Search results for "Metribuzin"
showing 6 items of 6 documents
Mid- and near-infrared determination of metribuzin in agrochemicals
2008
Abstract Two infrared-based methodologies were developed for metribuzin determination in pesticide formulations after extraction with acetonitrile. Fourier transform mid infrared (MIR) procedure was based on peak area measurements between 1692 and 1670 cm −1 corrected with a baseline fixed at 1877 cm −1 . Fourier transform near infrared (NIR) determination was made by measuring the peak area between 6498 and 6332 cm −1 corrected using a two points baseline defined between 6570 and 6212 cm −1 . Repeatability, as relative standard deviation, of 5 independent measurements at mg g −1 concentration level was 0.3% and 0.03% for MIR and NIR, respectively, and limit of detection values of 9 and 17 …
Microbial toxicity and impacts on soil enzyme activities of pesticides used in potato cultivation
2009
In the conventional cultivation of potatoes, weed control and the control of potato late blight caused by Phytophthora infestans are carried out by the application of herbicides and fungicides. We investigated the impacts of the herbicides metribuzin and linuron and the fungicide fluazinam on soil microbiota in microcosms, in mesocosms and in the field. The toxicity of each pesticide in solution was assessed using the luminescent bacteria test and in soil by a solid phase modification. In microcosm tests, the microbial activity and biomass were estimated by measuring several soil enzyme activities together with soil ATP content. In the mesocosm tests, the separate addition of each pesticide…
Indoor and outdoor determination of pesticides in air by ion mobility spectrometry.
2016
Abstract The use of ion mobility spectrometry (IMS) has been evaluated as analytical methodology to detect and evaluate the occupational exposure to pesticides. The developed IMS methodology was used, in positive and negative modes, to determine the presence of pesticides in air and to evaluate possible inhalation exposures of workers and users based on active sampling on Teflon membranes and direct thermal desorption IMS. The negative IMS mode was used to determine bensulfuron, clorpyrifos, diniconazole, diuron, flutolanil and imidacloprid, while the positive mode was employed to evaluate formetanate, metalaxyl, metamitrone, metribuzin, paclobutrazol and pirimicarb. The IMS measurements pr…
Hemostatic, inflammatory, and oxidative markers in pesticide user farmers
2016
Research Article; International audience; The aim of this work was to investigate inflammatory, oxidative, and thrombotic parameters as biomarkers in farmers exposed to pesticides. Fifty farmers using chemical pesticides and 60 unexposed control men participated in this study. The Mediterranean diet compliance, the duration of pesticide use, and personal protection for pesticides handling were recorded using self-administered questionnaires. Serum biochemical parameters, oxidant/antioxidant, inflammatory, and thrombosis markers were determined. Our findings showed oxidative stress reflected by an increase in malondialdehyde, carbonyl proteins and superoxide anion levels and a decrease in vi…
Chronic low level metribuzin exposure induces metabolic alterations in rats
2013
Abstract In this work we evaluated the in vivo effects of chronic metribuzin exposure at doses that mimic human exposure through diet. Male and female rats were fed a potato diet containing metribuzin at low doses (D1, 1.3 mg/kg or D2, 13 mg/kg) for 3 months. Plasma biochemical parameters (glucose, lipid, urea, creatinine, alanine aminotransferase (ALT), aspartate aminotransferase (AST)), as well as lipid and protein contents, markers of oxidative stress in different organs (liver, adipose tissue, muscle, intestine) were determined. Our results showed that exposure to metribuzin induced a significant reduction in body weight, food intake and adverse alterations in biochemical parameters suc…
Effects of Mancozeb and Metribuzin on in vitro proliferative responses and oxidative stress of human and rat spleen lymphocytes stimulated by mitogens
2011
Pesticides have been shown to possess marked immunotropic activity. The aim of this work was to study the in vitro effects of different concentrations (1-100 µM) of Mancozeb (fungicide) and Metribuzin (herbicide), on the proliferative responses of human and rat spleen lymphocytes stimulated by concanavalin A (ConA, mitogen), the Th1- (IL-2, INFγ) and Th2- (IL-4) cytokine secretion and on the intracellular oxidative status. The results showed that Mancozeb significantly reduced ConA lymphocyte proliferation in a dose-dependent manner in both humans and rats. It also decreased IL-2, INFγ and IL-4 secretion with a a shift away to Th1 phenotype. Metribuzin at low concentrations (1-10 µM) result…