Search results for "Order theory"
showing 10 items of 150 documents
Tetramethylammonium chlorodiphenylthiocyanatoantimonate(III)
2005
The crystal structure of the title compound, (C4H12N)[Sb(C6H5)2Cl(NCS)], contains two cations and two anions in the asymmetric unit. The Sb atom exhibits a distorted pseudo-trigonal–bipyramidal coordination, with the phenyl groups and the lone pair of electrons in equatorial positions and N-bonded thiocyanate and Cl− ligands in axial positions.
1,4-Dimethyl-3-phenyl-3H-pyrazolo[3,4-c]isoquinolin-5(4H)-one
2008
The title compound, C18H15N3O, is the product of the thermal decomposition of the diazonium salt derived from 2-amino-N-methyl-N-(3-methyl-1-phenyl-1H-pyrazol-5-yl)benzamide. It is characterized by a trans orientation of the methyl groups with respect to the tricyclic ring system. The molecule has a nearly planar phenylpyrazolo[3,4-c]isoquinolin-5-one system, the largest deviation from the mean plane being 0.066 (2) angstrom for the O atom. The dihedral angle between the phenyl substituent and the heterotricycle is 67 (1)degrees. The packing is stabilized by C-H center dot center dot center dot N hydrogen-bond interactions, with the formation of molecular chains along the c axis.
Induced and reduced unbounded operator algebras
2012
The induction and reduction precesses of an O*-vector space \({{\mathfrak M}}\) obtained by means of a projection taken, respectively, in \({{\mathfrak M}}\) itself or in its weak bounded commutant \({{\mathfrak M}^\prime_{\rm w}}\) are studied. In the case where \({{\mathfrak M}}\) is a partial GW*-algebra, sufficient conditions are given for the induced and the reduced spaces to be partial GW*-algebras again.
Theoretical study of nitrogen heterocyclics. IV. Molecular diagrams and carcinogenic activity of some naphthindoles
2010
Molecular-orbital calculations of structural static parameters (bond orders, π-electron densities and free valences) and dynamic indices (atom, ortho- and para-localization energies) are presented for a number of naphthindoles. The results are used to predict the chemical properties of the molecules. We have made a comparison of the carcinogenic inactivity and the static and dynamic complex indices used to characterize the K region in some benzindoles and these naphthindoles.
(3RS,1SR)-3-Bromo-3-(1-phenylpropyl)chroman-2,4-dione
2005
The title compound, C18H15BrO3, was obtained by bromination of phenprocoumone with N-bromosuccinimide. The X-ray structure confirms an earlier proposal concerning the regioselectivity of the reaction to introduce the Br atom at the 3-position.
An unsolvated erbium organyl: (2,4,6,2′′,4′′,6′′-hexamethyl-1,1′:3′;1′′-terphenyl-2′-yl)bis(methylcyclopentadienyl)erbium(III)
2007
The title compound, [Er(Dmp)(C5H4Me)2] (Dmp = 2,6-Mes2C6H3, with Mes = 2,4,6-Me3C6H2) or [Er(C6H7)2(C24H25)], was obtained by the reaction of LiDmp with Er(C5H4Me)3. The Er atom is η5-coordinated by two methylcyclopentadienyl ligands (average Er⋯centroid distance = 2.341 A) and η1-coordinated by the ipso-C atom of the aryl substituent [Er—C = 2.434 (4) A]. An additional π-arene contact with one of the Mes groups [Er⋯C = 3.077 (4) A] gives rise to the pyramidalization of the metal-atom environment.
Ethyl 1-acetyl-3-amino-1H-pyrazole-4-carboxylate, a tetragonal structure with Z′ = 4
2006
The title compound, C8H11N3O3, crystallizes with Z' = 4. One pyrazole N atom is substituted and excluded from intermolecular contacts. The amine N, acetyl O and an ester O atom are involved in the formation of nearly planar molecular layers. The layers are perpendicular to the c axis, with an interlayer distance of 3.333 Å. The hydrogen-bonding patterns are similar for each molecule, i.e. intramolecular N-H...O, as well as intermolecular N-H...O and C-H...N(pyrazole), bonds are present.
$PT$-symmetric graphene under a magnetic field
2016
We propose a $PT$-symmetrically deformed version of the graphene tight-binding model under a magnetic field. We analyze the structure of the spectra and the eigenvectors of the Hamiltonians around the $K$ and $K'$ points, both in the $PT$-symmetric and $PT$-broken regions. In particular we show that the presence of the deformation parameter $V$ produces several interesting consequences, including the asymmetry of the zero-energy states of the Hamiltonians and the breakdown of the completeness of the eigenvector sets. We also discuss the biorthogonality of the eigenvectors, which {turns out to be} different in the $PT$-symmetric and $PT$-broken regions.
L2-L1 Translation Priming Effects in a Lexical Decision Task: Evidence From Low Proficient Korean-English Bilinguals
2018
One of the key issues in bilingual lexical representation is whether L1 processing is facilitated by L2 words. In this study, we conducted two experiments using the masked priming paradigm to examine how L2-L1 translation priming effects emerge when unbalanced, low proficiency, Korean-English bilinguals performed a lexical decision task. In Experiment 1, we used a 150 ms SOA (50 ms prime duration followed by a blank interval of 100 ms) and found a significant L2-L1 translation priming effect. In contrast, in Experiment 2, we used a 60 ms SOA (50 ms prime duration followed by a blank interval of 10 ms) and found a null effect of L2-L1 translation priming. This finding is the first demonstrat…
A fuzzy approach to multidimensional material deprivation measurement: the case of foreigners living in Italy
2014
This paper provides a new approach to the measurement of multidimensional material deprivation, based on partial order theory and on fuzzy set measurement. The main feature of the methodology is that the information needed for the deprivation assessment is extracted directly from the relational structure of the dataset, avoiding any kind of scaling and not proper aggregation procedure, so as to respect the measurement level of the data. An empirical illustration, using data from a special EU-SILC survey on migrants in Italy, provides a new insight on the material deprivation of foreigners living in Italy