Search results for "OLS"

Determination of water speciation in hydrous haplogranitic glasses with partial Raman spectra

2020

Abstract We use a mathematical approach to decompose the Raman water band at 3000 cm−1 to 3750 cm−1 into two partial Raman spectra corresponding to the individual Raman activity of the two water species, i.e., molecular water (H2Om) and OH-groups, present in hydrous rhyolitic glasses. The approach is based on a least-squares optimization algorithm and the assumption that the water band can be expressed as a linear combination of two partial Raman spectra. Our model makes no assumptions regarding the shape of the partial Raman spectra. The model input consists of about 700 Raman spectra from hydrous haplogranitic (HPG8) compositions with total water contents from 0.6 to 3.1 wt% and with know…

Steroid Biomarkers Revisited - Improved Source Identification of Faecal Remains in Archaeological Soil Material.

2017

Steroids are used as faecal markers in environmental and in archaeological studies, because they provide insights into ancient agricultural practices and the former presence of animals. Up to now, steroid analyses could only identify and distinguish between herbivore, pig, and human faecal matter and their residues in soils and sediments. We hypothesized that a finer differentiation between faeces of different livestock animals could be achieved when the analyses of several steroids is combined (Δ5-sterols, 5α-stanols, 5β-stanols, epi-5β-stanols, stanones, and bile acids). We therefore reviewed the existing literature on various faecal steroids from livestock and humans and analysed faeces …

Spectropolarimetric evidence for a siphon flow along an emerging magnetic flux tube

2016

©2017 The American Astronomical Society. All rights reserved.We study the dynamics and topology of an emerging magnetic flux concentration using high spatial resolution spectropolarimetric data acquired with the Imaging Magnetograph eXperiment on board the sunrise balloon-borne solar observatory. We obtain the full vector magnetic field and the line of sight (LOS) velocity through inversions of the Fe i line at 525.02 nm with the SPINOR code. The derived vector magnetic field is used to trace magnetic field lines. Two magnetic flux concentrations with different polarities and LOS velocities are found to be connected by a group of arch-shaped magnetic field lines. The positive polarity footp…

Reactive oxygen species formed in aqueous mixtures of secondary organic aerosols and mineral dust influencing cloud chemistry and public health in th…

2017

Mineral dust and secondary organic aerosols (SOA) account for a major fraction of atmospheric particulate matter, affecting climate, air quality and public health. How mineral dust interacts with SOA to influence cloud chemistry and public health, however, is not well understood. Here, we investigated the formation of reactive oxygen species (ROS), which are key species of atmospheric and physiological chemistry, in aqueous mixtures of SOA and mineral dust by applying electron paramagnetic resonance (EPR) spectrometry in combination with a spin-trapping technique, liquid chromatography-tandem mass spectrometry (LC-MS/MS), and a kinetic model. We found that substantial amounts of ROS includi…

Titan's surface albedo variations over a Titan season from near-infrared CFHT/FTS spectra

2006

International audience; We have observed Titan in a series of campaigns from 1991 to 1996 with the Fourier Transform Spectrometer on the CFH telescope. The data acquired provide a lightcurve from the geometric albedos in the 0.9–View the MathML source spectral region. The 1991–1993 data were previously analyzed in Coustenis et al. [1995. Titan's surface: composition and variability from its near-infrared albedo. Icarus 118, 87–104] with a spherical particle code by McKay et al. [1989. The thermal structure of Titan's atmosphere. Icarus 80, 23–53]. We present here three new datasets from the 1994, 1995 and 1996 observations, with additional information from the 0.94-μm methane window on Tita…

High‐resolution stimulated Raman spectroscopy and analysis of line positions and assignments for the ν 2 and ν 3 bands of 13 C 2 H 4

2016

High-resolution stimulated Raman spectra of13C2H4 in the regions of the ν2 and ν3 Raman active modes have been recorded at two temperatures (145 and 296 K) based on the quasi continuous-wave (cw) stimulated Raman spectrometer at Instituto de Estructura de la Materia IEM-CSIC in Madrid. A tensorial formalism adapted to X2Y4 planar asymmetric tops with D2h symmetry (developed in Dijon) and a program suite called D2hTDS (now part of the XTDS/SPVIEW spectroscopic software) were proposed to analyze and calculate the high-resolution spectra. A total of 103 and 51 lines corresponding to ν2 and ν3 Raman active modes have been assigned and fitted in wavenumber with a global root mean square deviatio…

2019

Abstract. The flow of fluids through porous media such as groundwater flow or magma migration is a key process in geological sciences. Flow is controlled by the permeability of the rock; thus, an accurate determination and prediction of its value is of crucial importance. For this reason, permeability has been measured across different scales. As laboratory measurements exhibit a range of limitations, the numerical prediction of permeability at conditions where laboratory experiments struggle has become an important method to complement laboratory approaches. At high resolutions, this prediction becomes computationally very expensive, which makes it crucial to develop methods that maximize …

Measuring the electron temperatures of coronal mass ejections with future space-based multi-channel coronagraphs: a numerical test

2018

Context. The determination from coronagraphic observations of physical parameters of the plasma embedded in coronal mass ejections (CMEs) is of crucial importance for our understanding of the origin and evolution of these phenomena. Aims. The aim of this work is to perform the first ever numerical simulations of a CME as it will be observed by future two-channel (visible light VL and UV Ly-α) coronagraphs, such as the Metis instrument on-board ESA-Solar Orbiter mission, or any other future coronagraphs with the same spectral band-passes. These simulations are then used to test and optimize the plasma diagnostic techniques to be applied to future observations of CMEs. Methods. The CME diagno…

Line parameters and shapes of high clusters: R-branch of the nu3 band of CH4 in He mixtures

2002

International audience; The IR absorption spectra of CH4 in pure gas and in mixture with helium were studied in the region of nu3 band at higher J line clusters R(17)-R(22). The frequencies and intensities of rotation-vibration lines were estimated from the experimental spectra at Doppler shape conditions. The line frequencies and intensities were calculated and used for the attribution of overlapped lines in clusters. The calculated line intensities are close to the experimental values. The calculated frequency structure of the higher J manifolds are somewhat wider than the observed one. The shapes of helium-broadened line clusters were compared with those calculated accounting for line mi…

Predicting year of plantation with hyperspectral and lidar data

2017

This paper introduces a methodology for predicting the year of plantation (YOP) from remote sensing data. The application has important implications in forestry management and inventorying. We exploit hyperspectral and LiDAR data in combination with state-of-the-art machine learning classifiers. In particular, we present a complete processing chain to extract spectral, textural and morphological features from both sensory data. Features are then combined and fed a Gaussian Process Classifier (GPC) trained to predict YOP in a forest area in North Carolina (US). The GPC algorithm provides accurate YOP estimates, reports spatially explicit maps and associated confidence maps, and provides sens…