Search results for "Note"
showing 10 items of 10709 documents
Electrical power production from low-grade waste heat using a thermally regenerative ethylenediamine battery
2017
Abstract Thermally regenerative ammonia-based batteries (TRABs) have been developed to harvest low-grade waste heat as electricity. To improve the power production and anodic coulombic efficiency, the use of ethylenediamine as an alternative ligand to ammonia was explored here. The power density of the ethylenediamine-based battery (TRENB) was 85 ± 3 W m−2-electrode area with 2 M ethylenediamine, and 119 ± 4 W m−2 with 3 M ethylenediamine. This power density was 68% higher than that of TRAB. The energy density was 478 Wh m−3-anolyte, which was ∼50% higher than that produced by TRAB. The anodic coulombic efficiency of the TRENB was 77 ± 2%, which was more than twice that obtained using ammon…
Battery characterization via eddy-current imaging with nitrogen-vacancy centers in diamond
2021
Sensitive and accurate diagnostic technologies with magnetic sensors are of great importance for identifying and localizing defects of rechargeable solid batteries in a noninvasive detection. We demonstrate a microwave-free AC magnetometry method with negatively charged NV centers in diamond based on a cross-relaxation feature between NV centers and individual substitutional nitrogen (P1) centers occurring at 51.2 mT. We apply the technique to non-destructive solid-state battery imaging. By detecting the eddy-current-induced magnetic field of the battery, we distinguish a defect on the external electrode and identify structural anomalies within the battery body. The achieved spatial resolut…
Influence of the pH on the synthesis of reduced graphene oxide under hydrothermal conditions
2012
Here we describe the important role played by the pH on the morphology and structure of the reduced graphite oxide (rGO) samples obtained by hydrothermal treatment of the previously prepared GO. The nature of the resulting samples has been studied on the basis of a complete battery of experimental techniques.
Metal Oxides for Rechargeable Batteries Energy Applications
2020
Nearly three decades of significant academic and commercialization progress, appreciations have to be credited for Li+ ion-based rechargeable secondary batteries, which conquered the entire world. The Li+ ion batteries dictate the consumer battery market and are considered crucial for the practical realization of plug-in hybrid electric vehicles (PHEVs), hybrid electric vehicles (HEVs), and electric vehicles (EVs). Recently, post-lithium–ion batteries, particularly Na, K, Mg, and Zn, and Al–ion batteries have also been intensively explored for various energy storage tenders due to their natural abundance, low cost, and environmental safety of these materials. The utilization of metal oxides…
Electrodes with Immobilized Particles and Droplets: Three-Phase Electrodes
2014
It is a common feature of electrodes with immobilized particles and droplets that three phases are in close contact with each other, i.e., each phase having an interface with the two other phases. This situation exists also in most of the so-called surface-modified or film electrodes, many battery and fuel cell electrodes, electrodes of the second kind, etc. In fact, the majority of surface-modified electrodes consist of arrays of particles that partially cover the electrode surface. It would be far beyond the scope of this book to include all chemical and electrochemical techniques to deposit films on electrodes. Here we shall deal only with electrodes where the particles or droplets have …
Rapid online solid-state battery diagnostics with optically pumped magnetometers
2020
Applied Sciences 10(21), 7864 (2020). doi:10.3390/app10217864
Battery technologies for electric vehicles
2017
This chapter gives a brief overview of the following types of vehicles: battery electric vehicle (BEV), plug-in hybrid electric vehicle (PHEV), and hybrid electric vehicle (HEV). It then provides a comprehensive summary of the electrochemical energy storage including Ni-MH battery, Li-ion battery, and advanced rechargeable battery. Battery chemistry is explained in a detailed manner including an abbreviated modelling approach. Also, the issues of battery-charging method, management, and monitoring are addressed. The chapter concludes with a discussion on battery cell voltage balancing and temperature monitoring in addition to the battery state-of-charge (SOC) estimation.
On the regeneration of thermally regenerative ammonia batteries
2018
In the past few years, thermally regenerative ammonia battery (TRAB) has been proposed as an effective tool to recover waste heat at temperatures below 130 °C. Most of the literature available is devoted to the power production step, with less attention being given to the regeneration step (e.g. the removal of ammonia from the anolyte). In this paper, the TRAB is analyzed with particular attention to the regeneration step and to the study of various generation of energy-regeneration cycles. It was shown that approximately 90 °C is necessary for the regeneration step due to the fact that ammonia is present in the anolyte mainly as a complex. Various cycles were performed with success, demons…
Power Grid Integration and Use-Case Study of Acid-Base Flow Battery Technology
2021
There are many different types of energy storage systems (ESS) available and the functionality that they can provide is extensive. However, each of these solutions come with their own set of drawbacks. The acid-base flow battery (ABFB) technology aims to provide a route to a cheap, clean and safe ESS by means of providing a new kind of energy storage technology based on reversible dissociation of water via bipolar electrodialysis. First, the main characteristics of the ABFB technology are described briefly to highlight its main advantages and drawbacks and define the most-competitive use-case scenarios in which the technology could be applied, as well as analyze the particular characteristi…
Different scenarios of electric mobility: Current situation and possible future developments of fuel cell vehicles in Italy
2020
The diffusion of electric vehicles in Italy has started but some complications weight its spread. At present, hybrid technology is the most followed by users, due particularly to socioeconomic factors such as cost of investment and range anxiety. After a deep discussion of the Italian scenario, the aim of the paper is to recognize whether fuel cell technology may be an enabling solution to overcome pollution problems and respect for the environment. The opportunity to use fuel cells to store electric energy is quite fascinating&mdash