Search results for "One-Step"
showing 10 items of 37 documents
One step continuous hydrothermal synthesis of very fine stabilized superparamagnetic nanoparticles of magnetite
2011
International audience; Stable suspensions of citrated SPIO nanoparticles were synthesised in one step using a hydrothermal continuous process. Citrates control the crystallite size and the oxidation degree of metallic ions despite the very short reaction time (4 s). Magnetite particles, Fe2.94O4, with an average size of 4 nm and good monodispersity were obtained.
TEM morphological characterization of a one-step self-etching system applied clinically to human caries-affected dentin and deep sound dentin
2013
Purpose: To examine morphologically the hybrid layer of one-step self-etching adhesive, Clearfil S3 Bond (S3bond), in caries-affected dentin (CAD) and deep sound dentin (DSD) cavities performed clinically. For a comparative group, the two-step self etching adhesive Clearfil Protect Bond (Pbond) was used in a similar clinical situation. Methods: This study was carried out on carious and sound teeth clinically selected for extraction. In carious teeth, CAD was obtained by way of subjective criteria by removing infected tissue to form a cavity bottom. DSD was obtained at a depth of 4 mm in the dentin cavity of sound teeth. S3bond and Pbond were applied in the CAD and DSD cavities as indicated …
Durability of solvent-free one-step self-etch adhesive under simulated intrapulpal pressure
2015
Background: There are different solvents presented in simplified adhesives. Bond-1 SF has been developed, which contains neither water nor organic solvents, in order to eliminate technical issues in terms of evaporation of solvents and concerns for the durability of resin-dentin bond. Thus this study was conducted to evaluate the microtensile bond strength (μTBS) of solvent-free and ethanol-based one-step self-etch adhesives to dentin under simulated intrapulpal pressure (IPP). Material and Methods: Occlusal surfaces of human molars were prepared to expose mid-dentin depth. Bond-1SF Solvent-Free SE [SF] and Adper TM easy one [AE] adhesives were applied on dentin specimens. Resin composite b…
One-step reactive processing of low density polyethylene and octavinyl polyhedral oligomeric silsesquioxane
2015
Polyhedral oligomeric silsesquioxane (POSS) are an innovative class of organosilicon compounds suitable for formulation of advanced organic-inorganic hybrid materials. Nanocomposites based POSS found application mostly in high-temperature resistance and fire-resistance materials. POSS are characterized by a three dimensional cage-like structure, made of Si-O bonds, with different organic groups directly linked to the Si atoms of the cage structure. The organic groups can be designed to facilitate the dispersion of the nanoparticle itself in the polymer matrix or also to react with the polymer chain. This work focuses on the possibility to obtain crosslinking of polyethylene using octavinyl-…
Structural Signatures of Type IV Isotherm Steps: Sorption of Trichloroethene, Tetrachloroethene, and Benzene in Silicalite-I
2002
We have investigated by in situ neutron diffraction the structural properties of C2HCl3, C2Cl4, and C6D6 sorbed phases in silicalite-1. Our motivation is to correlate the structure of these three confined species to the fact that their adsorption isotherms are characterized by no step, one step, and two steps, respectively. From our detailed neutron diffraction investigation, we deduce that the adsorption isotherm steps are not signatures of phase transitions but are correlated to the different adsorption stages observed during the silicalite-1 loading. For C6D6, such a loading is a three stage process (the C6D6 molecules fill successively, the intersections, then the straight channels and …
Spinovo rozlisena time-of-flight k-reozlisena fotoemissia Ir-- Kompletny fotoemissny experiment.
2017
Ultramicroscopy 183, 19 - 29 (2017). doi:10.1016/j.ultramic.2017.06.025
Gamma rays induced synthesis of graphene oxide/gold nanoparticle composites: structural and photothermal study
2022
Gamma irradiation provides an alternative pathway to conventional gold nanoparticle synthesis because it is simple, fast, and economical. Here, we employed gamma irradiation at low doses (1–20 kGy) to obtain gold nanoparticles (Au NPs) anchored onto graphene oxide (GO) sheets. GO was selected as a suitable platform for the nucleation and growth of Au NPs because of its large surface area and good dispersibility in water due to the presence of polar oxygen-containing functional groups in its structure. Gamma irradiation at all the applied doses led to the reduction of chloroauric acid and the formation of evenly distributed Au NPs at the GO surface, simultaneously causing the reduction of GO…
Two- and one-step cooperative spin transitions in Hofmann-like clathrates with enhanced loading capacity
2014
Structural, magnetic, calorimetric and Mo¨ssbauer studies of the cooperative spin crossover naphthalene and nitrobenzene clathrates of the novel FeII Hofmann-like porous metal–organic framework {Fe(bpb)[Pt(CN)4]}2Guest are described (bpb = bis(4-pyridyl)butadiyne).
A facile chemoenzymatic approach: one-step syntheses of monoterpenoid indole alkaloids.
2010
Facile chemoenzymatic syntheses of cytotoxic monoterpenoid indole alkaloids with novel skeletons and multiple chiral centers are described. Synthesis of these alkaloids was achieved by a simple one-step reaction using strictosidine and 12-aza-strictosidine as the key intermediates. Strictosidines were prepared by coupling of secologanin with tryptamine and 7-aza-tryptamine, respectively, using the immobilized recombinant Rauvolfia strictosidine synthase. A detailed stereochemical analysis is presented herein. The results provide an opportunity for a chemoenzymatic approach that leads to an increased diversification of complex alkaloids with improved structures and activities.
Shear bond strength of one-step self-etch adhesives to dentin: Evaluation of NaOCl pretreatment
2018
Background The aim of this study was to evaluate the influence of dentin pretreatment with NaOCl on shear bond strength of four one-step self-etch adhesives with different pH values. Material and methods Bovine permanent incisors were used. Four one-step self-etch adhesives were tested: Adper™ Easy Bond, Futurabond NR, G-aenial Bond, Clearfil S3 Bond. One two-step self-etch adhesive (Clearfil SE Bond) was used as control. Group 1- no pretreatment; group 2- pretratment with 5,25 % NaOCl; group 3- pretreatment with 37 % H3PO4 etching and 5,25 % NaOCl. A hybrid composite resin was inserted into the dentin surface. The specimens were tested in a universal testing machine. The examiners evaluate…