Search results for "NUMBER"

Entrapment of amino acids in gas phase surfactant assemblies: The case of tryptophan confined in positively charged (1R,2S)-dodecyl (2-hydroxy-1-meth…

2017

The ability of positively charged aggregates of the surfactant (1R,2S)‐dodecyl (2‐hydroxy‐1‐methyl‐2‐phenylethyl))dimethylammonium bromide (DMEB) to incorporate D-tryptophan or L-tryptophan in the gas phase has been investigated by electrospray ion mobility mass spectrometry (ESI‐IM‐MS). Strongly impacted by the pH of the electrosprayed solutions, both protonated (T+) and deprotonated (T-) tryptophan are effectively included into the aggregates, whereas, tryptophan in zwitterionic (T0) form is practically absent in singly charged DMEB aggregates but can be found in multiply charged ones. The ability to incorporate tryptophan increases with the aggregation number and charge state of aggr…

Silica-protein composite layers of the giant basal spicules from Monorhaphis: Basis for their mechanical stability

2010

The hexactinellid sponge Monorhaphis chuni possesses with its giant basal spicules the largest biosilica structure on Earth. The approximately 8.5-mm-thick spicules are composed of up to 800 lamellae. By application of high-resolution electron microscopy (HR-SEM), it is shown that within the siliceous lamellae a proteinaceous scaffold exists which is composed of one protein of a size of 27 kDa. Analyses with Fourier transform infrared (FT-IR) emission and energy-dispersive X-ray (EDX) spectroscopy support this localization of the protein. No evidence for the presence of protein on the surfaces of the lamellae could be obtained. Heating the giant basal spicule to 600 °C destroys and eliminat…

Crystal structure determination of a new LaPO4 phase in a multicomponent glass ceramic via 3D electron diffraction

2022

Abstract A glass ceramic from the MgO–Al2O3–SiO2 system containing additives of ZrO2, TiO2, La2O3 and P2O5 was investigated. Via x-ray powder diffraction (XRPD) and Transmission electron microscopy(TEM) the crystalline phases present could be identified as MgAl2O4 (Spinel), orthorhombic ZrTiO4 and a polymorph of LaPO4 with a previously unknown crystal structure. The crystal structure of this LaPO4 phase was solved ab initio via 3D ED Data. The polymorph occurs in a distorted barite structure type in the same space group (P21/n) as the stable monazite type polymorph, however the density is higher and the La has a higher coordination number. Furthermore the LaPO4 is present in a spinodal reli…

ChemInform Abstract: Genetic, Biological and Structural Hierarchies During Sponge Spicule Formation: from Soft Sol-Gels to Solid 3D Silica Composite …

2012

Efficient polarization of high-angular-momentum systems

2016

We propose methods of optical pumping that are applicable to open, high-angular-momentum transitions in atoms and molecules, for which conventional optical pumping would lead to significant population loss. Instead of applying circularly polarized cw light, as in conventional optical pumping, we propose to use techniques for coherent population transfer (e.g., adiabatic fast passage) to arrange the atoms so as to increase the entropy removed from the system with each spontaneous decay from the upper state. This minimizes the number of spontaneous-emission events required to produce a stretched state, thus reducing the population loss due to decay to other states. To produce a stretched stat…

Radio k-Labelings for Cartesian Products of Graphs

2005

International audience; Frequency planning consists in allocating frequencies to the transmitters of a cellular network so as to ensure that no pair of transmitters interfere. We study the problem of reducing interference by modeling this by a radio k-labeling problem on graphs: For a graph G and an integer k ≥ 1, a radio k-labeling of G is an assignment f of non negative integers to the vertices of G such that |f(x)−f(y)| ≥ k+1−dG(x,y), for any two vertices x and y, where dG(x,y) is the distance between x and y in G. The radio k-chromatic number is the minimum of max{f(x)−f(y):x,y ∈ V(G)} over all radio k-labelings f of G. In this paper we present the radio k-labeling for the Cartesian pro…

D-stability for discrete-time t-s fuzzy descriptor systems with multiple delays

2014

In this work, the D-stability problem is considered for a class of discrete-time Takagi-Sugeno (T-S) fuzzy descriptor systems with multiple state delays. In terms of linear matrix inequality, sufficient conditions are proposed to ensure that all poles of the descriptor T-S fuzzy system are located within a disk contained in the unit circle. Moreover, a sufficient condition is presented such that the singular system is regular, causal and D-stable in spite of multiple state delays. Finally, an example is given to show the effectiveness and advantages of the proposed techniques Refereed/Peer-reviewed

Effects of ocean acidification on embryonic respiration and development of a temperate wrasse living along a natural CO2 gradient

2016

Volcanic CO2 seeps provide opportunities to investigate the effects of ocean acidification on organisms in the wild. To understand the influence of increasing CO2 concentrations on the metabolic rate (oxygen consumption) and the development of ocellated wrasse early life stages, we ran two field experiments, collecting embryos from nesting sites with different partial pressures of CO2 [pCO2; ambient (400 µatm) and high (800-1000 µatm)] and reciprocally transplanting embryos from ambient- to high-CO2 sites for 30 h. Ocellated wrasse offspring brooded in different CO2 conditions had similar responses, but after transplanting portions of nests to the high-CO2 site, embryos from parents that sp…

Cyclic Dynamic Evaluation of Logistics Services Stakeholders Based on System with OFN Model

2021

The challenge for enterprises and supply chains is to deliver successful logistics services in compliance with their aims. Logistics services are affected by many stakeholders. Recognizing their impact on the undertaken services is important for the planning and execution of a sufficiently rigorous stakeholder management process. The aim of the paper is to present a new approach to the analysis of stakeholders - cyclic dynamic evaluation, which could be used in service management, such as in logistics services. We present a novel fuzzy inference system based on the mathematical apparatus of Ordered Fuzzy Numbers (OFNs). The evaluation of stakeholders consists in assessing key factors as - f…

Supersaturation and activity-rotation relation in PMS stars: the young Cluster h Per

2016

The magnetic activity of late-type MS stars is characterized by different regimes, and their activity levels are well described by Ro, the ratio between P_rot and the convective turnover time. Very young PMS stars show, similarly to MS stars, intense magnetic activity. However they do not show clear activity-rotation trends, and it still debated which stellar parameters determine their magnetic activity levels. To bridge the gap between MS and PMS stars, we studied the activity-rotation relation in the young cluster h Per, a ~13 Myr old cluster, that contains both fast and slow rotators, whose members have ended their accretion phase and have already developed a radiative core. It offers us…