Search results for "Mineral"
showing 10 items of 2711 documents
Natural gas hydrate investigations by synchrotron radiation X-ray cryo-tomographic microscopy (SRXCTM)
2008
[1] We report the 3D microstructure analyses of natural gas hydrates sampled from Gulf of Mexico. The samples were characterized by synchrotron radiation X-ray cryo-tomographic microscopy (SRXCTM) using the ‘TOMCAT’ beam line at the Swiss Light Source (SLS). The SRXCTM demonstrates its applicability to unlock some microscopic features of the marine hydrates, in particular of crystallite size and grain boundary network. The gas hydrate domains are surrounded by a network of pores of typically a few micrometers, which are largely due to decomposition. Out of the SRXCTM data, the porosity, total volume of the voids, the void surface area and number of the total gas-filled voids have been calcu…
Implementation of a comprehensive ice crystal formation parameterization for cirrus and mixed-phase clouds in the EMAC model (based on MESSy 2.53)
2018
A comprehensive ice nucleation parameterization has been implemented in the global chemistry-climate model EMAC to improve the representation of ice crystal number concentrations (ICNCs). The parameterization of Barahona and Nenes (2009, hereafter BN09) allows for the treatment of ice nucleation taking into account the competition for water vapour between homogeneous and heterogeneous nucleation in cirrus clouds. Furthermore, the influence of chemically heterogeneous, polydisperse aerosols is considered by applying one of the multiple ice nucleating particle parameterizations which are included in BN09 to compute the heterogeneously formed ice crystals. BN09 has been modified in order to co…
Characterization of a Newly Developed Aircraft-Based Laser Ablation Aerosol Mass Spectrometer (ALABAMA) and First Field Deployment in Urban Pollution…
2011
We present here the development and first field deployment of a novel Aircraft-based Laser ABlation Aerosol MAss spectrometer (ALABAMA), which is capable of measuring the chemical composition and size of individual ambient aerosol particles in the size range between 150 and 900 nm. The instrument uses a continuous wave 532 nm laser to size and detect the particles, a pulsed 266 nm laser to ablate and ionize the particles, and a bipolar, Z-shaped time-of-flight mass spectrometer to detect positive and negative ions. The ALABAMA fits into a 19"-aircraft rack of 150 cm height and has a total weight of 140 kg, thus currently being one of the smallest and lightest-weight instruments of its type.…
Thermal and structural modeling of the Scillato wedge-top basin source-to-sink system. Insights into the Sicilian fold-and-thrust belt evolution (Ita…
2019
AbstractTemperature-dependent clay mineral assemblages, vitrinite reflectance, and one-dimensional (1-D) thermal and three-dimensional (3-D) geological modeling of a Neogene wedge-top basin in the Sicilian fold-and-thrust belt and its pre-orogenic substratum allowed us to: (1) define the burial history of the sedimentary succession filling the wedge-top basin and its substratum, (2) reconstruct the wedge-top basin geometry, depocenter migration, and sediment provenance through time in the framework of a source-to-sink system, and (3) shed new light into the kinematic evolution of the Apennine-Maghrebian fold-and-thrust belt.The pre-orogenic substratum of the Scillato basin shows an increase…
Impact of Coseismic Frictional Melting on Particle Size, Shape Distribution and Chemistry of Experimentally-Generated Pseudotachylite
2020
In natural friction melts, or pseudotachylites, clast textures and glass compositions can influence the frictional behavior of faults hosting pseudotachylites, and are, in turn, sensitive to the processes involved in pseudotachylite formation. Quantification of these parameters in situations where the host rock composition and formation conditions are well-constrained, such as analogue experiments, may yield calibrations that can be employed in analysis of natural pseudotachylites. In this paper, we experimentally-generated pseudotachylites in granitoid rocks (tonalite and Westerly granite) at Pconf= 40 MPa and slip rates of ∼0.1 m s−1, comparable to the conditions under which natural pseud…
In situ carbon and oxygen isotopes measurements in carbonates by fiber coupled laser diode-induced calcination: A step towards field isotopic charact…
2021
International audience; Natural stable isotopes ratios (δ13Ccarb and δ18Ocarb) of carbonates archived in the geological record are routinely used to reconstruct local and global paleo temperatures and the secular evolution of the biogeochemical carbon cycle. The state-of-the-art technique, employed since the mid 20th century, to measure these isotopic ratios starts with field sampling followed by several steps of physical and chemical laboratory preparation including: (i) microdrilling and/or sawing and crushing, (ii) CO2 release by wet acid digestion, (iii) gas equilibration, purification and transfer, before (iv) gas phase IRMS measurements. While these steps are time and resource consumi…
Mineral soil composition interfacing archaeology and chemistry
2016
Abstract In the last decade, different soil types have been analysed to evaluate the effect of human activities from an archaeological point of view. In particular, in the last few years, tremendous advances have been made in sample preparation and analytical methods used in archaeological soil analyses. However, there is still a need to set standardized protocols to achieve different archaeological goals. Therefore, in this study, the analytical methods available to study archaeological soils have been reviewed together with a critical discussion on the challenging archaeological questions, which could be answered by determining their mineral composition. Data on trace elements and rare ea…
Structural contacts in subduction complexes and their tectonic significance: the Late Palaeozoic coastal accretionary wedge of central Chile
2007
Understanding the contact between the very low-grade metagreywacke of the Eastern Series and high-pressure metamorphosed schist of the Western Series in the Late Palaeozoic accretionary wedge of central Chile is fundamental for the understanding of the evolution of ancient accretionary wedges. We show the progressive development of structures and finite strain from the least deformed rocks in the eastern part of the Eastern Series of the accretionary wedge to high-pressure schist of the Western Series at the Pacific coast. Upright chevron folds of sedimentary layering are associated with an axial-plane foliation, S1. As the F1 folds became slightly overturned to the west, S1 was folded abou…
Evidence of aerial volcanic activity during the Valanginian along the northern Tethys margin.
2009
7 pages; International audience; Stratigraphic measurement and sampling on three sections (Vergol, La Charce, and Montclus) through Valanginian deposits from the Vocontian Basin (southeastern France) reveals the occurrence of centimetre thick ochre-coloured layers, which can be correlated from one section to another. At least twelve of these are identified in sediments dated from the Pertransiens to Furcillata ammonite Zones. These horizons appear similar to previously described Oxfordian and Aptian bentonites, also from the Vocontian Basin. Clay-mineralogical and geochemical data are similar in the Valanginian ochre horizons and their enclosing marls except in one of these that shows a cla…
Environmental and climatic controls of the clay mineralogy of Albian deposits in the Paris and Vocontian basins (France)
2020
18 pages; International audience; High-resolution clay mineral analyses were performed on lower and middle Albian deposits from the Paris and Vocontian basins in order to specify the weathering conditions that prevailed at that time. The clay mineral assemblages are composed of small proportions of chlorite and vermiculitic clays associated with abundant illite, R0 type illite-smectite mixed-layers (smectite) and kaolinite. Clay minerals originated from the physical alteration and chemical weathering of rocks and soils outcropping on the Variscan massifs bordering the studied areas. In the Paris Basin, the covariation of illite and kaolinite suggests the reworking of these latter minerals f…