Search results for "Metals"
showing 10 items of 2013 documents
Folded Cr12Co12 and Cr12Ni12 wheels: a sharp increase in nuclearity of heterometallic chromium rings
2014
Two novel record-sized heterometallic Cr12M12 (M = Co, Ni) chromium wheels with an unusual saddle-like architecture are created by reacting appropriate precursor complexes with the bridging ligand 2,2'-bipyrimidine.
Improvement of flame spraying PEEK coating characteristics using lasers
2011
Flame spraying is frequently used for PEEK coatings elaboration on metallic surfaces. However, this process has a certain number of limitations particularly considering the quality of the coatings like high porosity or low interfacial adherence. For that reason a thermal post-processing is often necessary. From all of the processes which can be used (flame, oven, etc.), laser can be an interesting technology. Then, the aim of this study is to analyse the dependence of the morphological structure (compactness) and the adherence of the flame sprayed PEEK coatings to the stainless steel (304L) and aluminium alloy (AA2017) substrates on laser parameters. Moreover, the influence of the laser bea…
Self-assembly and magnetic properties of a double-propeller octanuclear copper(II) complex with a meso-helicate-type metallacryptand core.
2004
An octanuclear copper(II) complex possessing a dimer-of-tetramers structure self-assembles from a binuclear oxamatocopper(II) metallacryptand of the meso-helicate type; its magnetic behaviour is consistent with its unique double-propeller molecular topology. Pardo Marín, Emilio José, Emilio.Pardo@uv.es ; Julve Olcina, Miguel, Miguel.Julve@uv.es ; Lloret Pastor, Francisco, Francisco.Lloret@uv.es ; Ruiz Garcia, Rafael, Rafael.Ruiz@uv.es
Large monolithic silica-based macrocellular foams with trimodal pore system.
2003
Silica-based materials with hierarchical pore systems at three different length scales (small mesopores–large mesopores–macropores) have been prepared through a nanotectonic approach by using mesoporous nanoparticles as building blocks; the resulting materials present a highly accessible foam-like architecture and can be prepared as large monoliths. Huerta Morillo, Lenin Jose, Lenin.Huerta@uv.es ; Latorre Saborit, Julio, Julio.Latorre@uv.es ; Beltran Porter, Aurelio, Aurelio.Beltran@uv.es ; Beltran Porter, Daniel, Daniel.Beltran@uv.es ; Amoros del Toro, Pedro Jose, Pedro.Amoros@uv.es
Tetrathiotetracene thin film morphology and electrical properties
2015
The electrical properties of organic thin films are determined by their chemical constituents and the morphology of the films deposited. In this paper the morphology of vacuum sublimed (7?10-6 mbar) tetrathiotetracene (TTT) thin films is shown to be strongly affected by the thermal deposition temperature (222-350 K) and rate of deposition. Mostly needle-like morphologies are identified by scanning electron microscopy. Optimal TTT purity (a pre-requisite for device preparation via subsequent oxidation) is evidenced by their initially low electrical conductivity. Altering the TTT morphology, by variation of the evaporation parameters, strongly affects this base electrical conductivity. Four p…
Tailoring the microstructure and mechanical properties of Ti–Al alloy using a novel electromagnetic stirring method
2006
The effect of melt convection during the solidification of Ti45Al55 alloys was investigated in terms of microstructure evolution and the resulting mechanical properties. The samples were subjected to conventional induction melting as well as enhanced melt stirring by an external magnetic field using a specially designed floating zone arrangement. The stirred samples showed a significant improvement of plastic deformability. A strong change in the morphology from dendritic to spherical and an increased properitectic phase fraction were observed after stirring.
Multiphysical modeling of dissimilar welding via interlayer
2011
Abstract A multiphysical finite element modeling of dissimilar welding via interlayer material was proposed. A 2D model including heat transfer, fluid flow and level set problems allowed to simulate the morphology and the composition of melted zone in horizontal plane. The calculated thickness of melted interlayer was used as a main criterion for the choice of optimal welding conditions, when the chemical interaction between the joined materials must be avoided. A 1D diffusion model at the limit of melted zone allowed estimating the length and the composition of diffusion layer between one of the materials and the interlayer basing on previously calculated local temperature gradient. The si…
Growth and size distribution of Au nanoparticles in annealed Au/TiO2 thin films
2014
Abstract Nanocomposites consisting of noble metal nanoparticles (NPs) embedded in TiO2 thin films are of great interest for applications in optoelectronics, photocatalysis and solar-cells for which the plasmonic properties of the metal NPs play a major role. This work investigates the first stages of the formation of gold NPs by thermal annealing of Au-doped TiO2 thin films grown by magnetron sputtering. A low concentration of gold in the films is considered (5 at.%) in order to study the first stages of the formation of the NPs. Raman spectroscopy is used to follow the crystallization of TiO2 when increasing the annealing temperature. In addition, low-frequency Raman scattering (LFRS) is u…
Nanomaterials and phase sensitive based signal enhancment in surface plasmon resonance
2018
Measurement of small molecules in extremely dilute concentrations of analyte play an important role in different issues ranging from food industry to biological, pharmaceutical and therapeutical applications. Surface plasmon resonance (SPR) sensors can be a suitable choice for detection of small molecules based on interactions with biomolecules. However, sensitivity of the system for detection of these molecules is very low. Improving sensitivity has been a challenge for years. Therefore, different methods have been used to enhance SPR signals. The SPR signal enhancement using numerous nanomaterials has provided exciting results. Among various nanomaterials, metal nanoparticles (for instanc…
The design of magneto-plasmonic nanostructures formed by magnetic Prussian Blue-type nanocrystals decorated with Au nanoparticles.
2021
Abstract: We have developed a general protocol for the preparation of hybrid nanostructures formed by nanoparticles (NPs) of molecule-based magnets based on Prussian Blue Analogues (PBAs) decorated with plasmonic Au NPs of different shapes. By adjusting the pH, Au NPs can be attached preferentially along the edges of the PBA or randomly on the surface. The protocol allows tuning the plasmonic properties of the hybrids in the whole visible spectrum.