Search results for "Methylone"

showing 2 items of 2 documents

Analysis of drugs including illicit and new psychoactive substances in oral fluids by gas chromatography-drift tube ion mobility spectrometry

2021

Abstract In this study, a gas chromatograph (GC) has been coupled to a drift tube ion mobility spectrometer (IMS) in order to develop an analytical procedure for the determination of psychoactive substances in oral fluids. Working parameters, including the GC-IMS interface ones, were adjusted in order to obtain sensitive and robust signals. A volume of 500 μL of oral fluid was extracted with 250 μL chloroform and, after centrifugation, were injected into the GC-IMS system. Amphetamine, methylone, α-PVP, ketamine, lidocaine, MPHP, cocaine, THJ-2201, and 5F-ADB were employed as model compounds, providing limits of detection from 6 to 15 μg L−1 and recoveries from 70 to 115% for field oral flu…

Detection limitAnalyteChloroformChromatographyIon-mobility spectrometryMethyloneGas Chromatography-Mass SpectrometryAnalytical ChemistryAmphetaminechemistry.chemical_compoundCertified reference materialsCocainePharmaceutical PreparationschemistryLiquid–liquid extractionIon Mobility SpectrometrymedicineGas chromatographymedicine.drugTalanta
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Methylone determination in oral fluid using microextraction by packed sorbent coupled to ion mobility spectrometry

2020

Abstract A methodology based on microextraction by packed sorbent (MEPS) followed by ion mobility spectrometry (IMS) has been developed for the simple and automated determination of methylone in oral fluids. MEPS was carried out using a 100 µL eVol® XR hand-held automated analytical syringe filled with octadecyl silica sorbent. The effect of main experimental parameters of MEPS such as sample pH and ionic strength, number of aspirating/dispensing cycles, and elution solvent was studied to obtain a quantitative extraction of methylone. Oral fluid samples were spiked with methylone at different concentration levels from 50 to 400 µg L−1 and analyzed by the proposed MEPS-IMS procedure, giving …

SorbentChromatographyChemistryIon-mobility spectrometryElutionMethylone010401 analytical chemistryExtraction (chemistry)02 engineering and technology021001 nanoscience & nanotechnologyTandem mass spectrometry01 natural sciences0104 chemical sciencesAnalytical ChemistrySolventIonic strengthmedicine0210 nano-technologySpectroscopymedicine.drugMicrochemical Journal
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