Search results for "Organic Chemical"
showing 10 items of 733 documents
Low-temperature growth of n ++-GaN by metalorganic chemical vapor deposition to achieve low-resistivity tunnel junctions on blue light emitting diodes
2018
We report on low-resistivity GaN tunnel junctions (TJ) on blue light-emitting diodes (LEDs). Si-doped n ++-GaN layers are grown by metalorganic chemical vapor deposition directly on LED epiwafers. Low growth temperature (<800 °C) was used to hinder Mg-passivation by hydrogen in the p ++-GaN top surface. This allows achieving low-resistivity TJs without the need for post-growth Mg activation. TJs are further improved by inserting a 5 nm thick In0.15Ga0.85N interlayer (IL) within the GaN TJ thanks to piezoelectric polarization induced band bending. Eventually, the impact of InGaN IL on the internal quantum efficiency of blue LEDs is discussed.
Ion-Selective Organic Electrochemical Transistors
2014
Ion-selective organic electrochemical transistors with sensitivity to potassium approaching 50 μA dec(-1) are demonstrated. The remarkable sensitivity arises from the use of high transconductance devices, where the conducting polymer is in direct contact with a reference gel electrolyte and integrated with an ion-selective membrane.
Comparative evaluation of the swelling and degrees of cross-linking in three organic gel packings for SEC through some geometric parameters.
2003
Abstract The size exclusion chromatographic (SEC) behavior of five solvent/polymer systems in three organic column packings based on polystyrene/divinylbenzene (PS/DVB) copolymer, TSK-Gel H HR , μ-styragel and TSK-Gel H XL , has been compared. All the packings offer similar characteristics (pore size, particle size and efficiency) but some differences have been found when eluting the same systems. The different elution behavior observed in both polymeric gels has been analyzed in terms of their swelling and cross-linking degrees and of the fractal parameters. From the Universal Calibration plots, values of the chromatographic partition coefficient, K p , have been obtained and using some eq…
Porous organic cage compounds as highly potent affinity materials for sensing by quartz crystal microbalances.
2012
Porosity makes powerful affinity materials for quartz crystal microbalances. The shape-persistent organic cages and pores create superior affinity systems to existing ones for direct tracing of aromatic solvent vapors. A shape and size selectivity for the analytes is observed. These organic cages can be processed to thin films with highly reproducible sensing properties.
Ionic Space-Charge Effects in Solid State Organic Photovoltaics
2010
The effect of mobile ions on the operation of donor-acceptor bilayer solar cells is studied. We demonstrate the large effect ions can have on the energetics of the solar cells, illustrated by (for instance) changing the output voltage of a cell in situ from 0.35 to 0.74 V. More importantly, it is shown ionic species do not obstruct the charge generating properties of the photovoltaic devices and ionic space charge can be used in situ to improve their efficiencies. The results obtained are explained by taking into account energetic changes at the donor-acceptor interface as well as built-in potentials, giving clear guidelines on how ionic species can offer many new and exciting functionaliti…
Coastal Evolution in a Mediterranean Microtidal Zone: Mid to Late Holocene Natural Dynamics and Human Management of the Castellò Lagoon, NE Spain
2016
We present a palaeoenvironmental study of the Castelló lagoon (NE Spain), an important archive for understanding long-term interactions between dynamic littoral ecosystems and human management. Combining geochemistry, mineralogy, ostracods, diatoms, pollen, non-pollen palynomorphs, charcoal and archaeo-historical datasets we reconstruct: 1) the transition of the lagoon from a marine to a marginal environment between ~3150 cal BC to the 17th century AD; 2) fluctuations in salinity; and 3) natural and anthropogenic forces contributing to these changes. From the Late Neolithic to the Medieval period the lagoon ecosystem was driven by changing marine influence and the land was mainly exploited …
Shared effects of organic microcontaminants and environmental stressors on biofilms and invertebrates in impaired rivers
2016
Land use type, physical and chemical stressors, and organic microcontaminants were investigated for their effects on the biological communities (biofilms and invertebrates) in several Mediterranean rivers. The diversity of invertebrates, and the scores of the first principal component of a PCA performed with the diatom communities were the best descriptors of the distribution patterns of the biological communities against the river stressors. These two metrics decreased according to the progressive site impairment (associated to higher area of agricultural and urban-industrial, high water conductivity, higher dissolved organic carbon and dissolved inorganic nitrogen concentrations, and high…
Cordage, basketry and containers at the Pleistocene-Holocene boundary in southwest Europe. Evidence from Coves de Santa Maira (Valencian region, Spai…
2019
In this study we present evidence of braided plant fibres and basketry imprints on clay recovered from Coves de Santa Maira, a Palaeolithic-Mesolithic cave site located in the Mediterranean region of Spain. The anatomical features of these organic fibre remains were identified in the archaeological material and compared with modern Stipa tenacissima (esparto grass). Based on direct dating, the fragments of esparto cord from our site are the oldest worked plant fibres in Europe. Sixty fragments of fired clay are described. The clay impressions have allowed us to discuss the making of baskets and containers. According to their attributes and their functional interpretation, we have grouped th…
Isoprenoid biosynthesis in eukaryotic phototrophs: a spotlight on algae.
2011
Isoprenoids are one of the largest groups of natural compounds and have a variety of important functions in the primary metabolism of land plants and algae. In recent years, our understanding of the numerous facets of isoprenoid metabolism in land plants has been rapidly increasing, while knowledge on the metabolic network of isoprenoids in algae still lags behind. Here, current views on the biochemistry and genetics of the core isoprenoid metabolism in land plants and in the major algal phyla are compared and some of the most pressing open questions are highlighted. Based on the different evolutionary histories of the various groups of eukaryotic phototrophs, we discuss the distribution an…
The Role of Macrocyclic Receptors in Organization of Metal Centers
1994
The coordination properties of saturated aza or oxa-aza macrocyclic receptors are strictly dependent on their molecular topology. In order to rationalize the relationship between structural features and binding characteristics of such molecules we have studied the coordination behavior of different macrocyclic or macropolycyclic oxa-aza ligands towards metal cations. Depending on molecular topology, a variety of inorganic chemical species can be lodged inside the receptor’s cavity, such as simple metal ions, complexed inorganic anions, partially hydrated metal cations or binuclear assemblies.