Search results for "Oxide"

Heavy ion induced columnar defects: a sensitive probe for the 2D/3D behaviour of vortex matter in high-temperature superconductors

1998

Abstract Heavy ion irradiation is used to create columnar defects in high-temperature superconductors (HTS). The heavy ion induced defects are not only very well controlled in shape and density, but also in the direction of the tracks with respect to the crystallographic c-axis. Pinning of the flux lines as a function of magnetic field orientation then becomes dependent on vortex dimensionality. The two-dimensional (2D)/three-dimensional (3D) behaviour of flux lines was investigated in the highly anisotropic Bi-based superconducting oxide. Results obtained from transport current measurements with epitaxial films, measurements with small single crystals in flux transformer geometry and muon …

Free radical copolymerization of vinylidene fluoride and acrylic acid in supercritical carbon dioxide

2010

Preparation of drug-polymer composites by polymerization in supercritical carbon dioxide: a new method to increase the dissolution rate of bioactive …

2008

Structure and pair correlations of a simple coarse grained model for supercritical carbon dioxide

2009

A recently introduced coarse-grained pair potential for carbon dioxide molecules is used to compute structural properties in the supercritical region near the critical point, applying Monte Carlo simulations. In this model, molecules are described as point particles, interacting with Lennard-Jones (LJ) forces and a (isotropically averaged) quadrupole–quadrupole potential, the LJ parameters being chosen such that gratifying agreement with the experimental phase diagram near the critical point is obtained. It is shown that the model gives also a reasonable account of the pair correlation function, although in the nearest neighbour shell some systematic discrepancies between the model predicti…

Extraction of wheat germ oil by supercritical CO2 : Oil and defatted cake characterization

2003

In this paper the working conditions for the extraction of wheat germ oil in a supercritical CO2 pilot plant of 1-L extraction capacity were studied. The best conditions were: pressure, 38 MPa; temperature, 55degreesC; wheat germ particle size, about 0.35 mm; CO2 flow rate, 1.5 L min(-1). These conditions gave yields of about 92% of total oil after 3 h of processing. The obtained oils and the partially defatted cake were investigated with regard to their FA, tocol (tocopherol and tocotrienol), carotenoid, and sterol compositions and to their quality characteristics (FFA, PV, para-anisidine value, and color of the by-product). Moreover, the oil quality was evaluated in relation to the progre…

Supercritical CO2 extraction of essential oil from orange peel; effect of the height of the bed

2000

Abstract The influence of the height of the particle bed on the kinetics of supercritical fluid extraction (SFE) of essential oil from orange peel is analyzed in this article. Peel of dehydrated oranges of the satsuma and naveline cultivars was used. A series of experiments were designed wherein, for the same conditions, particle height varied widely. These experiments were also carried out on different scales with extraction volumes of 0.5 and 5 l. The results of the experiments were interpreted using Sovova's extended flow model as has been done in previous studies. The bibliography indicates that a number of phenomena may distort the process. One of these phenomena is the formation of ma…

Effective recovery of perfluoropolyether surfactants from PVDF and PTFE by supercritical carbon dioxide extraction

2007

Abstract The extraction of ammonium carboxylate perfluoropolyether surfactants from poly(vinylidenefluoride) (PVDF) and poly(tetrafluoroethylene) (PTFE) was performed with supercritical carbon dioxide. When proper conditions in terms of temperature, pressure and flow rate were used, extraction recoveries higher than 90% were obtained. For PVDF (with a concentration of surfactant of 5% w/w), at low pressure (12 MPa) and 40 °C, more than 100 min are necessary to have a quantitative extraction. On the other hand, at higher pressure (20 MPa) a quantitative recovery was obtained after few minutes. A strong influence of the temperature on the extraction recovery was also found. In the case of PTF…

Copolymerization of VDF and HFP in Supercritical Carbon Dioxide: A Robust Approach for Modeling Precipitation and Dispersion Kinetics

2011

A kinetic model is developed for the heterogeneous free-radical copolymerization of vinylidene fluoride and hexafluoropropylene in supercritical CO2. The model accounts for polymerization in both the dispersed (polymer-rich) phase and in the continuous (polymer-free) supercritical phase, for radical interphase transport, diffusion limitations, and chain-length-dependent termination in the polymer-rich phase. A parameter evaluation strategy is developed and detailed to estimate most of the kinetic parameters a priori while minimizing their evaluation by direct fitting. The resulting model predictions compare favorably with the experimental results of conversion and MWD at varying monomer fee…

Critical Micelle Density for the Self-Assembly of Block Copolymer Surfactants in Supercritical Carbon Dioxide

1999

The parameters which influence the self-assembly of molecules in solution include the temperature and solvent quality, and this study illustrates the use of these variables to regulate the degree of association of block copolymer amphiphiles in highly compressible supercritical carbon dioxide. Small-angle neutron scattering (SANS) has been used to examine the association behavior of a block copolymer containing a CO2-phobic moiety, poly(vinyl acetate), and a CO2-philic block, poly(1,1-dihydroperfluoro-octylacrylate). By adjustment of the density of the medium through pressure and temperature profiling, the self-assembly can be reversibly controlled from unimers to core−shell spherical micel…

A combined small-angle neutron and X-ray scattering study of block copolymers micellisation in supercritical carbon dioxide

2003

Small angle neutron and X-ray scattering (SANS and SAXS) are used to investigate the monomer–aggregate transition of fluorocarbon–hydrocarbon diblock copolymers in supercritical carbon dioxide. SANS data are analyzed using a polydisperse sphere core–shell model. Synchrotron SAXS data have been collected by profiling the pressure at different temperatures, and critical micellization densities have been obtained for a series of diblock solutions. Finally pressure jump experiments, combined with synchrotron SAXS, have revealed two steps in the dynamics of the formation of the aggregates.