Search results for "Noma"
showing 10 items of 6328 documents
Light-induced nonthermal population of optical phonons in nanocrystals
2017
Raman spectroscopy is widely used to study bulk and nanomaterials, where information is frequently obtained from spectral line positions and intensities. In this study, we monitored the Raman spectrum of ensembles of semiconductor nanocrystals (NCs) as a function of optical excitation intensity (optical excitation experiments). We observe that in NCs the red-shift of the Raman peak position with increasing light power density is much steeper than that recorded for the corresponding bulk material. The increase in optical excitation intensity results also in an increasingly higher temperature of the NCs as obtained with Raman thermometry through the commonly used Stokes/anti-Stokes intensity …
Towards Atomically Precise Supported Catalysts from Monolayer‐Protected Clusters: The Critical Role of the Support
2020
Abstract Controlling the size and uniformity of metal clusters with atomic precision is essential for fine‐tuning their catalytic properties, however for clusters deposited on supports, such control is challenging. Here, by combining X‐ray absorption spectroscopy and density functional theory calculations, it is shown that supports play a crucial role in the evolution of monolayer‐protected clusters into catalysts. Based on the acidic nature of the support, cluster‐support interactions lead either to fragmentation of the cluster into isolated Au–ligand species or ligand‐free metallic Au0 clusters. On Lewis acidic supports that bind metals strongly, the latter transformation occurs while pre…
Chiral footprint of the ligand layer in the all-alkynyl-protected gold nanocluster Au144(CCPhF)60
2019
The electronic structure and chiroptical properties of the recently isolated and structurally characterized all-alkynyl-protected gold nanocluster Au144(CCPhF)60 were analyzed via density functional theory (DFT) computations and compared to those of the structurally similar all-thiolate-protected Au144(SCH2Ph)60. While DFT predicts very strong CD signals of similar strength for both clusters, the origins of chiroptical activity are markedly different. The chiral response of Au144(CCPhF)60 originates only from the footprint of the outermost gold-ligand layer of 30 FPhCC-Au-CCPhF units covering an achiral Ih-symmetric Au114 core whereas the Au114 core of the Au144(SCH2Ph)60 cluster has a chir…
Solid-State Molecular Nanomagnet Inclusion into a Magnetic Metal-Organic Framework: Interplay of the Magnetic Properties.
2015
Single-ion magnets (SIMs) are the smallest possible magnetic devices and are a controllable, bottom-up approach to nanoscale magnetism with potential applications in quantum computing and high-density information storage. In this work, we take advantage of the promising, but yet insufficiently explored, solid-state chemistry of metal-organic frameworks (MOFs) to report the single-crystal to single-crystal inclusion of such molecular nanomagnets within the pores of a magnetic MOF. The resulting host-guest supramolecular aggregate is used as a playground in the first in-depth study on the interplay between the internal magnetic field created by the long-range magnetic ordering of the structur…
Superiority of Optimized Portfolios to Naive Diversification: Fact or Fiction?
2017
Abstract DeMiguel, Garlappi, and Uppal (2009) conducted a highly influential study where they demonstrated that none of the optimized portfolios consistently outperformed the naive diversification. This result triggered a heated debate within the academic community on whether portfolio optimization adds value. Nowadays several studies claim to defend the value of portfolio optimization. The commonality in all these studies is that various portfolio optimization methods are implemented using the datasets generously provided by Kenneth French and the performance is measured by means of the Sharpe ratio. This paper aims to provide a cautionary note regarding the use of Kenneth French datasets …
Understanding deep learning in land use classification based on Sentinel-2 time series
2020
AbstractThe use of deep learning (DL) approaches for the analysis of remote sensing (RS) data is rapidly increasing. DL techniques have provided excellent results in applications ranging from parameter estimation to image classification and anomaly detection. Although the vast majority of studies report precision indicators, there is a lack of studies dealing with the interpretability of the predictions. This shortcoming hampers a wider adoption of DL approaches by a wider users community, as model’s decisions are not accountable. In applications that involve the management of public budgets or policy compliance, a better interpretability of predictions is strictly required. This work aims …
Magma extrusion during the Ubinas 2013-2014 eruptive crisis based on satellite thermal imaging (MIROVA) and ground-based monitoring
2015
International audience; After 3 years of mild gases emissions, the Ubinas volcano entered in a new eruptive phase on September 2nd, 2013. The MIROVA system (a space-based volcanic hot-spot detection system), allowed us to detect in near real time the thermal emissions associated with the eruption and provided early evidence of magma extrusion within the deep summit crater. By combining IR data with plume height, sulfur emissions, hot spring temperatures and seismic activity, we interpret the thermal output detected over Ubinas in terms of extrusion rates associated to the eruption. We suggest that the 2013–2014 eruptive crisis can be subdivided into three main phases: (i) shallow magma intr…
Rare earths behaviour during the deposition of volcanic sublimates
2017
Abstract In this study, the REE distribution between volcanic fluids and related solids in fumaroles with temperatures ranging from approximately 100 to 421 °C was investigated in different geological scenarios. The treatment of geochemical REE data was carried out by calculating the REE enrichment factors (EF REE ) relative to the volcanic host rocks in studied sites under the assumption that the REE transport takes place as silicate aerosol in volcanic fluids. Shale-normalised REE concentrations in these fluids have been assessed to investigate whether the REE transport as aqueous complexes in water-saturated volcanic gas is reasonable. The REE behaviour in alkaline condensates according …
Characterization of the Medieval Climate Anomaly, Little Ice Age and recent warming in northern Lapland
2017
The major climate events of the Common Era (CE) have global imprints but significant variations in their timing and magnitude have been suggested. For reliable assessments of the past climate patterns and their applications for evaluations of the ongoing changes, spatially comprehensive network of high-fidelity paleorecords are necessary. In this study, we reconstruct summer air temperatures of the past 2000 years from northern Lapland (Utsjoki, Finland). We use fossil Chironomidae (Diptera) assemblages from sediments of a remote subarctic lake (Loažžejavri) and the transfer function approach for quantitative temperature reconstruction. The results indicate that the Chironomidae fauna were …
The global bio-events at the Cenomanian-Turonian transition in the reduced Bahloul Formation of Bou Ghanem (central Tunisia).
2010
In central Tunisia, the thickness of the Bahloul Formation varies generally between 20 to 40 m such as for example, respectively, at wadi Smara near Kalaat Senan and at wadi Bahloul near Maktar. The thickness is also of several tens metres at Koudiat el Azreg near Jerissa and at Tajerouine. In these sites where the thickness of the Bahloul Formation is dilated, in addition to five geochemical events (d13C), nine bio-events were defined near the Cenomanian-Turonian transition, successively in ascending order: 1. LO Rotalipora cushmani, 2. Heterohelix bio-event, 3. FO Pseudaspidoceras pseudonodosoides, 4. LO P. pseudonodosoides, 5. LO Thalmanninella multiloculata, 6. “filaments” bio-event, Ce…