Search results for "Material chemistry"
showing 10 items of 413 documents
Manufacturing and characterization of Al matrix composites with nano reinforcements via cold spraying
2019
This study aims at developing new routes for manufacturing Al matrix composites (AMCs) strengthened with nano reinforcements by solid-state cold spraying (CS) process. Three different AMCs including CNTs/Al, TiB2/AlSi10Mg and TiB2/7075Al were successfully fabricated by CS of the composite powders prepared using different approaches. The microstructure evolution of as-sprayed composite samples was investigated by means of different characterization methods like X-ray diffraction (XRD), scanning (SEM) and transmission electron microscopy (TEM) and electron backscatter diffraction (SEM/EBSD). The adhesion strength, tribological behaviour, corrosion properties as well as the mechanical performa…
Comportement en fatigue thermomécanique à haute température d’un système barrière thermique texturé par laser
2020
In service life of Thermal Barrier Coating (TBC) systems for blade applications can be limited by the top-coat (TC) spallation under thermo-mechanical fatigue (TMF) loadings. To improve its TMF life, laser texturing at the bond-coat/top coat interface in the CMSX-4 Plus / γ-γ’ BC/ EB-PVD TC system has been investigated.Thanks to the study of the laser-matter interaction, it seems that the different Ni-based single crystal superalloys have similar laser ablation behaviors and they present almost no sub-surface damage after ablation. Nevertheless, the formation of melted matter near created cavities, possibly recrystallized, is often observed.Different patterns (holes, lines, grids) have been…
Immobilization of single-stranded DNA fragments to solid surfaces and their repeatable specific hybridization : covalent binding or adsorption ?
2004
Abstract The different steps of the immobilization process of single-stranded DNA (ssDNA) on surfaces by means of chemical grafting have been investigated using systematic measurements of grafting and hybridization densities by means of radioactive labelling. The immobilization by chemical grafting to a dense monomolecular layer of N-hydroxysuccinimidyl ester reactive functions attached to silica plates was performed from a dilute solution of amino-terminated oligonucleotides (10 μmol/l). The slow evaporation of the solvent allowed to increase the DNA grafting density by a factor of 10. A precise control of the rinsing process that followed the immobilization reaction allowed the discrimina…
Experimental and theoretical studies on electropolymerization of polar amino acids on platinum electrode
2017
International audience; The anodic oxidation of polar amino acids (L-serine, L-threonine, L-asparagine, and L-glutamine) in aqueous electrolyte on smooth platinum electrode was carried out by cyclic voltammetry coupled to electrochemical quartz crystal microbalance (EQCM). pH (zwitterion, acidic and alkaline) effects on their electrochemical behavior were examined. The maximum current values are measured for zwitterion species. In addition, the current increases with increasing of concentration and scan rate, and decreases with increasing pH. The resulting passivation was studied by spectroscopic analysis such as attenuated total reflection FT infrared spectroscopy (ATR-FTIR), X-ray photoel…
Céramiques diélectriques commandables pour applications micro-ondes : composites à base de titanate de baryum-strontium et d'un oxyde non ferroélectr…
2001
Since the last decades, dielectric ceramics have been considered as attractive for microwave applications as tunable dielectric resonators or phase shifters. For that, ceramic devices should be tunable – change in dielectric constant with applied voltage- with moderate to low dielectric constant (30 to 1000) and loss tangent as low as possible. To reconcile these properties, composite ceramics based on Ba0.6Sr0.4TiO3 (BSTO) and a non-ferroelectric oxide with a low dielectric constant (MgTiO3 or MgO) were synthesised. The aim of this study was to correlate the microstructure with the dielectric properties, especially the Curie temperature and the dielectric relaxation phenomena.Ceramics with…
