Search results for "Optical Spectroscopy"
showing 10 items of 31 documents
Role of diffusing molecular hydrogen on relaxation processes in Ge-doped glass
2007
Temperature dependencies of steady-state and time-resolved photoluminescence (PL) from triplet state at 3.1 eV and singlet state at 4.2 eV ascribed to the twofold-coordinated Ge have been measured in unloaded and H2-loaded Ge-doped silica samples under 5.0 eV excitation in the 10–310 K range. Experimental evidences indicate that diffusing molecular hydrogen (H2) depopulates by a collisional mechanism the triplet state, decreasing both its lifetime of about 14% and the associated triplet PL intensity, whereas those of the singlet are insensitive to the presence of H2.
Conformational heterogeneity of the point defects in silica: The lifetime of the phosphorescence band at 2.7 eV
2008
We have measured the excitation and emission energy dependence of the lifetimes of the 2.7 eV photoluminescence band associated to oxygen deficient centers in silica glasses. The non-exponential behavior of this time decay is consistent with intrinsic conformational heterogeneity of these point defects in the amorphous matrix. Accordingly, we have analyzed the data in terms of a radiative rates distribution. Moreover, both surface and bulk typologies of these point defects have been studied. The mean value of the lifetime distribution of the surface defects increases from 12 to 15 ms varying the excitation energy from 4.6 to 5.2 eV, and it increases from 14 to 15 ms in the emission energy i…
Luminescence and absorption spectroscopy of Sn-related impurity centers in silica
2006
We report an experimental study on the absorption and luminescence spectra of oxygen deficient point defects in Sn-doped silica. The absorption band at 4.9 eV (B2β band) and the two related photoluminescence bands at ∼4.2 eV (singlet-singlet emission, S1 → S0) and at ∼3.2 eV (triplet-singlet emission, T1 → S0), linked by a thermally activated T1 → S1 inter-system crossing process (ISC), are studied as a function of temperature from 300 to 20 K. This approach allows us to investigate the dynamics properties of the matrix in the surroundings of the point defects and the effects of local disorder on the two relaxation processes from S1: the radiative channel to S0 and the ISC process to T1. We…
Generation of oxygen deficient point defects in silica by γ and β irradiation
2007
We report an experimental study of the effects of y and β irradiation on the generation of a point defect known as ODC(II) in various types of commercial silica (a-SiO 2 ). The ODC(II) has been detected by means of photoluminescence (PL) spectroscopy measuring the PL band centered at 4.4 eV and excited at 5.0 eV associated to this defect. Our experiments show that ODC(II) are induced in all the investigated materials after irradiation at doses higher than 5 x 10 2 kGy. A good agreement is observed between the efficiencies of generation of ODC(II) under y and β irradiation, enabling a comprehensive study up to the dose of 5 x 10 6 kGy. Two different growth rates, one in the low and one in th…
Far-infrared laser on quantum dots created by electric-field focusing
2003
The new proposal of a far-infrared laser employing intraband transitions in the system of quantum dots is briefly described. The conditions for inversion of population for electrons in the quantum dot matrix created by an electric-field focusing in narrow GaAs/AlGaAs quantum well are discussed. The laser is planned to be pumped by periodically repeated rapid creation and destruction of the quantum dot matrix allowing for repeated filling of the dot levels with electrons from a quantum well. Some major results of the analysis of the kinetics of the electron-photon system are presented.
Resonant laser spectroscopy of localized excitons in monolayer WSe_2
2016
Coherent quantum control and resonance fluorescence of few-level quantum systems is integral for quantum technologies. Here we perform resonance and near-resonance excitation of three-dimensionally confined excitons in monolayer WSe2 to reveal near-ideal single-photon fluorescence with count rates up to 3 MHz. Using high-resolution photoluminescence excitation spectroscopy of the localized excitons, we uncover a weakly fluorescent exciton state ∼5 meV blue shifted from the ground-state exciton, providing important information to unravel the precise nature of quantum states. Successful demonstration of resonance fluorescence paves the way to probe the localized exciton coherence in two-dime…
Indoor spectroradiometric characterization of plastic litters commonly polluting the Mediterranean Sea: toward the application of multispectral image…
2020
AbstractAround 350 million tonnes of plastics are annually produced worldwide. A remarkable percentage of these products is dispersed in the environment, finally reaching and dispersed in the marine environment. Recent field surveys detected microplastics’ concentrations in the Mediterranean Sea. The most commonly polymers found were polyethylene, polypropylene and viscose, ethylene vinyl acetate and polystyrene. In general, the in-situ monitoring of microplastic pollution is difficult and time consuming. The main goals of this work were to spectrally characterize the most commonly polymers and to quantify their spectral separability that may allow to determine optimal band combinations for…
Protein dynamics: conformational disorder, vibrational coupling and anharmonicity in deoxy-hemoglobin and myoglobin.
1993
In this work we study the temperature dependence of the Soret band lineshape of deoxymyoglobin and deoxyhemoglobin, in the range 300-20 K. To fit the measured spectra we use an approach originally proposed by Champion and coworkers (Srajer et al. 1986; Srajer and Champion 1991). The band profile is modelled as a Voigt function that accounts for the coupling with low frequency vibrational modes, whereas the coupling with high frequency modes is responsible for the vibronic structure of the spectra. Moreover, owing to the position of the iron atom out of the mean heme plane, inhomogeneous broadening brings about a non-Gaussian distribution of 0-0 electronic transition frequencies. The reporte…
Radiation-induced defects in fluorine-doped silica-based optical fibers: Influence of a pre-loading with H2
2009
International audience; We investigated the effects of 10-keV X-ray radiation on the transmission properties of F-doped optical fibers in the 200–850 nm range of wavelengths (1.5–6 eV). We also studied the influence of pre-loading this kind of fibers with hydrogen on its radiation sensitivity. Our results showed that, for our experimental conditions (pre-treatment with H2 several months before irradiation with diffusion of all the H2 out the fiber core and cladding before X-ray exposure), this pre-treatment increases the radiation-induced attenuation in the ultraviolet part (200–300 nm) of the spectrum. A previous H2-loading has no influence at greater wavelengths. The nature of the radiati…
Origin of the large spectral shift in electroluminescence in a blue light emitting cationic iridium(III) complex
2007
A new, but archetypal compound [ Ir( ppy- F-2) (2)Me(4)phen] PF6, where ppy- F2 is 2-(2',4'- fluorophenyl) pyridine and Me(4)phen is 3,4,7,8- tetramethyl- 1,10- phenanthroline, was synthesized and used to prepare a solid-state light-emitting electrochemical cell (LEEC). This complex emits blue light with a maximum at 476 nm when photoexcited in a thin film, with a photoluminescence quantum yield of 52%. It yields an efficient single-component solid-state electroluminescence device with a current efficiency reaching 5.5 cd A(-1) and a maximum power efficiency of 5.8 Lm Watt(-1). However, the electroluminescence spectrum is shifted with respect to the photoluminescence spectrum by 80 nm resul…