Search results for "NAD"
showing 10 items of 2033 documents
Recio Morales, Oscar: Alejandro O'Reilly, inspector general. Poder militar, familia y territorio en el reinado de Carlos III
2021
On the influence of the acid-base character of catalysts on the oxidative dehydrogenation of alkanes
1996
Vanadium oxides supported on metal oxide, i.e. Al2O3, MgO and Mg-Al mixed oxide, and V-containing microporous materials (VAPO-5 and MgVAPO-5) have been tested in the oxidative dehydrogenation of C2-C4 alkanes. In all cases, tetrahedral vanadium species (isolated and/or associated) were mainly observed from51V-NMR and diffuse reflectance spectroscopies. The reducibility of V5+-species, determined from the onset-reduction temperature, decreases as follows: VOx/AL > VAPO-5 > MgVAPO-5 =VOx/MG > VOx/MG + AL. The acid character of catalysts, determined from the FTIR spectra of pyridine adsorbed, decreases as: MgVAPO-5 > VOx/AL > VAPO-5 > VOx/MG + AL > VOx/MG. A similar trend between V-reducibilit…
Alkylation at the active site of the D-3-hydroxybutyrate dehydrogenase (BDH), a membrane phospholipid-dependent enzyme, by 3-chloroacetyl pyridine ad…
1997
The structure of the rat liver's D-3-hydroxybutyrate dehydrogenase (BDH) active site has been investigated using an affinity alkylating reagent, the 3-chloroacetyl pyridine adenine dinucleotide (3-CAPAD). This NAD+ analogue reagent strongly inactivates the enzyme following a concentration- and time-dependent process with a stoichiometry of approximately 1. The reagent reacts at the coenzyme binding site as revealed by the efficient protection by NADH. The effect of 3-CAPAD is stronger with the enzyme into its natural membrane environment than with the lipid-free purified apoBDH or with the reconstituted apoBDH-mitochondrial phospholipid complex. The pH-dependent effect on the inactivation p…
The hydrothermal system of the Domuyo volcanic complex (Argentina): A conceptual model based on new geochemical and isotopic evidences
2016
The Domuyo volcanic complex (Neuquén Province, Argentina) hosts one of the most promising geothermal systems of Patagonia, giving rise to thermal manifestations discharging hot and Cl−-rich fluids. This study reports a complete geochemical dataset of gas and water samples collected in three years (2013, 2014 and 2015) from the main fluid discharges of this area. The chemical and isotopic composition (δD-H2O and δ18O-H2O) of waters indicates that rainwater and snow melting are the primary recharge of a hydrothermal reservoir located at relative shallow depth (400–600 m) possibly connected to a second deeper (2–3 km) reservoir. Reactive magmatic gases are completely scrubbed by the hydrotherm…
The Effect of Electronic Properties of Anodized and Hard Anodized Ti and Ti6Al4V on Their Reactivity in Simulated Body Fluid
2022
The electronic properties of barrier and porous layers on Ti and Ti6Al4V were studied. Barrier anodic oxides grown to 40 V on Ti and on Ti6Al4V are both n-type semiconductors with a band gap of 3.3 eV and 3.4 eV respectively, in agreement with the formation of amorphous TiO2. Anodizing to 200 V at 20 mA cm−2 in calcium acetate and β-glycerol phosphate disodium pentahydrate leads to the formation of Ca and P containing porous films with a photoelectrochemical behaviour dependent on the metallic substrate. A band gap of 3.2 eV and the flat band potential of −0.5 V vs Ag/AgCl were measured for the porous oxide on Ti, while optical transitions at 2.15 eV and a significantly more positive flat b…
Jóvenes migrantes al habla: trayectorias educativas y vidas con género
2018
El artículo muestra la tensión biográfica y el proceso educativo de dos jóvenes menores que viajaron de África a Europa a través de construcciones biográficas marcadas por el paso de sociedad de origen a sociedad de destino. El relato y la representación gráfica de la trayectoria vivida aportan elementos de reflexión sobre el encauzamiento del alumnado de incorporación tardía en nuestra sociedad. Ambas biografías se extraen de una investigación que tiene por objeto conocer qué hace posible la progresión educativa exitosa del alumnado de incorporación tardía que vive en contextos vulnerables. A través de trayectorias encauzadas por el género y una clase social de origen media, Badra y Dakar …
Comunità resilienti e auto sostenibili. Le politiche urbane dell’agroalimentare in Andalusia
2014
Negli ultimi anni si sono moltiplicati i dibattiti riguardanti la sovranità alimentare. Il sistema agroalimentare, complessa struttura di relazioni ecologiche, sociali ed economiche, ricopre, infatti, un ruolo importante sia per quanto riguarda la forma del territorio, sia per il sostentamento della popolazione. In Andalusia, la maggiore area agricola produttiva spagnola ed europea, si stanno plasmando differenti realtà per lo sviluppo di un sistema agroalimentare alternativo a quello industriale. Questo nuovo sistema, che in questa Comunidad conta già 43 esperienze supportate da produttori, cittadini, amministrazioni e entità scientifiche, oltre ad essere rispettoso dell’ambiente, è capace…
Templated growth of smart coatings: Hybrid chemical vapour deposition of vanadyl acetylacetonate with tetraoctyl ammonium bromide
2009
Hybrid aerosol assisted and atmospheric pressure chemical vapour deposition methodology has been utilised to produce thin films of vanadium dioxide from vanadyl acetylacetonate. Tetraoctyl ammonium bromide (TOAB) was used in the aerosol precursor solution. The films were analysed by X-ray diffraction, scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy. Their optical and thermochromic behaviour was also determined. It was found that the use of TOAB had a templating effect that led to a halving in the particle size and that this consequently led to a significant decrease in the thermochromic transition temperature of the films to 34 8C.
Templated growth of smart nanocomposite thin films: Hybrid aerosol assisted and atmospheric pressure chemical vapour deposition of vanadyl acetylacet…
2009
Hybrid aerosol assisted and atmospheric pressure chemical vapour deposition methodology has been utilised to produce nanocomposite thin films of gold nanoparticles and vanadium dioxide from vanadyl acetylacetonate and auric acid. The addition of tetraoctyl ammonium bromide (TOAB) to the precursor Solution gave control of the size and distribution of gold nanoparticles in the vanadium oxide matrix. These reactions led to vanadium dioxide films with reduced crystallite sizes and enhanced thermochromic properties. The films were analysed by X-ray diffraction, scanning electron microscopy and X-ray photoelectron spectroscopy. Their optical and thermochromic behaviour was also determined, This h…
Lo bueno, si breve, dos veces bueno a veces
2007
Los bebedores pueden distribuirse dentro de un continuum, de acuerdo con su nivel de riesgo y problemas. Las intervenciones deberían distribuirse y administrarse también sin solución de continuidad, incluyendo desde la prevención hasta la rehabilitación.La intervención breve es una de las mejores estrategias para reducir la carga morbosa del alcohol; por otra parte, los pacientes dependientes deberían ser tratados con intervenciones amplias y personalizadas con años de seguimiento. Breve y extenso al mismo tiempo, ¿es una contradicción?Se presenta una reflexión en torno a la ampliación de la base del tratamiento y la necesidad de identificar las dimensiones psíquica , física y social dentro…