Search results for "Microstructure"
showing 10 items of 707 documents
Control of barium ferrite decomposition during spark plasma sintering: Towards nanostructured samples with anisotropic magnetic properties
2014
Abstract The sintering of barium ferrite (BaM) nano-sized powders by spark plasma sintering was studied. At the surface of the samples, an iron-rich layer (magnetite) was formed due to the decomposition of BaM and segregation in the secondary phases. To prevent the formation of secondary phases different protection layers between the graphite mould and the sample were used. Their effect on the sample microstructure was studied by X-ray diffraction and scanning electron microscopy. The most suitable protection layer was a highly dense sintered disc of aluminium oxide. Using this dense protection layer, sintered discs of BaM with 82% of theoretical density and grains of 90 ± 50 nm were obtain…
Nanostructured Alumina from Freeze-Dried Precursors
2010
Nanocrystalline alumina has been obtained on the 100 g scale by thermal decomposition of precursors resulting from the freeze-drying of aqueous solutions of different aluminum-containing products, namely aluminum acetate and aluminum L-lactate. Samples prepared at different temperatures (from 873 to 1573 K in steps of 100 K) were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM), and surface area measurements. In the acetate case, the transformation sequence involves the formation of θ-Al 2 O 3 as an intermediate phase between γ-Al 2 O 3 and α-Al 2 O 3 , whereas this θ phase is not observed in the lactate case. TEM…
Composition-related structural, thermal and mechanical properties of Ba1−xSrxTiO3ceramics (0 ≤x≤ 0.4)
2015
The Ba1−xSrxTiO3 (BST) ceramics were prepared by conventional ceramic method. The crystalline structure and morphology were studied by X-ray diffraction and scanning electron microscopy, respectively. Experimental results show that increase of sintering temperature leads to an uncontrolled precipitating of the phase with a lower content of Ti. The dielectric constant and specific heat as a function of composition and temperature were investigated. The increasing concentration of Sr ions leads to a shift of the Curie point below room temperature. To determine the elastic constants (the Young's modulus E, the shear modulus G and the Poisson's ratio v) of BST, a method of measurement of the lo…
Photochemical synthesis of pyrene perfluoroalkyl derivatives and their embedding in a polymethylmethacrylate matrix: a spectroscopic and structural s…
2014
A photochemical, alternative and eco-compatible approach to perfluoroalkyl derivatives of pyrene is presented. The perfluoroalkyl chain is regiospecifically introduced at the 1 position of pyrene. The synthesized products have been embedded in a polymethylmethacrylate matrix by photocuring at 365 nm. Both the photochemical reactions can be considered a “green tool” for the synthetic chemist in order to obtain materials with prospective optoelectronic applications. The so-obtained composites have been the object of a study by UV and fluorescence spectroscopy in order to explore their luminescence properties. The small angle X-ray scattering and the transmission electron microscopy techniques…
Experimental investigation of Brillouin and Raman scattering in a 2SG sulfide glass microstructured chalcogenide fiber.
2008
International audience; In this work, we investigate the Brillouin and Raman scattering properties of a Ge15Sb20S65 chalcogenide glass microstructured single mode fiber around 1.55 microm. Through a fair comparison between a 2-m long chalcogenide fiber and a 7.9-km long classical single mode silica fiber, we have found a Brillouin and Raman gain coefficients 100 and 180 larger than fused silica, respectively.
Optical propagation loss measurements in electro optical host-guest waveguides
2013
Thin organic waveguiding layers are applied more and more frequently as optical components in novel optoelectronic devices. For development of such devices it is important to know the optical properties of the used waveguides. One of the most important parameters is optical propagation loss in the waveguide. In this paper we present optical propagation loss measurements in planar electro optical waveguides using travelling fiber method. Using this method attenuation coefficient α at 633 nm as a function of chromophore concentration for the first two guiding modes in the slab waveguide was determined.
Dense Mosi2 produced by reactive flash sintering: Control of Mo/Si agglomerates prepared by high-energy ball milling
2011
The objective of this work is to determine the influence of the agglomeration state of the MA mixture on the microstructure and the chemical composition of SPS end-products. In order to produce MoSi2 with a microstructure and a density perfectly controlled via reactive sintering implying an SHS reaction, the characteristics of Mo/Si mechanically activated (MA) powder mixtures were investigated. Indeed, the MA powders have been characterized in terms of their surface specific area, size, phase composition and microstructure. The high-energy milling allows the formation of agglomerates (0.8 to 800 μm) composed of nanometric crystallites of molybdenum and silicon, as a consequence of a continu…
Potential of amorphous Mo–Si–N films for nanoelectronic applications
2003
The properties of amorphous metallic molybdenum–silicon–nitrogen (Mo–Si–N) films were characterised for use in nanoelectronic applications. The films were deposited by co-sputtering of molybdenum and silicon targets in a gas mixture of argon and nitrogen. The atomic composition, microstructure and surface roughness were studied by RBS, TEM and AFM analyses, respectively. The electrical properties were investigated in the temperature range 80 mK to 300 K. No transition into a superconductive state was observed. Nanoscale wires were fabricated using electron beam lithography with their properties measured as a function of temperature.
SiC-based sandwich material for Flow Channel Inserts in DCLL blankets: Manufacturing, characterization, corrosion tests
2017
This work has been carried out within the framework of the EUROfusion Consortium and has received funding from the Euratom research and training programme 2014–2018 under grant agreement No 633053. The views and opinions expressed herein do not necessarily reflect those of the European Commission.
PLZT—Synthesis, sintering and ceramics microstructure
2006
Abstract Producing of PLZT powders by original two-stage co-precipitation method from mixed solution of inorganic salts ZrOCl 2 ·8H 2 O, TiCl 4 , La(NO 3 ) 3 ·6H 2 O, Pb(NO 3 ) 2 , was carried out. The sequence of phases formed during PLZT synthesis has been studied by X-ray and DTA analysis. Ceramic samples were prepared by two-stage hot-pressing technology. Dielectric, ferroelectric and optical properties have been measured. Ceramic microstructures were studied by SEM with energy dispersive analytical capability (EDX). The fine-grained microstructure was quite uniform with the average grain size of 5–7 μm, without internal or grain boundary porosity. The optical transmittance of ceramic p…