Search results for "NOX"
showing 10 items of 727 documents
CCDC 1440374: Experimental Crystal Structure Determination
2016
Related Article: Kabali Senthilkumar, Krishnan Thirumoorthy, Claudia Dragonetti, Daniele Marinotto, Stefania Righetto, Alessia Colombo, Matti Haukka, Nallasamy Palanisami|2016|Dalton Trans.|45|11939|doi:10.1039/C6DT01590E
CCDC 1423254: Experimental Crystal Structure Determination
2015
Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C
CCDC 1562412: Experimental Crystal Structure Determination
2018
Related Article: Murat Alkan-Zambada, Sarah Keller, Laura Martínez-Sarti, Alessandro Prescimone, José M. Junquera-Hernández, Edwin C. Constable, Henk J. Bolink, Michele Sessolo, Enrique Ortí, Catherine E. Housecroft|2018|J.Mater.Chem.C|6|8460|doi:10.1039/C8TC02882F
Ethene/norbornene copolymerization with (isodicyclopentadienyl)titanium complex-MAO catalyst
2007
Norbornene (NB) homopolymerization and ethene/NB copolymerizations with a silylene-bridged (isodicyclopentadienyl)(tert-butylamido)titanium dichloride-methylalumoxane (MAO) catalyst system were investigated. This catalytic system shows no efficiency towards NB homopolymerization but produces poly(ethene-co-norbornene)s. An increase in the initial NB feed content leads to a loss of copolymerization activity as well as NB copolymer incorporation. The structure of the isodicyclopentadienyl fragment (IsodiCp) has a strong limiting effect on comonomer incorporation possibilities.
A Combined Experimental and Theoretical Study of the Ammonium Bifluoride Catalyzed Regioselective Synthesis of Quinoxalines and Pyrido[2,3-b]pyrazines
2015
International audience; Ammonium bifluoride was efficiently used (at a 0.5 mol % loading) to catalyze the cyclocondensation between 1,2-arylenediamines and 1,2-dicarbonyl compounds at room temperature in methanol-water, affording quinoxalines and pyrido[2,3-b]pyrazines in excellent yields. Importantly, 2,8-disubstituted quinoxalines and 3-substituted pyrido[2,3-b]pyrazines were regioselectively formed by reacting aryl glyoxals with 3-methyl-1,2-phenylenediamine and 2,3-diaminopyridine, respectively. Analysis of the DFT reactivity indices allowed to explain the catalytic role of ammonium bifluoride.
Carbon monoxide activation by a molecular aluminium imide: C-O bond cleavage and C-C bond formation
2020
Anionic molecular imide complexes of aluminium are accessible via a rational synthetic approach involving the reactions of organo azides with a potassium aluminyl reagent. In the case of K2 [(NON)Al(NDipp)]2 (NON=4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethyl-xanthene; Dipp=2,6-diisopropylphenyl) structural characterization by X-ray crystallography reveals a short Al-N distance, which is thought primarily to be due to the low coordinate nature of the nitrogen centre. The Al-N unit is highly polar, and capable of the activation of relatively inert chemical bonds, such as those found in dihydrogen and carbon monoxide. In the case of CO, uptake of two molecules of the substrate…
Mono-DMSO ligated cobalt nitrophenylcorroles: electrochemical and spectral characterization
2018
Four mono-DMSO ligated cobalt corroles with one or three meso-nitrophenyl substituents on the macrocycle were synthesized and investigated as to their electrochemical and spectroscopic properties in CH2Cl2 and DMSO. Comparisons are made between redox reactions of the five-coordinate DMSO adducts in the current study and earlier examined five- and six-coordinate cobalt corroles with pyridine axial ligands which were characterized in a variety of nonaqueous electrochemical solvents. The binding of carbon monoxide (CO) is also investigated.
Very Deep inside the SN 1987A Core Ejecta: Molecular Structures Seen in 3D
2017
Most massive stars end their lives in core-collapse supernova explosions and enrich the interstellar medium with explosively nucleosynthesized elements. Following core collapse, the explosion is subject to instabilities as the shock propagates outwards through the progenitor star. Observations of the composition and structure of the innermost regions of a core-collapse supernova provide a direct probe of the instabilities and nucleosynthetic products. SN 1987A in the Large Magellanic Cloud (LMC) is one of very few supernovae for which the inner ejecta can be spatially resolved but are not yet strongly affected by interaction with the surroundings. Our observations of SN 1987A with the Ataca…
Preliminary results on the influence of car characteristics on their gases emissions using gas sensors
2018
Abstract A method, based on the use of monitoring portable sensors, has been successfully employed for the determination of the composition of car exhausts from 11 diesel and 5 gasoline cars. These emissions include nitrogen oxides (NOx), carbon monoxide (CO), carbon dioxide (CO2) and volatile organic compounds (VOCs). The measures were taken in different places where each car was parked. In this study it has been tried to correlate the emitted gases with some of the car characteristics, such as the power (varied from 68 to 143 HP), the number of kilometers traveled and the age of the car (between 2 and 19 years). Results found show a significant variation of the emission values, which rang…
Zr/Hf ratio and REE behaviour: A coupled indication of lithogenic input in marginal basins and deep-sea brines
2019
Abstract The distribution of dissolved Zr, Hf and Rare Earth Elements (yttrium and lanthanides, hereafter referred to as REE) in the Eastern Mediterranean seawater column was measured in the Kryos basin to evaluate the lithogenic contribution from both Nile River and Sahara and Arabian desert dust. We found dissolved Zr/Hf ratios below the signature of crustal rocks and chondrites; a phenomenon likely driven by the dissolution of the Mn-rich coating of atmospheric dust particles delivered from the desert. In deeper waters, Zr/Hf ratios are clustered close to the signature of crustal rocks and chondrites according to the different Zr and Hf dissolved speciation. The Zr/Hf ratio observed in t…