependent on the donor phase pH, carrier concentration in the organic phase and NaCl concentration in the acceptor phase. The optimal extraction conditions are: donor phase pH>11, acceptor phase of 2 M NaCl solution and the organic phase composed of 20% (w/w) Aliquot 336 solution in di-hexyl ether. Counter-coupled transport of chloride anions f…
Influence of the boundary conditions on heat and mass transfer in spacer-filled channels
2017
The purpose of this study is to discuss some problems which arise in heat or mass transfer in complex channels, with special reference to the spacer-filled channels adopted in membrane processes. Among the issues addressed are the consistent definition of local and mean heat or mass transfer coefficients; the influence of the wall boundary conditions; the influence of one-side versus two-side heat/mass transfer. Most of the results discussed were obtained by finite volume CFD simulations concerning heat transfer in Membrane Distillation or mass transfer in Electrodialysis and Reverse Electrodialysis, but many of the conclusions apply also to different processes involving geometrically compl…
Study of the chemically activated sublimation of ZnSe
1999
Abstract The reactions and processes involved in the growth of ZnSe by chemically activated sublimation in a H 2 atmosphere are studied. The rate of transport as a function of source and substrate temperatures and the difference between them are determined from close spacing vapour transport experiments. According to this process, ZnSe layers are deposited on sapphire substrates by short distance chemically assisted sublimation. The experimental results are analysed and the thermodynamic constants of the transport are determined using a theoretical model for kinetically controlled processes, assuming water to act as sublimation catalyst. A preliminary optical and structural characterisation…
Sorption and diffusion properties of volatile phenols into cork
2010
International audience; The sorption and diffusion properties of seven common volatile phenols in hydro-alcoholic medium placed in contact with natural cork were investigated to determine the influence of cork closures on the concentration of these compounds in wine. Weighted cork samples were immersed in model wine solutions containing selected concentrations of each compound and were sampled over time. Sorption coefficients ranged between 125 and 306 mg of aroma compound per kg of cork, while diffusion coefficients varied from 0.8 to 4.1 × 10−11 m2/s. Sorption isotherms of guaiacol and 4-propylguaiacol, respectively, the lowest and highest sorbed compounds of an homologous series of guaia…
Analysis and Design of Induction Liquid Metal Processes Using Advanced Numerical Modelling
2019
Comprehensive knowledge of the turbulent flows, heat and mass transfer processes in the melt of induction applications is required to realize efficient metallurgical processes. Therefore, the process oriented development, design and optimization of induction furnaces for melting and casting of metals require praxis oriented simulation and analysis of the complex in-stationary turbulent melt flows and temperature distributions as well as the heat and mass transfer processes in the liquid metal. The studies, presented in this paper, demonstrate the possibilities of using advanced three-dimensional transient numerical modelling for successful simulation of the melt flow as well as heat and mas…
Numerical and experimental study of liquid metal stirring by rotating permanent magnets
2018
In this work, we study liquid gallium stirring by rotating permanent magnets. We demonstrate possibility of easily creating different flow patterns by rotating permanent magnets, which can be industrially important for controlling heat and mass transfer processes in the system. Unlike the typical approach of simulating magnet rotation as a transient problem and time-averaging the Lorentz forces, we solve the magnet rotation as a harmonic (frequency domain) problem, which leads to forces equal to time-averaged ones and decreases the simulation time considerably. Numerical results are validated using qualitative flow structure results from the neutron radiography visualization of tracer parti…