Search results for "Oct"
showing 10 items of 3052 documents
Synthesis of and structural studies on lead(II) cysteamin complexes.
2004
The novel compounds PbCl(2).(SCH(2)CH(2)NH(3)) (1), Pb(SCH(2)CH(2)NH(2))(2).2PbCl(SCH(2)CH(2)NH(2)) (2), and Pb(SCH(2)CH(2)NH(2))(2) (3) were synthesized by reaction of PbO or PbCl(2) with [HSCH(2)CH(2)NH(3)]Cl and NaOH, and were characterized by elemental analysis, IR-, and UV/vis-spectroscopy. Single-crystal X-ray diffraction revealed different coordination modes for the two Pb atoms in 2. The Pb atom in the Pb(SCH(2)CH(2)NH(2))(2) unit forms two covalent Pb-S and two intramolecular dative Pb...N bonds, leading to a pseudo trigonal bipyramidal configuration with a stereochemically active lone pair. The Pb atom in the PbCl(SCH(2)CH(2)NH(2)) unit, the first moiety structurally characterized…
Local structure and lattice dynamics of cubic Y2O3: an x-ray absorption spectroscopy study
2015
Classical molecular dynamics was used to interpret the temperature dependent (300-1273 K) Y K-edge x-ray absorption spectra of cubic c-Y2O3 and to validate two force-field models. It was shown that both models reproduce well thermal disorder effect, however are less accurate in description of static octahedra distortion around yttrium atoms. The temperature dependencies of mean-square displacements and mean-square relative displacements were obtained from molecular dynamics simulations for the first two shells of yttrium. The importance of anharmonic effects was demonstrated by comparison of molecular dynamics and lattice dynamics results.
A Bis(diazadiene) Adduct of MoCl 2 : Mononuclear, Octahedral, Undistorted and Diamagnetic
2004
The complex [MoCl2(iPr2dad)2] (iPr2dad = iPrN=CH−CH=N−iPr) is obtained in one step by reduction of [MoCl3(THF)3] in the presence of iPr2dad. The X-ray structure reveals a relatively undistorted octahedral coordination geometry with a relative cis configuration and points to a more appropriate description of the ligands as enediamides. The NMR investigation is in agreement with the same cis structure in solution and underlines the diamagnetism of the compound, at odds with previously reported very similar complexes. A bulk magnetic susceptibility measurement further confirms the compound’s diamagnetism. No equilibrium with a dinuclear, metal-metal bonded species is apparent from the solution…
La Méthode como hermenéutica musical Homenaje a Edgar Morin por su 100º cumpleaños
2021
The present work addresses the principles and properties of the complex thought formulated by the French thinker Edgar Morin and the way in which he was able me to articulate his conception of organizational complexity with one of the most important theories of musical analysis, which emerged at the beginning of the 20th century: the schenkerian analysis. It is a review and extension of a few pages of my doctoral thesis, which are intended to pay tribute to who has been, in addition to my teacher, Honorary President of Itamar since its first issue. His teachings and support has always been the engine for my quest for musical organization. On July 21, 2021, Morin celebrated his 100th birthda…
NEURODEGENERATION IN MULTIPLE SCLEROSIS: COMPARISON BETWEEN CLINICAL, NEUROPSYCHOLOGICAL, MRI,AND OPTICAL COHERENCE TOMOGRAPHY PARAMETERS
2015
BACKGROUND AND OBJECTIVE Optical Coherence Tomography (OCT) enables rapid, non-invasive in vivo measurement of retinal nerve fiber layer (RNFL) thickness, reflecting axonal density within the optic nerve. There is still lack of concordance about the use of OCT in clinical routine as a surrogate measure of brain atrophy. Objective: To investigate the role of OCT as possible predictor of disability, cognitive impairment and neurodegeneration in Multiple Sclerosis (MS). MATERIAL AND METHODS We recruited patients affected by MS according to validated criteria at the Neurological Department of the University of Palermo. Patients performed Stratus OCT- 3 Zeiss to assess RNFL and GCS measurements.…
Comunicación y conocimiento
2005
Ponencia de José Vidal-Beneyto en el "II Encuentro Internacional Complutense Ciencia y Sociedad: Globalización, pobreza y desarrollo. Los retos de la cooperación internacional" (IUDC - UCM, 15-17.11.2004).
Los museos etnológicos como instrumentos de formación ciudadana para hacer frente a los problemas que la humanidad tiene planteados
2017
Desde hace algunas décadas se viene llamando la atención desde diferentes ámbitos acerca de la insostenible situación de auténtica emergencia socioambiental planetaria en la que estamos inmersos y de la necesidad de contribuir a la formación de una ciudadanía consciente de dicha situación y preparada para participar en la toma de decisiones fundamentadas para hacer frente a la misma. Esta investigación responde a los llamamientos por Naciones Unidas a los educadores de todos los niveles, áreas y contextos, tanto de la educación formal como de la no reglada, con ese propósito de convertir la educación para la Sostenibilidad en una componente fundamental de la formación ciudadana. El objeto d…
Biogeneration of 1-octen-3-ol by lipoxygenase and hydroperoxide lyase activities of Agaricus bisporus
2001
Abstract The biogeneration of 1-octen-3-ol by lipoxygenase and associated hydroperoxide lyase activities of a homogenate of the cultivated mushroom Agaricus bisporus was investigated using linoleic acid as a substrate. The optimal substrate and protein concentrations were 1.5 mM and 1.5 mg ml −1 , respectively. The V max value for the enzymic coupled reaction lipoxygenase–hydroperoxide lyase was 6 μg of 1-octen-3-ol ml −1 min −1 , with a K m value of 0.3×10 −3 M. The highest enzymic activity was observed in the presence of pure oxygen (22.9 μg of 1-octen-3-ol ml −1 ), with a bioconversion yield of 36%. The production of 380 μg 1-octen-3-ol per g of mushroom homogenate was demonstrated using…
High myopic patients with and without foveoschisis: morphological and functional characteristics.
2020
Purpose: Myopic foveoschisis (MF) is characterized by the splitting of the retinal layers in the fovea of patients with high myopia (HM). MF may progress into foveal detachment or macular hole formation with consequent loss of central vision. The aim of this study is to investigate morphological and functional changes of the macular region in myopic subjects with and without foveoschisis. Design: Observational, cross-sectional, comparative study. Methods: Forty-eight patients with HM and 24 healthy controls were evaluated by spectral domain-optical coherence tomography (SD-OCT), multifocal electroretinography (mfERG) and microperimetry (MP-1) tests to assess macular thickness, functionality…
CCDC 781923: Experimental Crystal Structure Determination
2011
Related Article: K.Helttunen, E.Nauha, A.Kurronen, P.Shahgaldian, M.Nissinen|2011|Org.Biomol.Chem.|9|906|doi:10.1039/c0ob00602e