6533b7d1fe1ef96bd125cb54

RESEARCH PRODUCT

Natural gas hydrate investigations by synchrotron radiation X-ray cryo-tomographic microscopy (SRXCTM)

Christoph HintermüllerThore SzederFrieder EnzmannGerhard BohrmannMichael KerstenThomas HuthwelkerStephan A KlappWerner F. KuhsFederica MaroneMangir M MurshedMarco StampanoniMarco Stampanoni

subject

010504 meteorology & atmospheric sciencesbusiness.industryClathrate hydrateSynchrotron radiationMineralogy010502 geochemistry & geophysics01 natural sciencesGeophysicsNatural gasGeneral Earth and Planetary SciencesGrain boundaryCrystallitePorositybusinessHydrateGeologySwiss Light Source0105 earth and related environmental sciences

description

[1] We report the 3D microstructure analyses of natural gas hydrates sampled from Gulf of Mexico. The samples were characterized by synchrotron radiation X-ray cryo-tomographic microscopy (SRXCTM) using the ‘TOMCAT’ beam line at the Swiss Light Source (SLS). The SRXCTM demonstrates its applicability to unlock some microscopic features of the marine hydrates, in particular of crystallite size and grain boundary network. The gas hydrate domains are surrounded by a network of pores of typically a few micrometers, which are largely due to decomposition. Out of the SRXCTM data, the porosity, total volume of the voids, the void surface area and number of the total gas-filled voids have been calculated. The results reveal the capability of SRXCTM to access the 3D microstructure which is of fundamental importance to model the petrophysical properties of natural gas hydrates.

https://doi.org/10.1029/2008gl035460