Doping induced stable room temperature dual emission from gadolinium doped vacancy ordered double halide perovskite, Gd:Cs2SnCl6
2022
The recent advancement in bandgap engineering through controlled doping has widen the prospectof vacancy ordered double halide perovskites (VO DHPs) by conferring them with designableoptoelectronic properties. Here, we report synthesis of Gd doped Cs2SnCl6 via a simplesolvothermal method. Gd3+ ions doping lowers the band gap from 3.8 eV to 2.8 eV and facilitatesstable room temperature dual PL emission centered at 440 nm and 610 nm. The macroscopicemission process is well supported by the confocal PL emission studies on isolated crystallites.Both the pristine (Cs2SnCl6) and Gd:Cs2SnCl6 exhibit crystalline cubic structure with Fm3m spacegroup. Rietveld refinement correlates well with the cubi…
Influence of the U3O7 domain structure on cracking during the oxidation of UO2
2010
Abstract Cracking is observed when a UO 2 single crystal is oxidised in air. Previous studies led to the hypothesis that cracking occurs once a critical depth of U 3 O 7 oxidised layer is reached. We present some μ-Laue X-ray diffraction results, which evidence that the U 3 O 7 layer, grown by topotaxy on UO 2 , is made of domains with different crystalline orientations. This observation was used to perform a modelling of oxidation coupling chemical and mechanical parameters, which showed that the domain patterning induces stress localisation. This result is discussed in comparison with stress localisation observed in thin layer deposited on a substrate and used to propose an interpretation…
Spin-crossover compounds based on iron(II) complexes of 2,6-bis(pyrazol-1-yl)pyridine (bpp) functionalized with carboxylic acid and ethyl carboxylic …
2018
International audience; Four new salts of the iron(II) complex of the 2,6-bis(pyrazol-1-yl)pyridine ligand functionalized with a carboxylic acid group (bppCOOH) of formulas [Fe(bppCOOH)2](BF4)2 (1(BF4)2), [Fe(bppCOOH)2](CF3SO3)2·yMe2CO (1(CF3SO3)2·yMe2CO), [Fe(bppCOOH)2](AsF6)2·yMe2CO (1(AsF6)2·yMe2CO) and [Fe(bppCOOH)2](SbF6)2·yMe2CO (1(SbF6)2·yMe2CO) have been prepared and characterized together with a more complete structural and photomagnetic characterization of the previously reported [Fe(bppCOOH)2](ClO4)2 (1(ClO4)2). Furthermore, the iron(II) complex of the ethyl ester derivative of bppCOOH (bppCOOEt) has been prepared and characterized (compound [Fe(bppCOOEt)2](ClO4)2·yMe2CO, 2(ClO4)…
Host–guest inclusion complexes between peracetylated β-cyclodextrin and diphenyl(4-phenylphenyl)phosphine : computational studies
2006
PM3 and molecular dynamic calculations were performed upon the inclusion complexation of peracetylated β-cyclodextrin (Per-Ac-β-CD) with diphenyl(4-phenylphenyl)phosphine (DBP). Results show that the 4-phenylphenyl part of the DBP phosphine fits tightly in the cavity of the Per-Ac-β-CD, leading to the formation of stable inclusion complexes. Complexation energies indicate that the complex formed via the primary side of the Per-Ac-β-CD is more stable than that formed via the secondary side. Electrostatic potential mapping and frontier orbital analysis suggest that van der Waals interaction constitute a major driving force in the complexation of the DBP and Per-Ac-β-CD.
MCM-41 silica monoliths with independent control of meso- and macroporosity
2007
Centimetre sized macroporous silica monoliths consisting of MCM-41 have been prepared by a two-step procedure allowing an independent control of the meso- and macro-porosity. In the first step a monolith with a macroporosity tailored between 2 and 20 μm is prepared under acidic medium by a phase separation, named spinodal decomposition, leading to a bicontinuous structure of a silica/polymer phase and a water phase. The monolith is then reacted in an alkaline solution of cetyltrimethyl ammonium to transform the silica skeleton into MCM-41 under conditions which preserve the original morphology and macroporosity of the material. The combination of spinodal decomposition and pseudomorphic tra…