Search results for "Metals"

Equilibrium and studies on sorption of heavy metals from solutions by algae

2013

BODIPY atropisomer interconversion, face discrimination, and superstructure appending

2016

International audience; A strategy was developed to append sterically hindered apical pickets on both faces of the BODIPY platform to prevent stacking and aggregation. Ortho-substitution of both the meso-phenyl ring and the boron-bound catechol affords the right directionality to append pickets, achieve face discrimination, featuring two inter-convertible atropisomers, and is reminiscent of the picket-fence strategy in porphyrins.

Temporal trends of heavy metals in sediment core from the gulf of Palermo (Sicily, Italy)

2009

The evaluation of long–term heavy metal concentrations in the Gulf of Palermo was carried out in this study. Measurements of Cr, Cu, Hg, Pb and Zn concentrations were performed by atomic absorption spectrophotometry (AAS) on dated fractions of a sediment core, dated by the 210Pbex method. They are found to cover a time period from 1951 to 2004. The constant sedimentation rate model was used for dating. Specific activities of 137Cs have also been measured in the sediment core sections as a check of the time scale derived by the 210Pbex method. A time-series analysis based on temporal decomposition was used in order to investigate the presence of heavy metal pollution trend. The additive comp…

Marine Invertebrates as Bioindicators of Heavy Metal Pollution

2015

The marine environment presents a range of anthropogenic contaminants. According to the World Health Organization, more than 100,000 chemicals are released into the global environment every year as a consequence of their production, use and disposal. The fate of a chemical substance depends on physical-chemical properties, in combination with the characteristics of the environment where it is released. Among the substances that accumulate in the sea, for anthropogenic activities, metals/metalloids have a leading position. Some of these have a biological role but their bioaccumulation is injurious. Chemical pollutants can cause effects on organisms, biodiversity and human health. Various eff…

Structural Motifs of Alkali Metal Superbases in Non‐coordinating Solvents

2020

Abstract Lochmann–Schlosser superbases (LSB) are a standard reagent in synthetic chemistry to achieve an exchange of a proton on an organic framework with an alkali metal cation, which in turn can be replaced by a wide range of electrophilic groups. In standard examples, the deprotonating reagent consists of an equimolar mixture of n‐butyllithium and potassium t‐butoxide. However, the nature of the reactive species could not be pinned down either for this composition or for similar mixtures with comparable high reactivity. Despite the poor solubility and the fierce reactivity, some insights into this mixture were achieved by some indirect results, comparison with chemically related systems,…

Catalytic applications of TiO2

2021

Abstract The use of TiO2 as heterogeneous catalyst and/or active support for metals or other oxides is here reported. Many reactions of industrial relevance involve, in fact, titania-based catalysts, among them, NOx abatement, Fischer–Tropsch and water–gas shift, Deacon and Claus processes, hydrodesulfurizations and hydrogenations, selective reductions and selective oxidations. This chapter aims to discuss the main applications of TiO2, in its different forms, as effective support or catalyst for thermocatalytic and photo-thermocatalytic reactions, focusing on the role of its structural and physicochemical properties on the catalytic performance (activity, selectivity, stability).

An Easy Route Towards Regioselectively Difunctionalized Cyclens and New Cryptands.

2006

Reductive amination of various aldehydes with cyclen represents a very convenient method for the synthesis of a wide range of 1,7-difunctionalized cyclens, as well as new cryptands.

Adsorption and Activation of Water on Cuboctahedral Rhodium and Platinum Nanoparticles

2017

Rh and Pt are widely used as the components in heterogeneous catalysts for multiple industrial applications. Because the metals are typically in the form of nanoparticles in real catalysts, it is important to carefully select models for the computational prediction of the catalytic properties. Here we report a first-principles study on the water activation, an important step in numerous catalytic reactions, using the finite-size Rh and Pt nanoparticle models and compare them to the extended surface models. We show that regardless of the model, adsorption and activation of water is practically identical for both metals, whereas the dissociation is energetically more favorable on Rh. The expe…

2-Methylresorcinarene: a very high packing coefficient in a mono-anion based dimeric capsule and the X-ray crystal structure of the tetra-anion

2016

Mono- and tetra-deprotonated 2-methylresorcinarene anions (1 and 2) as their trans-1,4-diammoniumcyclohexane (TDAC)2+ inclusion complexes are reported. The mono-anion forms a fully closed dimeric capsule [1·H2O·MeOH]22− with a cavity volume of 165 Å3 and (TDAC)2+ as the guest with an extremely high packing coefficient, PC = 84.2%, while the tetra-anion forms a close-packed structure with two structurally isomeric tetra-anions 2a and 2b with a 50 : 50 ratio in the crystal lattice. peerReviewed

Applications and non-idealities of submicron Al–AlOx–Nb tunnel junctions

2016

We have developed a technique to fabricate sub-micron, 0.6µm×0.6µm Al-AlOx-Nb tunnel junctions using a standard e-beam resist, angle evaporation and double oxidation of the tunneling barrier, resulting in high quality niobium, as determined by the the high measured values of the critical temperature TC ∼ 7.5 K and the gap ∆ ∼ 1.3 meV. The devices show great promise for local nanoscale thermometry in the temperature range 1 - 7.5 K. Electrical characterization of the junctions was performed at sub-Kelvin temperatures both with and without an external magnetic field, which was used to suppress superconductivity in Al and thus bring the junction into a normal-metal-insulator-superconductor (NI…