Search results for "Nitrogen"
showing 10 items of 1200 documents
Effects of Increasing Doses of Nitrogen Fertilization on Winter Melon Production in the Western Coast of Sicily
2010
The winter melon is largely grown in the open field in the Mediterranean island of Sicily on about 6000 hectares. Nitrogen fertilization is a key aspect of a winter melon cultural system as it can dramatically improve fruit production and play a crucial role on fruit quality attributes such as fruit size, colour and uniformity. An experiment was performed to determine the influence of increasing doses of nitrogen fertilization on fruit yield and quality of winter melon. The trial was conducted in the north-western coast of Sicily near Buseto Palizzolo in the province of Trapani, 250-m elevation. Plug type transplants cv. Helios were planted in the first week of May. A transparent polyethyle…
Synthesis and analysis of activity of a potential anti-melanoma prodrug with a hydrazine linker
2013
A potential anti-melanoma prodrug containing a phenolic activator, a hydrazine linker, and a nitrogen mustard effector - (N-{4-[bis-(2-chloroethyl)amino]benzoyl}-N'-(4-hydroxybenzyl)hydrazine) has been synthesized in seven steps. Spectrophotometric measurements of its oxidation by tyrosinase showed a rapid increase of absorbance at 337 nm. HPLC analysis demonstrated that two major products were formed. However, during the reaction one of the products was converted into the other. The stable product with a maximum of absorption at 337 nm was isolated and identified as 5,6-dihydroxy-1H-indazol-1-yl 4-[bis-(2-chloroethyl)amino]benzoate. It was formed by a cyclization of the enzymatically gener…
Nitrogen recovery using a membrane contactor: Modelling nitrogen and pH evolution
2020
[EN] A hollow fibre membrane contactor has been applied for nitrogen recovery from anaerobic digestion supernatant at different operating conditions obtaining nitrogen recovery efficiencies over 99 %. A mathematical model able to represent the time evolution of pH and nitrogen concentration during the recovery process is presented in this paper. The developed model accurately reproduced the results obtained in 26 experiments carried out at different pH values (from 9 to 11), temperatures (from 25 to 35 degrees C), membrane surfaces (from 1.2 to 2.4 m(2)) and feed flow rates (from 0.33 x 10(-5) to 5.83 x 10(-5) m(3)/s) predicting the variations in nitrogen recovery rates measured at the diff…
Simultaneous sludge minimization, biological phosphorous removal and membrane fouling mitigation in a novel plant layout for MBR.
2020
Abstract The integration of one anaerobic reactor in the mainstream (AMSR) of a pre-denitritication-MBR was evaluated with the aim to achieve simultaneous sludge minimization and phosphorous removal. The excess sludge production was reduced by 64% when the AMSR was operated under 8 h of hydraulic retention time (HRT). The highest nutrients removal performances referred to organic carbon (98%), nitrogen (90%) and phosphorous (97%) were obtained under 8 h of HRT. In contrast, prolonged anaerobic-endogenous conditions were found to be detrimental for all nutrients removal performances. Similarly, the lowest membrane fouling tendency (FR = 0.65∙1011 m−1 d−1) was achieved under 8 h of HRT, where…
Biological minimization of excess sludge in a membrane bioreactor: Effect of plant configuration on sludge production, nutrient removal efficiency an…
2018
Abstract Excess sludge minimization was studied in a MBR with pre-denitrification scheme. Sludge minimization, nitrogen removal performance and membrane fouling tendency were investigated in two configurations, characterized by a different position of the sludge retention reactor (SRR). In particular, the SRR was placed: i) in the return activated sludge line (Anaerobic Side-Stream Reactor – ASSR configuration) and ii) in the mainstream between the anoxic and aerobic reactor (Anaerobic Main-Stream Reactor – AMSR configuration). The achieved results demonstrated that the ASSR enabled a higher excess sludge reduction (74% vs 32%), while achieving lower biological nitrogen removal (BNR) (TN = …
Integrated fixed-film activated sludge membrane bioreactors versus membrane bioreactors for nutrient removal: A comprehensive comparison
2018
Abstract This research elucidates the pollutants (nutrients and carbon) removal performance and nitrous oxide (N2O) emissions of two pilot plants. Specifically, a University of Cape Town (UCT) Membrane Bioreactor (MBR) plant and an Integrated Fixed Film Activated Sludge (IFAS)-UCT-MBR plant were investigated. The plants were fed with real wastewater augmented with acetate and glycerol in order to control the influent carbon nitrogen ratio (C/N). The short-term effect of the inlet C/N ratio variation (C/N = 5 mgCOD/mgN and C/N = 10 mgCOD/mgN) on the behaviour of both plants was investigated. The results showed that the IFAS-UCT-MBR configuration provided the best performance in terms of poll…
A comprehensive integrated membrane bioreactor model for greenhouse gas emissions
2018
Abstract A comprehensive integrated membrane bioreactor (MBR) model for wastewater treatment is here proposed. The model quantifies the main biological and physical processes. The model describes the biological removal of organic matter, nitrogen and phosphorus including greenhouse gases (carbon dioxide, CO 2 and nitrous oxide, N 2 O). The model takes into account the following main innovative aspects jointly: i. Two-step nitrification process; ii. N 2 O formation due to ammonia-oxidizing bacteria as a product of the hydroxylamine oxidation (NH 2 OH) and of the nitrite (NO 2 − ) reduction; iii. Soluble microbial product (SMP) formation/degradation due to microbial growth and endogenous resp…
Sequential batch membrane bio-reactor for wastewater treatment: The effect of increased salinity
2016
In this work, a sequential batch membrane bioreactor pilot plant is investigated to analyze the effect of a gradual increase in salinity on carbon and nutrient removal, membrane fouling and biomass kinetic parameters. The salinity was increased by 2 g NaCl L-1 per week up to 10 g NaCl L-1. The total COD removal efficiency was quite high (93%) throughout the experiment. A gradual biomass acclimation to the salinity level was observed during the experiment, highlighting the good recovery capabilities of the system. Nitrification was also influenced by the increase in salinity, with a slight decrease in nitrification efficiency (the lowest value was obtained at 10 g NaCl L-1 due to lower nitri…
Chemical and electrochemical behaviour of 4,4’,4’’,4’’’-tetrakis(dimethylamino)-tetraphenylethylene in an oxidant environment: Toward a new sensor fo…
2020
Abstract Electrochromic compounds are suitable candidates for being used in sensor design. Here we report the use of 4,4’,4’’,4’’’-tetrakis(dimethylamino)-tetraphenylethylene for detecting both NO2 and SO2. Whereas the sensing mechanism in the case of nitrogen dioxide is a simple chemical oxidation reaction, in the case of sulfur dioxide, the mechanism is much more complex and the reaction requires the presence of t-butylhydroperoxide to take place. By modifying the detection conditions both compounds can be detected in gas phase. Additionally, a wide electrochemical study has been carried out to understand the role played by the t-butylhydroperoxide in the reaction with sulfur dioxide.
On the attribution of contributions of atmospheric trace gases to emissions in atmospheric model applications
2010
Abstract. We present an improved tagging method, which describes the combined effect of emissions of various species from individual emission categories, e.g. the impact of both, nitrogen oxides and non-methane hydrocarbon emissions on ozone. This method is applied to two simplified chemistry schemes, which represent the main characteristics of atmospheric ozone chemistry. Analytical solutions are presented for this tagging approach. In the past, besides tagging approaches, sensitivity methods were used, which estimate the contributions from individual sources based on differences in two simulations, a base case and a simulation with a perturbation in the respective emission category. We ap…