Search results for "Nanosecond"
showing 10 items of 59 documents
Fourth-order cascaded Raman shift in AsSe chalcogenide suspended-core fiber pumped at 2 μm
2011
International audience; Cascaded Raman wavelength shifting up to the fourth order ranging from 2092 to 2450nm is demonstrated using a nanosecond pump at 1995nm in a low-loss As38Se62 suspended-core microstructured fiber. These four Stokes shifts are obtained with a low peak power of 11W, and only 3W are required to obtain three shifts. The Raman gain coefficient for the fiber is estimated to (1.6 +-0.5)x 10e−11 m/W at 1995nm. The positions and the amplitudes of the Raman peaks are well reproduced by the numerical simulations of the nonlinear propagation.
Nanosecond thermo-optical dynamics of polymer loaded plasmonic waveguides
2013
The thermo-optical dynamics of polymer loaded surface plasmon waveguide (PLSPPW) based devices photo-thermally excited in the nanosecond regime is investigated. We demonstrate thermo-absorption of PLSPPW modes mediated by the temperature-dependent ohmic losses of the metal and the thermally controlled field distribution of the plasmon mode within the metal. For a PLSPPW excited by sub-nanosecond long pulses, we find that the thermo-absorption process leads to modulation depths up to 50% and features an activation time around 2ns whereas the relaxation time is around 800ns, four-fold smaller than the cooling time of the metal film itself. Next, we observe the photo-thermal activation of PLSP…
Spectral and kinetic characteristics of pyroelectric luminescence in LiGaO2
2019
Abstract Pyroelectric luminescence was observed in noncentrosymmetrical crystal LiGaO2 with the direct band gap around 6 eV. For the first time spectral and kinetic characteristics of pyroelectric luminescence were obtained. The temporal structure of the PEL signal was determined as a sequence of pulses with duration not longer than several nanoseconds. This allowed proposing of the luminescence mechanism: in vacuum conditions in LiGaO2 crystal pyroelectric luminescence occurs inside the sample due to radiative recombination of electrons with the positively charged intrinsic luminescence centres.
Short photoluminescence lifetimes in vacuum-deposited ch3nh3pbI3 perovskite thin films as a result of fast diffusion of photogenerated charge carriers
2019
It is widely accepted that a long photoluminescence (PL) lifetime in metal halide perovskite films is a crucial and favorable factor, as it ensures a large charge diffusion length leading to a high power conversion efficiency (PCE) in solar cells. It has been recently found that vacuumevaporated CH3NH3PbI3 (eMAPI) films show very short PL lifetimes of several nanoseconds. The corresponding solar cells, however, have high photovoltage (>1.1 V) and PCEs (up to 20%). We rationalize this apparent contradiction and show that eMAPI films are characterized by a very high diffusion coefficient D, estimated from modeling the PL kinetics to exceed 1 cm2/s. Such high D values are favorable for long di…
Synthesis of multi-color luminescent ZnO nanoparticles by ultra-short pulsed laser ablation
2020
Abstract Crystalline ZnO nanoparticles (NPs) are synthesized by ultra-short femtosecond (fs) pulsed laser ablation (PLA) of a zinc plate in deionized water, and are investigated by optical absorption and time resolved luminescence spectra in combination with the morphology and structure analysis. The comparison with previous experiments based on short nanosecond (ns) PLA highlights that pulse duration is a crucial parameter to determine the size and the optical properties of ZnO NPs. While short PLA generates NPs with average size S ‾ of ~ 30 nm, ultrashort PLA allows to achieve much smaller NPs, S ‾ ⩽ 10 nm, that evidence weak quantum confinement effects on both the absorption edge and th…
2015
Two novel charged organic thermally activated delayed fluorescence (TADF) emitters, 1 and 2, have been synthesized. Their TADF behavior is well-supported by the multiexponential decay of their emission (nanosecond and microsecond components) and the oxygen dependence of the photoluminescence quantum yields. Spin-coated electroluminescent devices have been fabricated to make light-emitting electrochemical cells (LEECs) and organic light-emitting diodes (OLEDs). The first example of a non-doped charged small organic molecule LEEC is reported and exhibited an external quantum efficiency (EQE) of 0.39% using 2. With a multilayer architecture, a solution-processed OLED device using neat 2 as the…
Tracking the structural dynamics of proteins in solution using time-resolved wide-angle X-ray scattering
2008
We demonstrate tracking of protein structural changes with time-resolved wide-angle X-ray scattering (TR-WAXS) with nanosecond time resolution. We investigated the tertiary and quaternary conformational changes of human hemoglobin under nearly physiological conditions triggered by laser-induced ligand photolysis. We also report data on optically induced tertiary relaxations of myoglobin and refolding of cytochrome c to illustrate the wide applicability of the technique. By providing insights into the structural dynamics of proteins functioning in their natural environment, TR-WAXS complements and extends results obtained with time-resolved optical spectroscopy and X-ray crystallography.
Electrochemical Tantalum Oxide for Resistive Switching Memories
2017
Redox-based resistive switching memories (ReRAMs) are strongest candidates for the next-generation nonvolatile memories fulfilling the criteria for fast, energy efficient, and scalable green IT. These types of devices can also be used for selector elements, alternative logic circuits and computing, and memristive and neuromorphic operations. ReRAMs are composed of metal/solid electrolyte/metal junctions in which the solid electrolyte is typically a metal oxide or multilayer oxides structures. Here, this study offers an effective and cheap electrochemical approach to fabricate Ta/Ta2O5-based devices by anodizing. This method allows to grow high-quality and dense oxide thin films onto a metal…
Fourth order cascaded Raman shift in As38Se62 chalcogenide suspended core fiber pumped at 1.995 μm
2011
Fourth order cascaded Raman wavelength shift is demonstrated in As 38 Se 62 suspended core fiber using 1995 nm nanosecond source. The measured Raman gain coefficient is∼2×10−11 m/W at 1995 nm. The Raman peaks are reproduced by numerical simulations.
Tapering photonic crystal fibres for supercontinuum generation with nanosecond pulses at 532nm
2008
Experimental results on supercontinuum generation in photonic crystal fibre tapers using pump pulses of 7 ns duration at 532 nm are presented. Photonic crystal fibre tapers with the first wavelength of zero dispersion around 532 nm were fabricated. The generation of supercontinuum was investigated in normal and anomalous dispersion regimes. Supercontinuum spectra spanning more than 400 nm in the visible region are reported.