Search results for "NANOCOMPOSITE"
showing 10 items of 641 documents
Morphology, mechanical properties and thermal degradation kinetics of PMMA-zirconia nanocomposites prepared by melt compounding
2012
Zirconia nanoparticles were synthesized by means of a sol-gel method and embedded in poly(methyl methacrylate) (PMMA) by melt compounding. The zirconia was well dispersed in the PMMA matrix, with only a few clusters, especially for the highest investigated zirconia content. NMR results showed heteronuclear dipolar interactions involving the carbons and the surrounding hydrogen nuclei. The effect of the amount of zirconia, in the range of 1–5!wt%, on the thermomechanical properties and thermal degradation kinetics of PMMA was also investigated by means of dynamic mechanical analysis (DMA), thermogravimetric analyses (TGA), and Fourier-transform infrared spectroscopy (FTIR). The presenc…
Morphology and properties of polyamide/CNTs nanocomposite fibres
2010
RADIATION-CLEAVABLE MICROPARTICLE CHAPERONES FOR DURABILITY-CONTROLLED NANOCOMPOSITE BIOPLASTICS
2012
Polysaccharide micro/nanoparticles, incorporating stabilizers (natural antioxidants), prodegrading agents (such as enzymes or metal oxide nanoparticles) or other active ingredients, can be considered ideal chaperones to introduce various and heterogeneous substances into polysaccharide films in virtue of their structural affinity. The possibility of obtaining biodegradable and colloidally stable nanoparticles from xyloglucan has been here investigated. Xyloglucans are a major class of structural polysaccharides found in the primary cell walls of higher plants. They are particularly interesting raw materials for their excellent film forming properties, thermal stability and hydroxyl rich, hi…
CHARACTERIZATION AND PROCESSABILITY NOF POLYESTER BASED NANOCOMPOSITES
2008
PREPARATION AND CHARACTERIZATION OF CLAY NANOCOMPOSITES BASED ON COMPATIBILIZED POLYAMMIDE6/POLYETHYLENE BLENDS
2008
Synergistic effects of multiwalled carbon nanotubes and Al on the electrochemical hydrogen storage properties of Mg2Ni-type alloy prepared by mechani…
2012
Abstract Mg 2− x Al x Ni ( x = 0, 0.25) electrode alloys with and without multiwalled carbon nanotubes (MWCNTs) have been prepared by mechanical alloying (MA) under argon atmosphere at room temperature using a planetary high-energy ball mill. The microstructures of synthesized alloys are characterized by XRD, SEM and TEM. XRD analysis results indicate that Al substitution results in the formation of AlNi-type solid solution that can interstitially dissolve hydrogen atoms. In contrast, the addition of MWCNTs hardly affects the XRD patterns. SEM observations show that after co-milling with 5 wt. % MWCNTs, the particle sizes of both Mg 2 Ni and Mg 1.75 Al 0.25 Ni milled alloys are decreased e…
Photo-oxidation behaviour of polyethylene/polyamide 6 blends filled with organomodified clay: Improvement of the photo-resistance through morphology …
2010
Abstract The impact of small amounts of organomodified clay (OMMT) on the photo-degradation behaviour of two blends obtained by mixing either low-density polyethylene (LDPE) or high density polyethylene (HDPE) with polyamide 6 (PA6) (LDPE/PA6 and HDPE/PA6 75/25 wt-%) was studied. The complex photo-degradation behaviour was followed by monitoring the main physical–mechanical properties of the blends. In particular, mechanical and spectroscopic tests were performed in conditions of accelerated artificial aging. An accurate mechanical and morphological characterization was previously carried out. The presence of the OMMT promotes the unexpected formation of a co-continuous morphology for the H…
An Extended Physico-Chemical Study of Nanocomposites Based on Block Copolymers and Inorganic Nanoparticles
2009
Nanocomposites based on clay nanoparticles and block copolymer
2008
Palladium–Polypyrrole Nanocomposites Pd@PPy for Direct C–H Functionalization of Pyrroles and Imidazoles with Bromoarenes
2016
International audience; Palladium–polypyrrole nanocomposites (Pd@PPy) with unique combination of high palladium dispersion (nanoparticle size 2.4 nm) and high palladium content (35 wt%) are efficient catalysts for the selective arylation of substituted pyrroles and imidazoles with either activated or deactivated aryl bromides. The performances of the recoverable supported palladium catalyst matches the best performances of homogeneous systems based on Pd(OAc)2 at 0.5–0.2 mol%, and largely overwhelm the classical Pd/C catalyst.