Search results for "Orbit"

X-Ray structure, Hirshfeld analysis and DFT studies of two new hits of triazolyl-indole bearing alkylsulfanyl moieties

2021

Two new hits of triazolyl-indole containing two different alkylsulfanyl analogues named tert-butyl 2-((4-amino-5-(1H-indol-2-yl)-4H-1,2,4-triazol-3-yl)thio)acetate 2, and ethyl 2-((4-amino-5-(1H-indol-2-yl)-4H-1,2,4-triazol-3-yl)thio)acetate 3 were synthesized via reaction of 4-amino-5-(1H-indol-2-yl)-1,2,4-triazol-3(2H)-thione 1 with tert-butyl bromoacetate and ethyl chloroacetate in the presence of base (Et3N). The molecular structure of 2, and 3 was confirmed by single-crystal X-ray diffraction and 1H/13C- NMR spectroscopic techniques. In compound 2, the molecular packing depends on significant O...H (9.3%), N...H (12.4%) and S...H (3.1%) as well as relatively weak C...H (14.1%), S...C (…

Análisis espectroscópico de fragmentos cometarios y asteroidales a su entrada en la atmósfera terrestre.

2002

En la presente tesis se analiza el origen y composición de la materia interplanetaria a partir de una perspectiva nueva basada en el estudio de los fenómenos luminosos que producen estas partículas a su entrada a la atmósfera terrestre, llamados meteoros. Estas partículas, procedentes mayoritariamente de la degradación de las superficies de cometas y asteroides, cuando se hayan en órbita solar se denominan genéricamente meteoroides. Dependiendo de la geometría del encuentro con la Tierra los meteoroides alcanzan la atmósfera a velocidades comprendidas en el rango de 11 a 73 km/s. A estas velocidades a alturas de entre 120 y 70 km. la densidad atmosférica es suficiente para que las colisione…

Psicobiologia dell'attaccamento

2008

In this work, the emotional and cerebral development of the individual is treated as a complex process, within which genetic and experiential factors interact; equal focus is given to these factors as is through the interactions of both that the human brain achieves full maturity. The recent literature on neuroscientific findings has allowed to understand further which are the mechanisms that play the most important role in the human brain. In particular, this recent work has pointed out the importance of precocious experiences of emotional syntonization between the baby and its development partners; the quality of the experiences that such partners will be able to provide will configure no…

All-sky search in early O3 LIGO data for continuous gravitational-wave signals from unknown neutron stars in binary systems

2021

Rapidly spinning neutron stars are promising sources of continuous gravitational waves. Detecting such a signal would allow probing of the physical properties of matter under extreme conditions. A significant fraction of the known pulsar population belongs to binary systems. Searching for unknown neutron stars in binary systems requires specialized algorithms to address unknown orbital frequency modulations. We present a search for continuous gravitational waves emitted by neutron stars in binary systems in early data from the third observing run of the Advanced LIGO and Advanced Virgo detectors using the semicoherent, GPU-accelerated, binaryskyhough pipeline. The search analyzes the most s…

Retrieving and broadcasting near-real-time biophysical parameters from MODIS and SEVIRI receiving stations at the global change unit of the Universit…

2015

We present here the automatic processing chains implemented at the Global Change Unit of the University of Valencia. These allow for a near-real-time retrieval of various biophysical parameters from both Sun-synchronous TERRA/AQUA Moderate Resolution Imaging Spectroradiometer MODIS and geostationary Meteosat Second Generation Spinning Enhanced Visible and Infrared Imager MSG SEVIRI sensors. Retrieved parameters, namely sea and land surface temperatures SST and LST, respectively, normalized difference vegetation index NDVI, and vegetation condition index VCI, are similar for both sensors, and specific approaches have been developed and implemented for near-real-time parameter retrievals: htt…

Aktuelle interdisziplinäre Diagnostik und Therapie der endokrinen Orbitopathie*

2008

Diagnostic Localizing Value of the Electrically Elicited Blink Reflex

1993

The blink reflex (BlinkR) following electrical stimulation of the supraorbital nerve consists of an early ipsilateral reflex component (R1) and bilateral late reflex components ipsilaterally (R2) and contralateral (R2c). An additional, and even later component, also bilateral, R3, R3c was first described by Penders and Delwaide [34] and so far has not been studied systematically.

Effects of the silencing of sorbitol dehydrogenase on sugar partitioning in vegetative sinks in apple

2011

Synthesis, X-ray structure, Hirshfeld analysis, and DFT studies of a new Pd(II) complex with an anionic s-triazine NNO donor ligand

2020

Abstract A new Pd(II) complex, [Pd(Triaz)Cl], with the hydrazono-s-triazine ligand, 2,4-di-tert-butyl-6-((2-(4-morpholino-6-(phenylamino)-1,3,5-triazin-2-yl)hydrazono)methyl)phenol (HTriaz), was synthesized by the reaction of PdCl2 with the organic ligand (1:1) in acetone under isothermal conditions. The molecular structure of the [Pd(Triaz)Cl] complex was determined using FTIR and 1H NMR spectroscopic techniques, and single-crystal X-ray diffraction. Moreover, using Hirshfeld surface analysis, the percentages of the intermolecular interactions were determined. The obtained values were 60.6%, 11.6%, 8.1%, 3.6%, and 5.0% for the H⋯H, C⋯H, O⋯H, N⋯H, and Cl⋯H interactions, respectively. Among …

Chalcogen‐Bonding Interactions in Telluroether Heterocycles [Te(CH2)m]n(n=1–4;m=3–7)

2020

The Te⋅⋅⋅Te secondary bonding interactions (SBIs) in solid cyclic telluroethers were explored by preparing and structurally characterizing a series of [Te(CH2 )m ]n (n=1-4; m=3-7) species. The SBIs in 1,7-Te2 (CH2 )10 , 1,8-Te2 (CH2 )12 , 1,5,9-Te3 (CH2 )9 , 1,8,15-Te3 (CH2 )18 , 1,7,13,19-Te4 (CH2 )20 , 1,8,15,22-Te4 (CH2 )24 and 1,9,17,25-Te4 (CH2 )28 lead to tubular packing of the molecules, as has been observed previously for related thio- and selenoether rings. The nature of the intermolecular interactions was explored by solid-state PBE0-D3/pob-TZVP calculations involving periodic boundary conditions. The molecular packing in 1,7,13,19-Te4 (CH2 )20 , 1,8,15,22-Te4 (CH2 )24 and 1,9,17,…