Search results for "Mixing"
showing 10 items of 795 documents
Tunable Four-wave Mixing Light Source Based on Photonic Crystal Fibers with Variable Chromatic Dispersion
2019
We present a detailed experimental study of fourwave mixing tuning in photonic crystal fibers that were filled either with ethanol or with heavy water. It is demonstrated that wide tuning ranges can be achieved in both cases through the variable chromatic dispersion generated by thermo-optic effect. Tunability of the signal band from 745 nm to 919 nm, and of the idler band from 1260 nm to 1759 nm is demonstrated with a pump at 1064 nm. Numerical calculations were carried out and show good agreement with experimental measurements. We present a detailed experimental study of fourwave mixing tuning in photonic crystal fibers that were filled either with ethanol or with heavy water. It is demon…
Four-wave mixing in a ring cavity
2014
We investigate a four-wave mixing process in an N interaction scheme in Rb vapor placed inside a low-finesse ring cavity. We observe strong amplification and generation of a probe signal, circulating in the cavity, in the presence of two strong optical pump fields. We study the variations in probe field gain and dispersion as functions of experimental parameters with an eye on potential application of such a system for enhanced rotation measurements. A density-matrix calculation is performed to model the system, and the theoretical results are compared to those of the experiment.
Enhanced photorefractive properties of Bi-doped Sn2P2S6
2008
International audience; Enhanced photorefractive properties of tin hypothiodiphosphate (Sn2P2S6) crystals as a result of Bi doping are presented. These new crystals were obtained by the vapor-transport technique using stoichiometric Sn2P2S6 composition with an additional amount of Bi up to 0.5 mol. % in the initial compound. The bandgap edges of the obtained crystals are located at ~750 nm and shift toward the red wavelengths with increasing Bi concentration. Sn2P2S6:Bi crystals are found to exhibit larger two-beam coupling gain coefficients (up to 17 cm−1 at a wavelength of 854 nm) as compared to (i) pure Sn2P2S6 (2.5 cm−1 at 854 nm), (ii) Sn2P2S6 crystals modified by the growth conditions…
Real-time monitoring of graphene patterning with wide-field four-wave mixing microscopy
2016
The single atom thick two-dimensional graphene is a promising material for various applications due to its extraordinary electronic, optical, optoelectronic, and mechanical properties. The demand for developing graphene based applications has entailed a requirement for development of methods for fast imaging techniques for graphene. Here, we demonstrate imaging of graphene with femtosecond wide-field four-wave mixing microscopy. The method provides a sensitive, non-destructive approach for rapid large area characterization of graphene. We show that the method is suitable for online following of a laser patterning process of microscale structures on single-layer graphene. peerReviewed
Frequency tunable polarization and intermodal modulation instability in high birefringence holey fiber
2009
International audience; We present an experimental analysis of polarization and intermodal noise-seeded parametric amplification, in which dispersion is phase matched by group velocity mismatch between either polarization or spatial modes in birefringent holey fiber with elliptical core composed of a triple defect. By injecting quasi-CW intense linearly polarized pump pulses either parallel or at 45 degrees with respect to the fiber polarization axes, we observed the simultaneous generation of polarization or intermodal modulation instability sidebands. Furthermore, by shifting the pump wavelength from 532 to 625 nm, we observed a shift of polarization sidebands from 3 to 8 THz, whereas int…
Formulation, Characterization and Optimization of the Processing Conditions of Blends of Recycled Polyethylene and Ground Tyre Rubbers: Mechanical an…
2005
Abstract Recycling represents a valid alternative to the disposal of post-consumer plastics in common landfills if it is possible to obtain new materials with good final properties compatible with practical application and, above all, by using cheap methods. In this work the possibility to produce secondary materials by blending recycled polyethylene (RPE) coming from greenhouses and post-consumer ground tyre rubber (GTR) has been studied. In particular, the preparation of these blends has been carried out in a common industrial twin screw extruder. RPE pellets and GTR powder were fed to the extruder without any other additive. Temperature, processing speed, mixing procedure and composition…
Thermodynamics of Phase Behavior in PEO/P(EO-b-DMS) Homopolymer and Block Co-Oligomer Mixtures under Pressure
2003
The cloud-point temperatures (T-cl's) of poly(ethylene oxide) (PEO) and poly(ethylene oxide)-block-polydimethylsiloxane (P(EO-b-DMS)) homopolymer and block-oligomer mixtures were determined by turbidity measurements over a range of temperatures (105 to 130degrees), pressures (1 to 800 bar), and compositions (10-40 wt.-% PEO). The system phase separates upon cooling and T-cl was found to decrease with an increase in pressure for a constant composition. In the absence of special effects, this finding indicates negative excess volumes. Special attention was paid to the demixing temperatures as a function of the pressure for the different polymer mixtures and the plots in the T-phi plane (where…
Effect of processing temperature and mixing time on the properties of PP/GnP nanocomposites
2020
Abstract During processing of molten polymers the thermal and mechanical stress acting on the melt in presence of oxygen can induce degradation with a modification of the chemical structure of the polymers. This picture can become even more relevant if the melt is a multiphasic polymer system. In this last case, the effects of the degradation depend also on the presence of a second phase and on the interactions between the two phases. In this work, the effect of the processing conditions, temperature and time, have been considered in order to investigate the thermo-mechanical and thermo-oxidative degradation of nanocomposites made by polypropylene and different contents of graphene nanoplat…
Recycling of degraded polyethylene: Blends with nylon 6
1992
Abstract Recycled polyethylene can be used for blending with nylon to obtain blends with mechanical properties better than those of blends with virgin polyethylene. Moreover, the mechanical properties of these blends are very close to and, in some cases, better than those of the pure nylon and those of blends made with functionalized polyolefines. The carbonyl groups of the photo-oxidized polyethylene react with amino end-groups of nylon 6, giving rise to graft copolymers which act as interfacial agents between the two incompatible phases. Large degrees of photo-oxidation of the polyethylene and intense mixing improve the properties of the blends.
Exploiting Reaction-Diffusion Conditions to Trigger Pathway Complexity in the Growth of a MOF.
2021
Coordination polymers (CPs), including metal–organic frameworks (MOFs), are crystalline materials with promising applications in electronics, magnetism, catalysis, and gas storage/separation. However, the mechanisms and pathways underlying their formation remain largely undisclosed. Herein, we demonstrate that diffusion-controlled mixing of reagents at the very early stages of the crystallization process (i.e., within ≈40 ms), achieved by using continuous-flow microfluidic devices, can be used to enable novel crystallization pathways of a prototypical spin-crossover MOF towards its thermodynamic product. In particular, two distinct and unprecedented nucleation-growth pathways were experimen…