Search results for "NiTi"

Systematic Investigation of Resorcin[4]arene-Based Cavitands as Affinity Materials on Quartz Crystal Microbalances.

2017

Resorcin[4]arene cavitands are well-known supramolecular hosts, and their outstanding guest-binding abilities in solution have been studied in detail in recent decades. In a systematic approach, different resorcin[4]arene cavitands and container molecules are characterized as affinity materials for gravimetric sensing using high-fundamental-frequency quartz crystal microbalances. Analysis of their affinity toward a series of various analytes reveals a remarkable dependence of both selectivity and sensitivity on the shape, accessibility, and size of the cavity, along with their supramolecular interactions with the host molecules.

Formation and trapping of the thermodynamically unfavoured inverted-hemicucurbit[6]uril

2019

Amplification of a thermodynamically unfavoured macrocyclic product through the directed shift of the equilibrium between dynamic covalent chemistry library members is difficult to achieve. We show for the first time that during condensation of formaldehyde and cis-N,N'-cyclohexa-1,2-diylurea formation of inverted-cis-cyclohexanohemicucurbit[6]uril (i-cis-cycHC[6]) can be induced at the expense of thermodynamically favoured cis-cyclohexanohemicucurbit[6]uril (cis-cycHC[6]). The formation of i-cis-cycHC[6] is enhanced in low concentration of the templating chloride anion and suppressed in excess of this template. We found that reaction selectivity is governed by the solution-based template-a…

Recognition of self-assembled water-nitrate cluster in a Co(III)-2,2′-bipyridine host: Synthesis, X-ray structure, DNA cleavage, molecular docking an…

2016

A mononuclear cobalt(III) complex [Co(bpy)2Cl2]NO3⋅2H2O (1) (bpy = 2,2′-bipyridine) has been synthesized and crystallographically characterized. Self-assembly of the lattice water molecules from rectangular tetrameric water cluster interacts with nitrate anion along the c-axis forming a six membered hexagonal water-nitrate cluster. It presents a new mode of association of water molecules with nitrate molecules which is not predicted theoretically or found experimentally. The molecule effectively cleaves bacterial genomic DNA and shows important cytotoxicity against human hepatocarcinoma cell (HepG2).

Application of Rigidity-Controlled Supramolecular Affinity Materials for the Gravimetric Detection of Hazardous and Illicit Compounds.

2016

The combination of an (-)-isosteviol-derived building block and 9,9'-spirobifluorene or tetraphenylmethane generated highly potent new affinity materials for the detection of volatile organic compounds (VOCs). Comparison of their affinity behaviour with different core structures showed remarkable influence on selectivity and sensitivity due to structural rigidity and their pre-organization. Their unique supramolecular properties were investigated in an affinity assay using high fundamental frequency quartz crystal microbalances.

Transnational bodies: Embodiment of transnational settings

2016

AbstractThe everyday life of more and more people is characterized by transnationalism. People increasingly interact across borders and in a network of transnational relationships. While interactions may be border-crossing, the actors’ body remains situated and limited in time and space. However, the thesis of this paper is that transnationalism processes are embodied. Thus, we speak of an embodiment of transnational settings. We focus on symbolic interactionism – Charles H. Cooley and George H. Mead in particular provide a large repertoire of concepts – to theoretically conceive transnational bodies. To show how transnational embodiment can manifest itself we use the example of young peopl…

2019

Abstract. This study uses the synergy of multi-resolution soil moisture (SM) satellite estimates from the Soil Moisture Ocean Salinity (SMOS) mission, a dense network of ground-based SM measurements, and a soil–vegetation–atmosphere transfer (SVAT) model, SURFEX (externalized surface), module ISBA (interactions between soil, biosphere and atmosphere), to examine the benefits of the SMOS level 4 (SMOS-L4) version 3.0, or “all weather” high-resolution soil moisture disaggregated product (SMOS-L43.0; ∼1 km). The added value compared to SMOS level 3 (SMOS-L3; ∼25 km) and SMOS level 2 (SMOS-L2; ∼15 km) is investigated. In situ SM observations over the Valencia anchor station (VAS; SMOS calibrati…

Associations between air pollution and pediatric eczema, rhinoconjunctivitis and asthma: A meta-analysis of European birth cohorts

2020

Background: Uncertainly continues to exist regarding the role of air pollution on pediatric asthma and allergic conditions, especially as air pollution levels have started to decrease in recent decades. Objective: We examined associations of long-term air pollution levels at the home address with pediatric eczema, rhinoconjunctivitis and asthma prevalences in five birth cohorts (BIB, EDEN, GASPII, RHEA and INMA) from seven areas in five European countries. Methods: Current eczema, rhinoconjunctivitis and asthma were assessed in children aged four (N = 6527) and eight years (N = 2489). A multi-morbidity outcome (≥2 conditions versus none) was also defined. Individual outdoor levels of nitrog…

Fractals and geography

2007

Coastal precipitation regimes in Kenya.

1997

Kenya is under the influence of the seasonal reversal of the Indian ocean monsoons. However, its coastal belt, up to about 50 km inland, exhibits original climatic features. Hierarchical clustering...

Optimized Class-Separability in Hyperspectral Images

2016

International audience; Image visualization techniques are mostly based on three bands as RGB color composite channels for human eye to characterize the scene. This, however, is not effective in case of hyper-spectral images (HSI) because they contain dozens of informative spectral bands. To eliminate redundancy of spectral information among these bands, dimensionality reduction (DR) is applied while at the same trying to retain maximum information. In this paper, we propose a new method of information-preserved hyper-spectral satellite image visualization that is based on fusion of unsupervised band selection techniques and color matching function (CMF) stretching. The results show consist…