Search results for "Ordination"
showing 10 items of 1367 documents
Synthesis and spectral studies on metal complexes with the neutral O,N,O-tridentate Schiff base 6-amino-5-formyl-1,3-dimethyluracil-benzoylhydrazone
1999
Abstract From the reaction between different Co(II), Cu(II), Zn(II) and Pd(II) salts and the Schiff base 6-amino-5-formyl-1,3-dimethyluracil-benzoylhydrazone (H 2 BEZDO), in ethanol and acetone media, five complexes with M/L stoichiometry 1/1, containing the neutral organic ligand, have been obtained. These compounds have been studied by IR, 13 C and 1 H-NMR, UV-VIS-NIR and EPR spectroscopies and magnetic measurements. A single crystal X-ray diffraction study has been carried out on the compound [Cu(ClO 4 )(H 2 BEZDO)(H 2 O)]ClO 4 . The structure consists of mononuclear cations [Cu(ClO 4 )(H 2 BEZDO)(H 2 O)] + and uncoordinated perchlorate anions. The coordination environment around the Cu(…
Self-assembly of extended Schiff base amino acetate skeletons, 2-{[(2Z)-(3-hydroxy-1-methyl-2-butenylidene)]amino}phenylpropionate and 2-{[(E)-1-(2-h…
2007
The organotin(IV) compounds, [Ph 3 SnL 1 H] n · nCCl 4 ( 1 ), [Me 2 SnL 2 (OH 2 )] ( 2 ), [ n Bu 2 SnL 2 ] ( 3 ), [Ph 2 SnL 2 ] n ( 4 ), [Ph 3 SnL 2 H] n ( 5 ) and [Ph 3 SnL 3 H] n ( 7 ) (L 1 = 2-{[(2 Z )-(3-hydroxy-1-methyl-2-butenylidene)]amino}phenylpropionate and L 2−3 = 2-{[( E )-1-(2-hydroxyaryl)alkylidene]amino}phenylpropionate), were synthesized by treating the appropriate organotin(IV) chloride(s) with the potassium salt of the ligand in a suitable solvent, while [ n Bu 2 SnL 3 (OH 2 )] ( 6 ) was obtained by reacting the acid form of L 3 (generated in situ) with n Bu 2 SnO. These complexes have been characterized by 1 H, 13 C, 119 Sn NMR, ESI-MS, IR and 119m Sn Mossbauer spectro…
C3-symmetric trinuclear copper(ii) species as tectons in crystal engineering
2013
Three new complexes have been obtained using C3-symmetric trinuclear complexes as tectons; [Cu3(felden)(NCS)3(dmf)3] (1), [Cu3(felden)(mand)3]·(C2H5)2O (2), and [Cu3(felden)(dca)3(C2H5OH)]·2H2O (3) (H3felden is the Schiff base resulting from the condensation of 2,4,6-triformylphloroglucinol with N,N-dimethylethylenediamine, mand− is the anion of the R-mandelic acid and dca− is the dicyanamide anion). Compounds 1 and 2 are discrete trinuclear species, while compound 3 is a 2D coordination polymer, constructed from trinuclear nodes and dicyanamido spacers. The variable-temperature magnetic properties of 1–3 have been investigated and they reveal the occurrence of weak antiferromagnetic intera…
Magnetic and catalytic properties of a new copper(II)–Schiff base 2D coordination polymer formed by connected helical chains
2011
Abstract A dicyanamide bridged 2D polynuclear complex of copper(II) having molecular formula [Cu2(L)(μ1,5-dca)2]n (1) has been synthesized using the Schiff base ligand N,N′-bis(salicylidene)-1,3-diaminopentane, (H2L) and sodium dicyanamide (dca). The complex presents a 2D hexagonal structure formed by 1,5-dca singly bridged helical chains connected through double 1,5-dca bridges. The chelating characteristics of the H2L Schiff base ligand results in the formation of copper(II) dimer with a double phenoxo bridge presenting a very strong antiferromagnetic coupling in the copper(II) derivative (1) (J = −510 cm−1). The dimeric asymmetric unit of 1 is very similar to the active site of the catec…
MOTOR COORDINATION DIFFICULTIES IN CHILDREN WITH LEARNING DISABILITIES
2016
Nowadays increasing the number of children with learning disabilities in comprehensive schools of Latvia, so it is necessary preventive measures during schooltime. One of the support measures are short movement activity in academic lessons. The aim of article is theoretical analyze the correlations between motor coordination difficulties and the child's academic achievement and find out primary school teachers' views on possible support for children with learning disabilities. Main findings – development of motor coordination in children of primary schools is effective when using short movement breaks in classroom. Research methods: analysis of scientific and methodological literature, a su…
Necesidad de una coordinación socio-sanitaria ante situaciones de emergencia social en las localidades de Xàtiva y Ontinyent (España)
2019
This article try to show up whether there is a need to coordinate the local Social Services (“SS.SS” in Spanish) with the Emergency Health Care Service (“SAMU” in Spanish) from both Xàtiva and Ontinyent (towns of the Community of Valencia) in order to allow an integrated care, carried out using an ad-hoc survey completed by (“SAMU” in Spanish) health workers and social workers from both Xàtiva and Ontinyent making up a descriptive, cross-sectional and observational study. Some of the results show that all the professionals point out the absolute need to coordinate the SAMU with the (“SS.SS” in Spanish) and that almost all of the sample believe that it is essential or necessary to implement …
Nematode community response to fish-farm impact in the western Mediterranean.
2002
A previous investigation on fish-farm biodeposition effects on benthos, carried out in the Gaeta Gulf (northwestern Mediterranean Sea), revealed a strong impact on meiofaunal assemblages. This study implements these findings by examining in detail the nematode assemblage and its response to organic enrichment from the start of a fish farm activity to the conclusion of the fish rearing cycle. Density, community structure and individual size were utilised for univariate (genus, trophic diversity and abundance patterns) and multivariate analyses (MDS) in order to identify the best descriptors of impact and the response of the nematode assemblages. Nematodes displayed significantly reduced dens…
Progetti per raccontare la città
2020
Nell’ambito di una ricerca interdipartimentale il lavoro presenta l’esperienza di coordinamento di una attività progettuale condotta con giovani laureati nel centro storico di Caltabellotta, i cui lavori si offrono come occasione per aiutare la città a precisare intenzioni e atteggiamenti, riflessioni e azioni per innescare processi reali di rigenerazione. Un testo iniziale precisa e racconta le finalità del coordinamento.
The Design of Effective Maintenance Outsourcing Contracts
2009
Recent developments in maintenance planning and management demonstrate that the establishment of optimized maintenance policies may drastically improve the performance and reduce the operating cost of facilities. However maintenance activities are typically outside of the core business of production facilities, hence enterprises often fail to catch the opportunities that may originate by properly optimized management strategies. A strategic maintenance management should hence encompass the possibility of outsourcing maintenance activities to ensure the necessary perfomance of production systems, while allowing enterprises to concentrate their resources on their core activities. In order to …
MAC design on real 802.11 devices: From exponential to Moderated Backoff
2016
In this paper we describe how a novel backoff mechanism called Moderated Backoff (MB), recently proposed as a standard extension for 802.11 networks, has been prototyped and experimentally validated on a commercial 802.11 card before being ratified. Indeed, for performance reasons, the time critical operations of MAC protocols, such as the backoff mechanism, are implemented into the card hardware/firmware and cannot be arbitrarily changed by third parties or by manufacturers only for experimental reasons. Our validation has been possible thanks to the availability of the so called Wireless MAC Processor (WMP), a prototype of a novel wireless card architecture in which MAC protocols can be p…