Search results for "Observable"
showing 10 items of 634 documents
From nuclei to micro-structure in colloidal crystallization: Investigating intermediate length scales by small angle laser light scattering.
2014
Hard sphere suspensions are well recognized model systems of statistical physics and soft condensed matter. We here investigate the temporal evolution of the immediate environment of nucleating and growing crystals and/or their global scale distribution using time resolved Small Angle Light Scattering (SALS). Simultaneously performed Bragg scattering (BS) measurements provide an accurate temporal gauging of the sequence of events. We apply this approach to studies of re-crystallization in several different shear molten hard sphere and attractive hard sphere samples with the focus being on the diversity of observable signal shapes and their change in time. We demonstrate that depending on th…
Nonmonotone Saturation Profiles for Hydrostatic Equilibrium in Homogeneous Porous Media
2012
Nonmonotonic saturation profiles (saturation overshoot) occur as travelling waves in gravity driven fingering. They seem important for preferential flow mechanisms and have found much attention recently. Here, we predict them even for hydrostatic equilibrium when all velocities vanish. We suggest that hysteresis suffices to explain the effect. Recently, the observation of nonmonotonicity of traveling wave solutions for saturation profiles during constant-flux infiltration experiments has highlighted the shortcomings of the traditional, seventy year old mathematical model for immiscible displacement in porous media. Several recent modifications have been proposed to explain these observation…
Observable Quantities for Electrodiffusion Processes in Membranes
2008
Electrically driven ion transport processes in a membrane system are analyzed in terms of observable quantities, such as the apparent volume flow, the time dependence of the electrolyte concentration in one cell compartment, and the electrical potential difference between the electrodes. The relations between the fluxes and these observable quantities are rigorously deduced from balances for constituent mass and solution volume. These relations improve the results for the transport coefficients up to 25% with respect to those obtained using simplified expressions common in the literature. Given the practical importance of ionic transport numbers and the solvent transference number in the ph…
THE ROLE OF SUNK COSTS IN THE DECISION TO INVEST IN R&D
2009
We present a dynamic empirical model of a firm's R&D decisions that is consistent with the existence of sunk R&D costs, taking into account that these costs may differ between small and large firms, and among different technological regimes. We estimate a multivariate dynamic discrete choice model using firm-level data of Spanish manufacturing for 1990–2000. Conditional on firm heterogeneity and serially correlated unobservable factors, we find that R&D history matters. This true state dependence allows inferring the existence of sunk R&D costs associated with performing R&D. Sunk R&D costs are found to be higher for large, high-tech firms.
Statistics of reversible transitions in two-state trajectories in force-ramp spectroscopy
2014
A possible way to extract information about the reversible dissociation of a molecular adhesion bond from force fluctuations observed in force ramp experiments is discussed. For small loading rates the system undergoes a limited number of unbinding and rebinding transitions observable in the so-called force versus extension (FE) curves. The statistics of these transient fluctuations can be utilized to estimate the parameters for the rebinding rate. This is relevant in the experimentally important situation where the direct observation of the reversed FE-curves is hampered, e.g. due to the presence of soft linkers. I generalize the stochastic theory of the kinetics in two-state models to the…
Hyperpolarized 1H long lived states originating from parahydrogen accessed by rf irradiation
2013
Hyperpolarization has found many applications in Nuclear Magnetic Resonance (NMR) and Magnetic Resonance Imaging (MRI). However, its usage is still limited to the observation of relatively fast processes because of its short lifetimes. This issue can be circumvented by storing the hyperpolarization in a slowly relaxing singlet state. Symmetrical molecules hyperpolarized by Parahydrogen Induced Hyperpolarization (PHIP) provide a straightforward access to hyperpolarized singlet states because the initial parahydrogen singlet state is preserved at almost any magnetic field strength. In these systems, which show a remarkably long 1H singlet state lifetime of several minutes, the conversion of t…
Single-layer metal-on-metal islands driven by strong time-dependent forces
2012
Non-linear transport properties of single-layer metal-on-metal islands driven with strong static and time-dependent forces are studied. We apply a semi-empirical lattice model and use master equation and kinetic Monte Carlo simulation methods to compute observables such as the velocity and the diffusion coefficient. Two types of time-dependent driving are considered: a pulsed rotated field and an alternating field with a zero net force (electrophoretic ratchet). Small islands up to 12 atoms were studied in detail with the master equation method and larger ones with simulations. Results are presented mainly for a parametrization of Cu on Cu(001) surface, which has been the main system of int…
Fluorescence Lifetime of a Single Molecule as an Observable of Meta-Basin Dynamics in Fluids Near the Glass Transition
2006
Using single molecule spectroscopy, we show that the fluorescence lifetime trajectories of single probe molecules embedded in a glass-forming polymer melt exhibit strong fluctuations of a hopping character. Using molecular dynamics simulations targeted to explain these experimental observations, we show that the lifetime fluctuations correlate strongly with the average square displacement function of the matrix particles. The latter observable is a direct probe of the meta-basin transitions in the potential energy landscape of glass-forming liquids. We thus show here that single molecule experiments can provide detailed microscopic information on system properties that hitherto have been ac…
Complete Measurement of the Λ Electromagnetic Form Factors.
2019
The exclusive process e+e−→ΛΛ¯, with Λ→pπ− and Λ¯→p¯π+, has been studied at s=2.396 GeV for measurement of the timelike Λ electric and magnetic form factors, GE and GM. A data sample, corresponding to an integrated luminosity of 66.9 pb−1, was collected with the BESIII detector for this purpose. A multidimensional analysis with a complete decomposition of the spin structure of the reaction enables a determination of the modulus of the ratio R=|GE/GM| and, for the first time for any baryon, the relative phase ΔΦ=ΦE−ΦM. The resulting values are R=0.96±0.14(stat)±0.02(syst) and ΔΦ=37°±12°(stat)±6°(syst), respectively. These are obtained using the recently established and most precise value of …
Second harmonic generation and beam cleaning in optically poled multimode graded-index fibers
2017
Recent experimental results have confirmed that nonlinear effects in multimode graded-index (MM-GRIN) fibers lead to a wealth of observable spatiotemporal effects. In spite of the large number of modes supported by the fiber, by increasing the input power the transverse profile evolves in a clean bell-shaped beam [1, 2]. Next, the input laser line experiences a strong spectral broadening and Geometric Parametric Instability (GPl) peaks are observed [3].