Search results for "Metals"
showing 10 items of 2013 documents
Disordered sodium alkoxides from powder data: crystal structures of sodium ethoxide, propoxide, butoxide and pentoxide, and some of their solvates
2021
The crystal structures of NaOEt, NaOPr, NaOBu and NaOAm (Am = amyl = pentyl) were determined from powder data. These compounds crystallize in an anti-PbO structure in the space groups P 21 m and P4/nmm. Additionally, solvates with the composition NaOEt·2EtOH, NaOPr·2PrOH, NaOiPr·5iPrOH and NaOtAm·tAmOH were synthesized, and their structures were determined from single crystals. They form interesting chain structures of different compositions and topologies.
Design and development of a new machine tool for continuous friction stir extrusion
2023
In the present paper the Continuous Friction Stir Extrusion process (CFSE), derived from the already known Friction Stir Extrusion (FSE), is proposed for effective solid-state recycling of metal scraps. A new dedicated machine tool was designed and developed. A Lagrangian implicit thermomechanical numerical model was set up and used to determine the proper ranges of the most relevant process parameters. An effective case study is proposed, involving the actual extrusion of a recycled wire in a continuous way. Metallurgical observations and mechanical characterization tests were carried out on the obtained specimen showing the potential of the process and its industrial feasibility.(c) 2023 …
A preliminary comparison between finite element and meshless simulations of extrusion
2009
In this paper the extrusion process of a cross-shaped profile was investigated. In particular, the study was focused on the distortion of extruding profiles when the workpiece and die axis are not aligned. The process was simulated using the finite element method (FEM) and the natural element method (NEM), both implemented in an updated-Lagrangian formulation, in order to avoid the burden associated with the description of free surfaces in ALE or Eulerian formulations. Furthermore, an experimental equipment was developed in order to obtain reliable data in terms of deformed entity, required process load and calculated pressure. At the end, a comparison between the numerical predictions and …
Study of economic availability related to rare metals in the context of the energy transition
2014
A growing number of academic studies and international organizations reports have noticed an increasing dependency of new energy technologies on a specific class of natural resources often called minor metals. For several years, worries about economic availability of these metals in order to realize the energy transition have appeared. This thesis aims at underline the broader risks and constraints involved by general use of these metals in new energy technologies. A first part of this thesis is devoted to theories and indicators related to the depletion of non renewable resources. This part also shows that minor metals share many characteristics and that they can form a group of metal cons…
Dependence between renewable energy related critical metal futures and producer equity markets across varying market conditions
2022
We study the dependence of renewable energy production-related critical metal futures and producer equity returns, compared to the non-renewable energy (oil and natural gas) and some other globally relevant commodity markets. We find different asymmetric and symmetric dependencies in these commodity markets. The dependence is asymmetric in the most important critical metal markets, i.e., of silver, copper, and platinum. Still, surprisingly, for example, in the oil market, the relationship is symmetric, and no relationship is found in the natural gas market. Furthermore, the oil and agricultural markets have homogenous dependence structures in most market conditions, so the information trans…
Review of methodologies for evaluating university social responsability
2015
The article presents a review of methodologies for the assessment of the so-called University Social Responsibility from the analysis of indicator systems in the area of higher education in Ibero-America. A publication-based research was conducted, compiling progress made between the years 2006-2013. A total of two doctoral theses that presented evaluation systems in students; two models proposed by universities in Peru and Spain; and the papers of two university networks that designed a University Social Responsibility conceptual development and indicator systems for its assessment were identified. The article points out that despite the spectrum of conceptual proposals produced during the…
Influence of some relevant process parameters on the dimensional accuracy in incremental forming: a numerical and experimental investigation
2004
Abstract As known, incremental forming is a flexible and innovative sheet metal forming process which allows complex shape shells forming without the need for any die. For these reasons, incremental forming is nowadays suggested for rapid prototyping and customised products. The present paper is focused on material formability in incremental forming and, in particular, on the evaluation and compensation of elastic springback. The latter significantly modifies the imposed shape. For this purpose, a deeper assessment of the process was developed following three different approaches. First of all, a wide experimental investigation on the influence of some relevant process parameters was develo…
Influence of arbuscular mycorrhizal colonisation on cadmium induced Medicago truncatula root isoflavonoid accumulation.
2012
Cadmium is a serious environmental pollution threats to the planet. Its accumulation in plants affects many cellular functions, resulting in growth and development inhibition, whose mechanisms are not fully understood. However, some fungi forming arbuscular mycorrhizal symbiosis with the majority of plant species have the capacity to buffer the deleterious effect of this heavy metal. In the present work we investigated the capacity of Rhizophagus irregularis (syn. Glomus irregularis) to alleviate cadmium stress in Medicago truncatula. In spite of a reduction in all mycorrhizal parameters, plants colonized for 21 days by R. irregularis and treated by 2 mg kg(-1) cadmium displayed less growth…
Cadmium-induced changes in soil biochemical characteristics of oat (Avena sativa L.) rhizosphere during early growth stages
2011
A microcosm was assembled to physically separate soil from roots and was used to study both the impact of living roots on the soil–plant system during early stages of growth and plant responses to abiotic stress. Oat (Avena sativa L.) seedlings were grown in the microcosm unit for 44 days. Twenty-three days after planting, 0.154 mg CdSO4/g dry soil was added. Plants grown in Cd-treated microcosms showed considerable inhibition of shoot growth rates, and leaf chlorophyll content. Soil microbial biomass C and respiration increased with plant age, and most of the measured biochemical indicators decreased with increasing distance from the soil–root interface, thus demonstrating the rhizosphere …
Crystal structure and microstructure of synthetic hexagonal magnesium–cobalt cordierite solid solutions (Mg2−2xCo2xAl4Si5O18)
2013
Co2+-containing cordierite glasses, of nominal compositions (Mg1−xCox)2Al4Si5O18(withx= 0, 0.2, 0.4, 0.6, 0.8 and 1), were prepared by melting colloidal gel precursors. After isothermal heating at 1273 K for around 28 h, a single-phase α-cordierite (high-temperature hexagonal polymorph) was synthesized. All materials were investigated using X-ray powder diffraction and field-emission scanning electron microscopy. The crystal structure and microstructure were determined from X-ray diffraction patterns. Rietveld refinement confirmed the formation of magnesium–cobalt cordierite solid solutions. The unit-cell volume increased with the increase of cobalt content in the starting glass. The crysta…