Search results for "Oxidation-Reduction"
showing 10 items of 689 documents
Antibacterial studies, DNA oxidative cleavage, and crystal structures of Cu(II) and Co(II) complexes with two quinolone family members, ciprofloxacin…
2005
Nine coordination compounds of Cu(II) and Co(II) with Ciprofloxacin (HCp) and Enoxacin (HEx) as ligands have been prepared and characterized. Single crystal structural determinations of [Cu(HCp)2(ClO4)2].6H2O (1) and [Co(HEx)2(Ex)]Cl.2CH(3)OH.12H2O (4) are reported. The crystal of 1 is composed of [Cu(HCp)2(ClO4)2] units with the two perchlorate anions semicoordinated, and uncoordinated water molecules. The copper ion, at a crystallographic inversion centre, is in a tetragonally distorted octahedral environment. The structure of 4 consists of cationic monomeric [Co(HEx)2(Ex)]+ units, chloride anions, and uncoordinated methanol and water molecules. The complex is six-coordinate, with a sligh…
Current and new insights on phytosterol oxides in plant sterol-enriched food.
2011
Over the past 15 years, plant sterol-enriched foods have faced a great increase in the market, due to the asserted cholesterol-lowering effect of plant sterols. However, owing to their chemical structures, plant sterols can oxidize and produce a wide variety of oxidation products with controversial biological effects. Although oxyphytosterols can derive from dietary sources and endogenous formation, their single contribution should be better defined. The following review provides an overall and critical picture on the current knowledge and future perspectives of plant sterols-enriched food, particularly focused on occurrence of plant sterol oxidation products and their biological effects. T…
Reverse electrodialysis performed at pilot plant scale: Evaluation of redox processes and simultaneous generation of electric energy and treatment of…
2017
Abstract This paper describes the experimental campaign carried out with a reverse electrodialysis (RED) demonstration plant (Marsala, Italy) with the main aims of: (i) evaluating the effect of various operating parameters, including the redox processes, on the system performances; (ii) using the plant for the simultaneous generation of electric energy and treatment of wastewater. The prototype (44 × 44 cm2, 500 cell pairs) was tested using both real (brackish water and brine) and artificial solutions. Tests with two different electrode rinse solutions (with or without iron redox couples) were performed. In agreement with the data obtained in the laboratory, the presence of iron ions contri…
Experimental sulphide inhibition calibration method in nitrification processes: A case-study.
2020
[EN] Sulphide is one of the inhibitors in the nitrification process in WWTP in regions with sulphate rich soils. As little information is currently available on sulphide nitrification inhibition, the aim of this study was to develop a method based on a modification of the Successive Additions Method to calibrate the effect of sulphide on the activity of ammonia-oxidising bacteria (AOB) and nitrite-oxidising bacteria (NOB). The developed method was then applied to activated sludge samples from two WWTPs with different influent sulphide concentrations. In both cases, sulphide had a greater inhibitory effect on NOB than AOB activity. The sulphide inhibition was found to be lower in the activat…
Comparison of organic peracids in wastewater treatment: Disinfection, oxidation and corrosion.
2015
The use of organic peracids in wastewater treatment is attracting increasing interest. The common beneficial features of peracids are effective anti-microbial properties, lack of harmful disinfection by-products and high oxidation power. In this study performic (PFA), peracetic (PAA) and perpropionic acids (PPA) were synthesized and compared in laboratory batch experiments for the inactivation of Escherichia coli and enterococci in tertiary wastewater, oxidation of bisphenol-A and for corrosive properties. Disinfection tests revealed PFA to be a more potent disinfectant than PAA or PPA. 1.5 mg L(-1) dose and 2 min of contact time already resulted in 3.0 log E. coli and 1.2 log enterococci r…
Are agricultural soils under a continental temperate climate susceptible to episodic reducing conditions and increased leaching of phosphorus?
2012
International audience; Soil science research has probably underestimated the significance that short-term, episodic cycles of reduction and oxidation has had on phosphorus (P) reactivity. Here, the effects of eleven pulsed reduction-oxidation (including wet-dry) cycles on soil P dynamics are compared for 12 soils having contrasting properties and all overfertilised with respect to P. The laboratory based incubation conditions attempted to simulate transient waterlogging of the soil profile and involved repeated sampling and analysis of both the solution and solid phase P forms. An initial increase in P concentration in solution that occurred up to and including the fourth full cycle was fo…
Treatment of a submerged anaerobic membrane bioreactor (SAnMBR) effluent by an activated sludge system: the role of sulphide and thiosulphate in the …
2014
This work studies the use of a well-known and spread activated sludge system (UCT configuration) to treat the effluent of a submerged anaerobic membrane bioreactor (SAnMBR) treating domestic waste-water. Ammonia, phosphate, dissolved methane and sulphide concentrations in the SAnMBR effluent were around 55 mg NH4-N L-1, 7 mg PO4-P L-1, 30 mg non-methane biodegradable COD L-1, and 105 mg S2- L-1 respectively. The results showed a nitrification inhibition caused by the presence of sulphur compounds at any of the solids retention time (SRT) studied (15,20 and 25 days). This inhibition could be overcome increasing the hydraulic retention time (HRT) from 13 to 26 h. Among the sulphur compounds, …
Oxidation of diclofenac in the presence of iron(II) octacarboxyphthalocyanine
2021
Abstract This paper presents the results of the research on the influence of catalytic activity of iron(II) octacarboxyphthalocyanines (FePcOC) on the transformation of diclofenac (DCF) which is the most popular anti-inflammatory analgesic. Diclofenac poses a serious threat to the natural environment. The paper demonstrates that diclofenac, in the presence a monomeric form of iron octacarboxyphthalocyanine and hydroxyl radicals (HO•) (from H2O2), undergoes a transformation into diclofenac-2,5-iminoquinone (DCF-2,5-IQ), causing distinct changes in the UV–Vis absorption spectrum. In the presence of iron octacarboxyphthalocyanine and H2O2, the previously colourless diclofenac solution becomes …
Comparative assessment of a foam-based oxidative treatment of hydrocarbon-contaminated unsaturated and anisotropic soils.
2019
Abstract In situ delivery of liquid reagents in vadose zone is limited by soil anisotropy and gravity. The enhanced delivery of persulfate (PS) as oxidant, using a new foam-based method (F-PS) was compared at bench-scale to traditional water-based (W-PS) and surfactant solution-based (S-PS) deliveries. The goal was to distribute PS uniformly in coal tar-contaminated unsaturated and anisotropic soils, both in terms of permeability and contamination. Water was the less efficiently delivered fluid because of the hydrophobicity of the contaminated soils. Surfactant enhanced PS-distribution into contaminated zones by reducing interfacial tension and inverting soil wettability. Regardless of coal…
Polar organic marker compounds in PM2.5 aerosol from a mixed forest site in western Germany
2008
The molecular composition of PM2.5 (particulate matter with an aerodynamic diameter2.5 microm) aerosol samples collected during a very warm and dry 2003 summer period at a mixed forest site in Jülich, Germany, was determined by gas chromatography/mass spectrometry in an effort to evaluate photooxidation products of biogenic volatile organic compounds (BVOCs) and other markers for aerosol source characterization. Six major classes of compounds represented by twenty-four individual organic species were identified and measured, comprising tracers for biomass combustion, short-chain acids, fatty acids, sugars/sugar alcohols, and tracers for the photooxidation of isoprene and alpha-/beta-pinene.…