Search results for "NONEQUILIBRIUM"

Nonlinear relaxation phenomena in metastable condensed matter systems

2016

Nonlinear relaxation phenomena in three different systems of condensed matter are investigated. (i) First, the phase dynamics in Josephson junctions is analyzed. Specifically, a superconductor-graphene-superconductor (SGS) system exhibits quantum metastable states, and the average escape time from these metastable states in the presence of Gaussian and correlated fluctuations is calculated, accounting for variations in the the noise source intensity and the bias frequency. Moreover, the transient dynamics of a long-overlap Josephson junction (JJ) subject to thermal fluctuations and non-Gaussian noise sources is investigated. Noise induced phenomena are observed, such as the noise enhanced s…

Stabilization Effects of Dichotomous Noise on the Lifetime of theSuperconducting State in a Long Josephson Junction

2015

We investigate the superconducting lifetime of a long overdamped current-biased Josephson junction, in the presence of telegraph noise sources. The analysis is performed by randomly choosing the initial condition for the noise source. However, in order to investigate how the initial value of the dichotomous noise affects the phase dynamics, we extend our analysis using two different fixed initial values for the source of random fluctuations. In our study, the phase dynamics of the Josephson junction is analyzed as a function of the noise signal intensity, for different values of the parameters of the system and external driving currents. We find that the mean lifetime of the superconductive…

Poly-l-Lactic Acid Nanofiber-Polyamidoamine Hydrogel Composites: Preparation, Properties, and Preliminary Evaluation as Scaffolds for Human Pluripote…

2016

Electrospun poly-l-lactic acid (PLLA) nanofiber mats carrying surface amine groups, previously introduced by nitrogen atmospheric pressure nonequilibrium plasma, are embedded into aqueous solutions of oligomeric acrylamide-end capped AGMA1, a biocompatible polyamidoamine with arg-gly-asp (RGD)-reminiscent repeating units. The resultant mixture is finally cured giving PLLA-AGMA1 hydrogel composites that absorb large amounts of water and, in the swollen state, are translucent, soft, and pliable, yet as strong as the parent PLLA mat. They do not split apart from each other when swollen in water and remain highly flexible and resistant, since the hydrogel portion is covalently grafted onto the …

Chemically Fueled Volume Phase Transition of Polyacid Microgels

2021

Abstract Microgels are soft colloids that show responsive behavior and are easy to functionalize for applications. They are considered key components for future smart colloidal material systems. However, so far microgel systems have almost exclusively been studied in classical responsive switching settings using external triggers, while internally organized, autonomous control mechanisms as found in supramolecular chemistry and DNA nanotechnology relying on fuel‐driven out‐of‐equilibrium concepts have not been implemented into microgel systems. Here, we introduce chemically fueled transient volume phase transitions (VPTs) for poly(methacrylic acid) (PMAA) microgels, where the collapsed hydr…

Multicomponent density-functional theory for time-dependent systems

2007

We derive the basic formalism of density functional theory for time-dependent electron-nuclear systems. The basic variables of this theory are the electron density in body-fixed frame coordinates and the diagonal of the nuclear N-body density matrix. The body-fixed frame transformation is carried out in order to achieve an electron density that reflects the internal symmetry of the system. We discuss the implications of this body-fixed frame transformation and establish a Runge-Gross-type theorem and derive Kohn-Sham equations for the electrons and nuclei. We illustrate the formalism by performing calculations on a one-dimensional diatomic molecule for which the many-body Schrodinger equati…

Nonequilibrium statistical mechanics of dilute relativistic plasmas

2005

Energy of string loops and thermodynamics of dark energy

2011

We discuss the thermodynamic aspects of a simple model of cosmic string loops, whose energy is nonlinearly related to their lengths. We obtain in a direct way an equation of state having the form p=-(1+{alpha}){rho}/3, with {rho} the energy density and 1+{alpha} the exponent which relates the energy u{sub l} of a loop with its length l as u{sub l}{approx}l{sup 1+{alpha}}. In the linear situation ({alpha}=0) one has p=-{rho}/3, in the quadratic one ({alpha}=1) p=-2{rho}/3, and in the cubic case ({alpha}=2) p=-{rho}. For all values of {alpha} the entropy goes as S{approx}(2-{alpha})L{sup 3/2} (L being the string length density). The expression of S is useful to explore the behavior of such st…

Transfer coefficients for evaporation of a system with a Lennard-Jones long-range spline potential

2007

International audience; Surface transfer coefficients are determined by nonequilibrium molecular dynamics simulations for a Lennard-Jones fluid with a long-range spline potential. In earlier work A. Røsjorde et al., J. Colloid Interface Sci. 240, 355 2001; J. Xu et al., ibid. 299, 452 2006, using a short-range Lennard-Jones spline potential, it was found that the resistivity coefficients to heat and mass transfer agreed rather well with the values predicted by kinetic theory. For the long-range Lennard-Jones spline potential considered in this paper we find significant discrepancies from the values predicted by kinetic theory. In particular the coupling coefficient, and as a consequence the…

Waves Propagation in Turbulent Superfluid Helium in Presence of Combined Rotation and Counterflow

2010

A complete study of the propagation of waves (namely longitudinal density and temperature waves, longitudinal and transversal velocity waves and heat waves) in turbulent superfluid helium is made in three situations: a rotating frame, a thermal counterflow, and the simultaneous combination of thermal counterflow and rotation. Our analysis aims to obtain as much as possible information on the tangle of quantized vortices from the wave speed and attenuation factor of these different waves, depending on their relative direction of propagation with respect to the rotation vector.

Evidence for the Existence of an Effective Interfacial Tension between Miscible Fluids: Isobutyric Acid-Water and 1-Butanol-Water in a Spinning-Drop …

2006

We report definitive evidence for an effective interfacial tension between two types of miscible fluids using spinning-drop tensiometry (SDT). Isobutyric acid (IBA) and water have an upper critical solution temperature (UCST) of 26.3 degrees C. We created a drop of the IBA-rich phase in the water-rich phase below the UCST and then increased the temperature above it. Long after the fluids have reached thermal equilibrium, the drop persists. By plotting the inverse of the drop radius cubed (r(-)(3)) vs the rotation rate squared (omega(2)), we confirmed that an interfacial tension exists and estimated its value. The transition between the miscible fluids remained sharp instead of becoming more…