Search results for "Note"
showing 10 items of 10709 documents
Electro-optical characterization of ruthenium-based dye sensitized solar cells: A study of light soaking, ageing and temperature effects
2017
Abstract In this work, we report on the electro-optical characterization of Dye Sensitized Solar Cells (DSSCs) which use ruthenium complexes as sensitizers. In particular, several kinds of measurements have been performed to study the electrical performances and the efficiency levels of the cells at different operating conditions. In detail, the measurements have been conducted at varying temperatures and hours of light soaking. Our results show that the short circuit current density J SC , the open circuit voltage V OC and the conversion efficiency η increase with the hours of light soaking, while they decrease with temperature. A thorough investigation on the light soaking process at the …
One diode circuital model of light soaking phenomena in Dye-Sensitized Solar Cells
2018
Abstract In this work, we report on the modelling of light soaking effect on Ruthenium-based Dye Sensitized Solar cells (DSSCs). Such a phenomenon can be detected when exposing the cells at increasing hours of illumination and produces a reversible performance increase. Starting from the results obtained through the electro-optical characterization of the cells, we applied a one-diode circuital-model. Our results show a good agreement between the experimental and the simulated data, with a mean square error in the order of 10−12 and a maximum error in current lower than 0.6%. Finally such results allowed us to infer some precise trends followed by the cells main electrical parameters and of…
Simultaneous Removal and Recovery of Metal Ions and Dyes from Wastewater through Montmorillonite Clay Mineral
2019
The main objective of this work was to evaluate the potential of Montmorillonite nanoclay (Mt), readily and inexpensively available, for the simultaneous adsorption (and removal) of two classes of pollutants: metal ions and dyes. The attention was focused on two &ldquo
2,3-Dipentyldithieno[3,2-f:2′,3′-h]quinoxaline-Based Organic Dyes for Efficient Dye-Sensitized Solar Cells: Effect of π-Bridges and Electron Donors o…
2015
Five novel metal-free organic dyes DQ1-5 containing a dipentyldithieno[3,2-f:2',3'-h]quinoxaline (DPQ) unit were synthesized and applied in dye-sensitized solar cells (DSSCs), where DPQ was employed as a π-spacer for the first time. Their photophysical, electrochemical, and theoretical calculations and photovoltaic properties were systematically investigated. All the five dyes show broad photoresponse. Especially the absorption edges of DQ3-5 extend to 800 nm on the TiO2 films. The inserted electron-rich unit 3,4-ethylenedioxythiophene or electron-withdrawing group benzothiadiazole (BTD) in DPQ-based dyes can greatly influence the optoelectronic properties of the dyes. In addition, the diff…
Limbažu Dūņezera vides kvalitāte
2018
Limbažu Dūņezers atrodas īpaši aizsargājamā dabas teritorijā – Ziemeļvidzemes biosfēras rezervāta dabas lieguma “Dūņezers” zonā, biosfēras rezervāta ainavu aizsardzības zonas teritorijā un tā ir arī Natura 2000 teritorija. Neskatoties uz to, ezers ir pakļauts būtiskam punktveida piesārņojuma avotam – Limbažu notekūdeņu attīrīšanas iekārtām, un pēc Ministru Kabineta noteikumiem Nr. 418 ir iekļauts riska ūdensobjektu sarakstā. Bakalaura darba mērķis ir veikt ezera fizikāli ķīmiskās analīzes, analizēt iepriekš veiktu monitoringu datus un literatūru, lai saprastu ezerā notiekošos procesus, kuri ietekmē biogēno elementu apriti tajā, papildus ņemot vērā emitēto notekūdeņu apjomu un raksturu.
Estudio de las alteraciones genéticas asociadas con la resistencia al tratamiento neoadjuvante de deprivación estrogénica en cáncer de mama
2021
With current standard of care adjuvant therapy, approximately 25-30% of women with high risk early stage HR+/HER2- breast cancer experience relapse. The preoperative platform offers an opportunity to interrogate mechanisms of drug resistance that, in turn, could inform the choice of adjuvant therapy. We report herein a study where we performed targeted DNA sequencing and whole transcriptome analysis on whole tumor sections from a cohort of 68 operable ER+ breast cancers treated with the aromatase inhibitor letrozole for a median of 7.2 months before surgery, and a with a median follow up of 5 years. We found that resistant tumors were enriched in clinically actionable mutation and showed an…
Monte Carlo simulation of high‐order harmonics generation in bulk semiconductors and submicron structures
2004
To qualify the feasibility of standard semiconductor materials and Schottky‐barrier diodes (SBDs) for THz high‐order harmonic generation and extraction, the harmonic intensity, intrinsic noise and signal‐to‐noise ratio are calculated by the Monte Carlo method when a periodic high‐frequency large‐amplitude external signal is applied to a semiconductor device. Due to very high signal‐to‐noise ratio heavily doped GaAs SBDs are found to exhibit conditions for frequency mixing and harmonic extraction that are definitively superior to those of bulk materials. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
Ligand-Based Charge-Transfer Luminescence in Ionic Cyclometalated Iridium(III) Complexes Bearing a Pyrene-Functionalized Bipyridine Ligand: A Joint T…
2012
Two new heteroleptic iridium(III) complexes [Ir(ppy)(2)(pyr(2)bpy)][PF(6)] ([1a][PF(6)]) and [Ir(dfppy)(2)(pyr(2)bpy)][PF(6)] ([2a][PF(6)]), where Hppy = 2-phenylpyridine, Hdfppy = 2-(3,5-difluorophenyl)pyridine, and pyr(2)bpy = 5,5'-bis(pyren-1-yl)-2,2'-bipyridine, have been synthesized and fully characterized. The single-crystal structures of pyr(2)bpy and the complexes 4{[1a][PF(6)]}·2CH(2)Cl(2)·9H(2)O and [2a][PF(6)]·0.25CH(2)Cl(2)·H(2)O have been determined. The effect of the pyrene substituents on the electronic properties is investigated through a comprehensive photophysical and theoretical study on the two complexes in comparison to reference complexes without substituents on the an…
Temperature and doping dependence of normal state spectral properties in a two-orbital model for ferropnictides
2016
Using a second-order perturbative Green's functions approach we determined the normal state single-particle spectral function $A(\vec{k},\omega)$ employing a minimal effective model for iron-based superconductors. The microscopic model, used before to study magnetic fluctuations and superconducting properties, includes the two effective tight-binding bands proposed by S.Raghu et al. [Phys. Rev. B 77, 220503 (R) (2008)], and intra- and inter-orbital local electronic correlations, related to the Fe-3d orbitals. Here, we focus on the study of normal state electronic properties, in particular the temperature and doping dependence of the total density of states, $A(\omega)$, and of $A(\vec{k},\o…
Editorial for the Proceedings of the 2016 E-MRS Spring Meeting Symposium T - Advanced Materials and Characterization Techniques for Solar Cells III
2016
Abstract This paper contains the editorial of the proceedings of the 2016 E-MRS spring meeting symposium T on “Advanced materials and characterization techniques for solar cells III”.