6533b851fe1ef96bd12a9a11
RESEARCH PRODUCT
Solid-State Molecular Nanomagnet Inclusion into a Magnetic Metal-Organic Framework: Interplay of the Magnetic Properties.
Emilio PardoMarta MonDonatella ArmentanoAlejandro Pascual-álvarezJoan CanoThais GranchaJorge PasánFrancesc LloretJorge GasconJesús Ferrando-soriasubject
010405 organic chemistryMagnetismChemistryOrganic ChemistrySupramolecular chemistryPhysics::OpticsNanotechnologyGeneral Chemistry010402 general chemistry01 natural sciencesNanomagnetCatalysis0104 chemical sciencesMagnetic fieldMagnetMetal-organic frameworkNanoscopic scaleQuantum computerdescription
Single-ion magnets (SIMs) are the smallest possible magnetic devices and are a controllable, bottom-up approach to nanoscale magnetism with potential applications in quantum computing and high-density information storage. In this work, we take advantage of the promising, but yet insufficiently explored, solid-state chemistry of metal-organic frameworks (MOFs) to report the single-crystal to single-crystal inclusion of such molecular nanomagnets within the pores of a magnetic MOF. The resulting host-guest supramolecular aggregate is used as a playground in the first in-depth study on the interplay between the internal magnetic field created by the long-range magnetic ordering of the structured MOF and the slow magnetic relaxation of the SIM.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2015-12-15 | Chemistry (Weinheim an der Bergstrasse, Germany) |