Search results for "Mass spectrometer"
showing 5 items of 75 documents
Multiple reaction monitoring for identification and quantification of oligosaccharides in legumes using a triple quadrupole mass spectrometer.
2022
Raffinose family oligosaccharides are non-digestible compounds considered as dietary prebiotics with health-related properties. Hence, it is important to develop highly specific methods for their determination. An analytical method is developed in this study for oligosaccharide identification and quantification using liquid chromatography-tandem mass spectrometry equipped with a triple quadrupole analyser operating in Multiple Reaction Monitoring mode. Raffinose, stachyose and verbascose are separated in a 10-minute run and the method is validated over a broad concentration range, showing good linearity, accuracy, precision and high sensitivity. A low-cost, short eco-friendly procedure for …
Towards high-accuracy mass spectrometry of highly charged short-lived ions at ISOLTRAP
2006
Dedicated to H.-J. Kluge on the occasion of his 65th birthday anniversary - Jürgen Kluge Special Issue; Multiply charged ions of stable xenon isotopes from a plasma ion source have been mass-selected by the on-line mass separator ISOLDE/CERN and delivered to the triple-trap mass spectrometer ISOLTRAP. The doubly charged ions that survived the charge-exchange processes during bunching and ion preparation were transferred to a precision Penning trap for mass determination. Mass values were obtained for the isotopes with mass numbers A=126,129,130,136. They are consistent with previous results except for the case of $^{126}Xe$ where a significant deviation from the literature value was found. …
The NEXT Project: Towards Production and Investigation of Neutron-Rich Heavy Nuclides
2022
The heaviest actinide elements are only accessible in accelerator-based experiments on a one-atom-at-a-time level. Usually, fusion–evaporation reactions are applied to reach these elements. However, access to the neutron-rich isotopes is limited. An alternative reaction mechanism to fusion–evaporation is multinucleon transfer, which features higher cross-sections. The main drawback of this technique is the wide angular distribution of the transfer products, which makes it challenging to catch and prepare them for precision measurements. To overcome this obstacle, we are building the NEXT experiment: a solenoid magnet is used to separate the different transfer products and to focus those of …
An off-line ion guide quadrupole mass spectrometer system
2017
Off-line ioniohjain kvadrupolimassaspektrometri systeemi. Uuden erillisen ioniohjain-kvadrupolimassaspektrometri (IGQMS) -systeemin käyttöönotto on esitetty tässä työssä. Laitteisto on kehitetty uusien tekniikoiden testaamiseen ja kehittämiseen IGISOL–laitoksella. Työssä on tutkittu laitteiston differentiaalista pumpaussysteemiä ja laitteiston etuosan kuljetustehokkuutta käyttäen 223Ra alfa-rekyylilähdettä. Painemittausten tulokset eri parametreilla ovat esitetty. Kaasuohjaimen käyttöpainealue on mitattu olevan 1 ja 700 mbar:n välillä pitäen käyttöpaineen QMS kammiossa, ja skimmer-systeemin läpäisytehokkuus olevan lähellä 100 %. The commissioning of a new off-line ion guide quadrupole mass …
Elemental and microbiota content in indoor and outdoor air using recuperation unit filters
2021
Detection and quantification of engineered nanomaterials in environmental systems require precise knowledge of the elemental composition, association, and ratios in homologous natural nanomaterials (NNMs). Here, we characterized soil NNMs at the single particle level using single particle-inductively coupled plasma-time of flight-mass spectrometer (SP-ICP-TOF-MS) in order to identify the elemental purity, composition, associations, and ratios within NNMs. Elements naturally present as a major constituent in NNMs such as Ti, and Fe occurred predominantly as pure/single metals, whereas elements naturally present at trace levels in NNMs occurred predominantly as impure/multi-metal NNMs such as…