Search results for "OPTICS"
showing 10 items of 10033 documents
Noncovalent axial I∙∙∙Pt∙∙∙I interactions in platinum(II) complexes strengthen in the excited state
2021
Abstract Coordination compounds of platinum(II) participate in various noncovalent axial interactions involving metal center. Weakly bound axial ligands can be electrophilic or nucleophilic; however, interactions with nucleophiles are compromised by electron density clashing. Consequently, simultaneous axial interaction of platinum(II) with two nucleophilic ligands is almost unprecedented. Herein, we report structural and computational study of a platinum(II) complex possessing such intramolecular noncovalent I⋅⋅⋅Pt⋅⋅⋅I interactions. Structural analysis indicates that the two iodine atoms approach the platinum(II) center in a “side‐on” fashion and act as nucleophilic ligands. According to c…
High-resolution laser spectroscopy of long-lived plutonium isotopes
2017
Long-lived isotopes of plutonium were studied using two complementary techniques, high-resolution resonance ionisation spectroscopy (HR-RIS) and collinear laser spectroscopy (CLS). Isotope shifts have been measured on the $5f^67s^2\ ^7F_0 \rightarrow 5f^56d^27s\ (J=1)$ and $5f^67s^2\ ^7F_1 \rightarrow 5f^67s7p\ (J=2)$ atomic transitions using the HR-RIS method and the hyperfine factors have been extracted for the odd mass nuclei $^{239,241}$Pu. Collinear laser spectroscopy was performed on the $5f^67s\ ^8F_{1/2} \rightarrow J=1/2\; (27523.61\text{cm}^{-1})$ ionic transition with the hyperfine $A$ factors measured for $^{239}$Pu. Changes in mean-squared charge radii have been extracted and s…
Active lighting applied to three-dimensional reconstruction of specular metallic surfaces by polarization imaging
2006
International audience; In the field of industrial vision, the three-dimensional inspection of highly reflective metallic objects is still a delicate task. We deal with a new automated three-dimensional inspection system based on polarization analysis. We first present an extension of the shape-from-polarization method for dielectric surfaces to metallic surfaces. Then, we describe what we believe to be a new way of solving the ambiguity concerning the normal orientation with an active lighting system. Finally, applications to shape-defect detection are discussed, and the efficiency of the system to discriminate defects on specular metallic objects made by stamping and polishing is presente…
Analysis of FBG reflection spectra under uniform and non-uniform transverse loads
2019
Loads applied transversely on the external surface of waveguides change their circular cross-sectional geometry generating birefringence. Due to this effect the reflected spectrum of a Fibre Bragg grating (FBG) undergoes a splitting of the single peak of the Bragg wavelength. In this work, we employed the Transfer Matrix Method (TMM) for x- and y-polarized wave-modes to model the uniform FBG reflection spectra for uniform and non-uniform transverse loads. We also performed experimental measurements for two different transverse load scenarios. The load profiles chosen for these experiments were applied on the FBG sensor through a block of steel and a roll bearing pin. Then, the modelled and …
Orbital angular momentum parton distributions in quark models
1999
At the low energy, {\sl hadronic}, scale we calculate Orbital Angular Momentum (OAM) twist-two parton distributions for the relativistic MIT bag model and for non-relativistic quark models. We reach the scale of the data by leading order evolution in perturbative QCD. We confirm that the contribution of quarks and gluons OAM to the nucleon spin grows with $Q^2$, and it can be relevant at the experimental scale, even if it is negligible at the hadronic scale, irrespective of the model used. The sign and shape of the quark OAM distribution at high $Q^2$ may depend strongly on the relative size of the OAM and spin distributions at the hadronic scale. Sizeable quark OAM distributions at the had…
Effect of Er3+-doping on 65GeS2-25Ga2S3-10CsCl glass probed by annihilating positrons
2019
Abstract Effect of Er3+-doping resulting in pronounced mid-IR fluorescence functionality was examined first in chalcohalide 65GeS2-25Ga2S3-10CsCl glass using positron annihilation lifetime (PAL) spectroscopy. The detected PAL spectra were reconstructed from unconstrained x2-term analysis employing two-state simple trapping model for one kind of positron trapping free-volume defects, the parameterization being performed at the example of 65GeS2-25Ga2S3-10CsCl glass doped with 0.6 at. % of Er3+. The observed decrease in positron trapping rate was proved to be primary void-evolution process in this Er-activated glass, like in many other chalcogenide glasses affected by rare earth doping. The n…
A Statistical Approach for A-Posteriori Deployment of Microclimate Sensors in Museums: A Case Study
2022
[EN] The deployment of sensors is the first issue encountered when microclimate monitoring is planned in spaces devoted to the conservation of artworks. Sometimes, the first decision regarding the position of sensors may not be suitable for characterising the microclimate close to climate sensitive artworks or should be revised in light of new circumstances. This paper fits into this context by proposing a rational approach for a posteriori deployment of microclimate sensors in museums where long-term temperature and relative humidity observations were available (here, the Rosenborg Castle, Copenhagen, Denmark). Different statistical tools such as box-and-whisker plots, principal component …
Rayleigh-instability-driven dewetting of thin Au and Ag films on indium-tin-oxide surface under nanosecond laser irradiations
2013
Investigations have been carried out on laser-beam-induced nanoparticle (NP) formation in thin (5 nm) Au and Ag films on indium-tin-oxide substrate. After the irradiation the films were observed to break-up into NPs through a dewetting mechanism. This mechanism was investigated as a Rayleigh-instability- driven process. In fact, for each used laser fluence, the resulting Au and Ag NPs' mean size and surface-to-surface mean distance were quantified and correlated between them in the framework of the Rayleigh-instability theory showing an excellent agreement. © The Institution of Engineering and Technology 2013.
Selective writing and read-out of a register of static qubits
2013
We propose a setup comprising an arbitrarily large array of static qubits (SQs), which interact with a flying qubit (FQ). The SQs work as a quantum register, which can be written or read-out by means of the FQ through quantum state transfer (QST). The entire system, including the FQ's motional degrees of freedom, behaves quantum mechanically. We demonstrate a strategy allowing for selective QST between the FQ and a single SQ chosen from the register. This is achieved through a perfect mirror located beyond the SQs and suitable modulation of the inter-SQ distances.
Experimental Engineering of Arbitrary Qudit States with Discrete-Time Quantum Walks
2019
The capability to generate and manipulate quantum states in high-dimensional Hilbert spaces is a crucial step for the development of quantum technologies, from quantum communication to quantum computation. One-dimensional quantum walk dynamics represents a valid tool in the task of engineering arbitrary quantum states. Here we affirm such potential in a linear-optics platform that realizes discrete-time quantum walks in the orbital angular momentum degree of freedom of photons. Different classes of relevant qudit states in a six-dimensional space are prepared and measured, confirming the feasibility of the protocol. Our results represent a further investigation of quantum walk dynamics in p…