Search results for "Names"
showing 10 items of 6843 documents
Identification of Trans-Golgi Network Proteins in Arabidopsis thaliana Root Tissue
2014
Knowledge of protein subcellular localization assists in the elucidation of protein function and understanding of different biological mechanisms that occur at discrete subcellular niches. Organelle-centric proteomics enables localization of thousands of proteins simultaneously. Although such techniques have successfully allowed organelle protein catalogues to be achieved, they rely on the purification or significant enrichment of the organelle of interest, which is not achievable for many organelles. Incomplete separation of organelles leads to false discoveries, with erroneous assignments. Proteomics methods that measure the distribution patterns of specific organelle markers along densit…
Missing value imputation in proximity extension assay-based targeted proteomics data
2020
Targeted proteomics utilizing antibody-based proximity extension assays provides sensitive and highly specific quantifications of plasma protein levels. Multivariate analysis of this data is hampered by frequent missing values (random or left censored), calling for imputation approaches. While appropriate missing-value imputation methods exist, benchmarks of their performance in targeted proteomics data are lacking. Here, we assessed the performance of two methods for imputation of values missing completely at random, the previously top-benchmarked ‘missForest’ and the recently published ‘GSimp’ method. Evaluation was accomplished by comparing imputed with remeasured relative concentrations…
A Dynamic Distributed Algorithm for Multicast Path Setup
2005
In the past few years, there has been a considerable work on multicast route selection techniques, with the aim to design scalable protocols which can guarantee an efficient use of network resources. Steiner tree-based multicast algorithms produce optimal trees, but they are prohibitively expensive. For this reason, heuristic methods are generally employed. Conventional centralized Steiner heuristics provide effective solutions, but they are unpractical for large networks, since they require a complete knowledge of the network topology. In this paper, we propose a new distributed approach that is efficient and suitable for real network adoption. Performance evaluation indicates that it outp…
Proton pump for O2 reduction catalyzed by 5,10,15,20-tetraphenylporphyrinatocobalt(II).
2009
The role of 5,10,15,20-tetraphenylporphyrinatocobalt(II) ([Co(tpp)]) as a catalyst on molecular oxygen (O(2)) reduction by ferrocene (Fc) and its two derivatives, 1,1'-dimethylferrocene (DFc) and decamethylferrocene (DMFc) at a polarized water|1,2-dichloroethane (DCE) interface has been studied. The water|DCE interface essentially acts as a proton pump controlled by the Galvani potential difference across the interface, driving the proton transfer from water to DCE. [Co(tpp)] catalyzed O(2) reduction by Fc, DFc and DMFc is then followed to produce hydrogen peroxide (H(2)O(2)). The catalytic mechanism is similar to that proposed by Fukuzumi et al. for bulk reactions. This interfacial system …
Short hydrogen bonds enhance non-aromatic protein-related fluorescence
2020
AbstractFluorescence in biological systems is usually associated with the presence of aromatic groups. Here, we show that specific hydrogen bonding networks can significantly affect fluorescence employing a combined experimental and computational approach. In particular, we reveal that the single amino acid L-glutamine, by undergoing a chemical transformation leading to the formation of a short hydrogen bond, displays optical properties that are significantly enhanced compared to L-glutamine itself. Ab initio molecular dynamics simulations highlight that these short hydrogen bonds prevent the appearance of a conical intersection between the excited and the ground states and thereby signific…
Patterning of Magnetic Bimetallic Coordination Nanoparticles of Prussian Blue Derivatives by the Langmuir–Blodgett Technique
2012
We report a novel method to prepare patterns of nanoparticles over large areas of the substrate. This method is based on the adsorption of the negatively charged nanoparticles dispersed in an aqueous subphase onto a monolayer of the phospholipid dipalmitoyl-l-α-phosphatidylcholine (DPPC) at the air-water interface. It has been used to prepare patterns of nanoparticles of Prussian blue analogues (PBA) of different size (K(0.25)Ni[Fe(CN)(6)](0.75) (NiFe), K(0.25)Ni[Cr(CN)(6)](0.75) (NiCr), K(0.25)Ni[Co(CN)(6)](0.75) (NiCo), Cs(0.4)Co[Cr(CN)(6)](0.8) (CsCoCr), and Cs(0.4)Co[Fe(CN)(6)](0.9) (CsCoFe)). The behavior of DPPC monolayer at the air-water interface in the presence of the subphase of P…
Pseudo-Bosons from Landau Levels
2010
We construct examples of pseudo-bosons in two dimensions arising from the Hamiltonian for the Landau levels. We also prove a no-go result showing that non-linear combinations of bosonic creation and annihilation operators cannot give rise to pseudo-bosons.
Finite-dimensional pseudo-bosons: a non-Hermitian version of the truncated harmonic oscillator
2018
We propose a deformed version of the commutation rule introduced in 1967 by Buchdahl to describe a particular model of the truncated harmonic oscillator. The rule we consider is defined on a $N$-dimensional Hilbert space $\Hil_N$, and produces two biorhogonal bases of $\Hil_N$ which are eigenstates of the Hamiltonians $h=\frac{1}{2}(q^2+p^2)$, and of its adjoint $h^\dagger$. Here $q$ and $p$ are non-Hermitian operators obeying $[q,p]=i(\1-Nk)$, where $k$ is a suitable orthogonal projection operator. These eigenstates are connected by ladder operators constructed out of $q$, $p$, $q^\dagger$ and $p^\dagger$. Some examples are discussed.
A no-go result for the quantum damped harmonic oscillator
2019
Abstract In this letter we show that it is not possible to set up a canonical quantization for the damped harmonic oscillator using the Bateman Lagrangian. In particular, we prove that no square integrable vacuum exists for the natural ladder operators of the system, and that the only vacua can be found as distributions. This implies that the procedure proposed by some authors is only formally correct, and requires a much deeper analysis to be made rigorous.
Two-dimensional Noncommutative Swanson Model and Its Bicoherent States
2019
We introduce an extended version of the Swanson model, defined on a two-dimensional noncommutative space, which can be diagonalized exactly by making use of pseudo-bosonic operators. Its eigenvalues are explicitly computed and the biorthogonal sets of eigenstates of the Hamiltonian and of its adjoint are explicitly constructed.We also show that it is possible to construct two displacement-like operators from which a family of bi-coherent states can be obtained. These states are shown to be eigenstates of the deformed lowering operators, and their projector allows to produce a suitable resolution of the identity in a dense subspace of \(\mathcal{L}^\mathrm{2}\, (\mathbb{R}^\mathrm{2})\).