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CCDC 1850333: Experimental Crystal Structure Determination
2018
Related Article: A. Piontek, E. Bisz, B. Dziuk, R. Szostak, M. Szostak|2018|Acta Crystallogr.,Sect.C:Cryst.Struct.Chem.|74|1395|doi:10.1107/S2053229618013463
CCDC 1850335: Experimental Crystal Structure Determination
2018
Related Article: A. Piontek, E. Bisz, B. Dziuk, R. Szostak, M. Szostak|2018|Acta Crystallogr.,Sect.C:Cryst.Struct.Chem.|74|1395|doi:10.1107/S2053229618013463
CCDC 1439890: Experimental Crystal Structure Determination
2016
Related Article: Emilio Escrivà, José-Vicente Folgado, Guillermo Mínguez Espallargas, Lucia Soto, Amparo Sancho, Lourdes Perelló, Rosa Ortíz|2016|Polyhedron|112|137|doi:10.1016/j.poly.2016.03.041
Derivation of a Homogenized Two-Temperature Model from the Heat Equation
2014
This work studies the heat equation in a two-phase material with spherical inclusions. Under some appropriate scaling on the size, volume fraction and heat capacity of the inclusions, we derive a coupled system of partial differential equations governing the evolution of the temperature of each phase at a macroscopic level of description. The coupling terms describing the exchange of heat between the phases are obtained by using homogenization techniques originating from [D. Cioranescu, F. Murat: Coll\`ege de France Seminar vol. 2. (Paris 1979-1980) Res. Notes in Math. vol. 60, pp. 98-138. Pitman, Boston, London, 1982.]
Enantioselective synthesis of 4H-pyranonaphthoquinones via sequential squaramide and silver catalysis
2015
Chemical communications 52(8), 1669-1672(2016). doi:10.1039/C5CC09592A
One-Pot Synthesis to Quinone-Based Diaza[3.3]cyclophanes
2017
A simple one-pot synthesis to [3.3]cyclophanes that involves quinone moieties was found. The protocol tolerates a variety of amines that include aliphatic and aromatic structures with different functional groups, such as hydroxy groups, amides, and terminal double and triple bonds. The straightforward synthesis can be performed by a twofold N-alkylation reaction with 2,5-bis(bromomethyl)-3,6-dimethyl-1,4-benzoquinone (1). Neither anhydrous nor inert conditions are required. Various amines can be employed without any activating groups, several functionalities at end groups are tolerated, and the cyclophanes generated can be easily modified or embedded into larger molecular architectures. The…
Light Induced C-C Coupling of 2-Chlorobenzazoles with Carbamates, Alcohols, and Ethers.
2016
A light induced, transition-metal-free C-C coupling reaction of 2-chlorobenzazoles with aliphatic carbamates, alcohols, and ethers is presented. Inexpensive reagents, namely sodium acetate, benzophenone, water, and acetonitrile, are employed in a simple reaction protocol using a cheap and widely available 25 W energy saving UV-A lamp at ambient temperature.
The Water to Water Cycles in Microalgae.
2016
In oxygenic photosynthesis, light produces ATP plus NADPH via linear electron transfer, i.e. the in-series activity of the two photosystems: PSI and PSII. This process, however, is thought not to be sufficient to provide enough ATP per NADPH for carbon assimilation in the Calvin-Benson-Bassham cycle. Thus, it is assumed that additional ATP can be generated by alternative electron pathways. These circuits produce an electrochemical proton gradient without NADPH synthesis, and, although they often represent a small proportion of the linear electron flow, they could have a huge importance in optimizing CO2 assimilation. In Viridiplantae, there is a consensus that alternative electron flow comp…
Prevention of Fusarium head blight infection and mycotoxins in wheat with cut-and-carry biofumigation and botanicals
2020
Fusarium head blight (FHB) is a devastating fungal disease of wheat worldwide causing yield losses and grain contamination with mycotoxins that jeopardise food and feed safety. Field experiments using mulch layers or botanicals were conducted in two consecutive years to investigate prevention measures with the potential to suppress FHB and reduce mycotoxins in wheat. We simulated a system with high disease pressure, i.e. maize-wheat rotation under no-tillage, by applying maize residues artificially inoculated with Fusarium graminearum in field plots after wheat sowing. For mulch layers, a novel cut-and-carry biofumigation approach was employed. Cover crops grown in separate fields were harv…
The expedient application of microbial fermentation after whole-wheat milling and fractionation to mitigate mycotoxins in wheat-based products
2021
Abstract The effect of whole milling and fractionation of wheat grains from the 2017 and 2018 harvests on the mycotoxin transfer into milling products and the influence of microbial fermentation of such products on mycotoxin levels were analysed. Additionally, the identification and occurrence of fungal contamination in grains with different mycotoxin contamination levels was evaluated. The mycotoxin contents were determined by chromatography (HPLC-TOF-HRMS). The distribution of mycotoxins in wheat wholemeal fractions depended on wheat kernel contamination level. The flour fractions contained zearalenone (ZEN) from 59 to 92%, and deoxynivalenol (DON) and deoxynivalenol-3-glucoside (D3G) at …