Search results for "NICKEL"
showing 10 items of 1087 documents
Alkali-Activated Adsorbents from Slags: Column Adsorption and Regeneration Study for Nickel(II) Removal
2021
Alkali-activated adsorbents were synthesized by mixing three different slags from the steel industry: blast furnace slag (BFS), ladle slag (LS), and Lintz–Donawitz converter slag (LD). These powdered slag-based geopolymers (GP) were used to remove nickel(II) from aqueous solutions in fixed-bed column studies. The experiments were conducted in pH 6 using a phosphate buffer with initial nickel(II) concentration of 50 mg/L. Samples were taken at time intervals of between 5 and 90 min. Three adsorption–desorption cycles were implemented with a flow rate of 5 mL/min. The geopolymers were characterized by Fourier-Transform Infrared Spectroscopy (FTIR), X-ray powder diffraction (XRD), Field Emissi…
Fine plastic foil as backing for sputtered nickel targets
2013
Targets of 58Ni and 60Ni with areal density between 71 and 105 μg/cm2 backed with polyimide foil of 35–40 μg/cm2 were prepared by sputtering with Ar ions produced by a home made sputtering device at the Target Laboratory, University of Jyväskylä. The efficiency of the procedure was about 20 %.
AC impedance behavior of the Ti4Ni2Oy and Ti3.5Zr0.5Ni2Oy type metal hydride electrodes
1999
The hydrogen storage alloy electrodes of the type Ti4Ni2Oy (y=0, 0.3 and 0.6) and Ti3.5Zr0.5Ni2Oy (y=0.15 and 0.3) were investigated by impedance spectroscopy for potential application as negative electrode in alkaline secondary nickel-metal hydride (MH) batteries. The phase Ti4Ni2O0.30 was found to be electrochemically more stable during the cycling. The addition of copper or nickel powder as current collector improved the electrochemical behavior of the electrodes. It was possible in this way to decrease the charge transfer resistance. These additions have a negligible influence on the stability of electrode material during cycling.
Direct imaging of delayed magneto-dynamic modes induced by surface acoustic waves.
2017
The magnetoelastic effect—the change of magnetic properties caused by the elastic deformation of a magnetic material—has been proposed as an alternative approach to magnetic fields for the low-power control of magnetization states of nanoelements since it avoids charge currents, which entail ohmic losses. Here, we have studied the effect of dynamic strain accompanying a surface acoustic wave on magnetic nanostructures in thermal equilibrium. We have developed an experimental technique based on stroboscopic X-ray microscopy that provides a pathway to the quantitative study of strain waves and magnetization at the nanoscale. We have simultaneously imaged the evolution of both strain and magne…
Structural and Magnetic Properties of Nickel Oxide Nanopowders
2010
Structure and magnetic properties of nickel oxide (NiO) nanopowders have been studied by X-ray/neutron diffraction, SQUID magnetometer, and micro-Raman spectroscopy. Our diffraction data indicate that at room temperature all NiO powders are antiferromagnetically ordered and have a rhombohedral (R-3m) phase. The SQUID magnetometry and Raman spectroscopy measurements support the presence of the antiferromagnetic ordering.
High temperature alloy chloridation at 850°C
2007
The resistance of eight alloys against chloridation was tested at 850 °C in Ar/Cl 2 (2.5% Cl 2 ) for 15 min. Pre-oxidation treatments were performed for 1 h and 8 h at 850°C in order to produce a thin, adherent and protective oxide scale able to improve the chloridation behaviour of the tested materials. The chloridised sample morphologies were compared to the morphologies observed on the non pre-oxidised samples. The alloys containing a large amount of iron did not exhibit any chloridation resistance, even after pre-oxidation, and were severely damaged. The nickel based alloys gave interesting results but were also attacked by chloride, probably by the "active oxidation" mechanism. The dur…
Elaboration of Nickel Aluminide Diffusion Coatings: Application to Oxidation Resistance
2008
Aluminide diffusion coatings are widely used in aeronautic domain. Nickel based superalloys present good mechanical properties and creep resistance at high temperature but their corrosion resistance is somewhat poor. In order to enhance their lifetime at high temperature, aluminide coatings can be applied on alloy surface. Aluminium present on material surface can form, at high temperature, alumina scale which is a protective oxide scale. In the present study, nickel aluminide coatings were carried out by aluminisation in a single step pack cementation process on nickel based superalloys 600 and AM1. Ni-Al intermetallic was obtained in each case. Oxidation tests were carried out at 900°C in…
Ni-Based Catalysts for Low Temperature Methane Steam Reforming: Recent Results on Ni-Au and Comparison with Other Bi-Metallic Systems
2013
Steam reforming of light hydrocarbons provides a promising method for hydrogen production. Ni-based catalysts are so far the best and the most commonly used catalysts for steam reforming because of their acceptably high activity and significantly lower cost in comparison with alternative precious metal-based catalysts. However, nickel catalysts are susceptible to deactivation from the deposition of carbon, even when operating at steam-to-carbon ratios predicted to be thermodynamically outside of the carbon-forming regime. Reactivity and deactivation by carbon formation can be tuned by modifying Ni surfaces with a second metal, such as Au through alloy formation. In the present review, we su…
Precursor-based synthetic pathways to nanometer NdNiO3−x particles
1993
Abstract The oxygen deficient neodymium nickel perovskite, NdNiO3−x, has been obtained by different low temperature-low oxygen pressure synthetic procedures. Besides a solid-matrix based route, both ordered and disordered chemical-precursors have been used as starting products. X-ray powder diffraction shows that the structure of this defective perovskite is orthorhombic. The study of the grain morphology of the products as resulting from the different synthetic procedures indicates that the main parameter determining the average particle size, which is in the nanometer range, is the maximum temperature achieved in the synthesis. Resistivity and DSC measurements show the existence of a meta…
Ni61Mössbauer study of the hyperfine magnetic field near the Ni surface
1987
$^{61}\mathrm{Ni}$ M\"ossbauer measurements have been performed at 4.2 K on spherical Ni particles covered with a protective layer of SiO, with average diameter of 500 and 50 \AA{}. The hyperfine magnetic field at $^{61}\mathrm{Ni}$ nuclei for 500-\AA{} particles has been found to be 78.3(4) kOe, compared with the field for Ni foil of 75.0(2) kOe. The small difference is due to the demagnetization and dipolar fields in 500-\AA{} particles. The spectrum of 50-\AA{} particles has a surface component with the corresponding value of the hyperfine magnetic field of 40.3(5.4) kOe. This strongly indicates that, in accordance with recent theoretical studies, there is a decrease of the hyperfine mag…