Search results for "Oxyquinoline"

showing 7 items of 17 documents

CCDC 133180: Experimental Crystal Structure Determination

2003

Related Article: M.Albrecht, K.Witt, E.Wegelius, K.Rissanen|2000|Tetrahedron|56|591|doi:10.1016/S0040-4020(99)01057-1

Space GroupCrystallographyCrystal SystemCrystal Structure7-Acetamido-8-hydroxyquinolineCell ParametersExperimental 3D Coordinates
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CCDC 1013128: Experimental Crystal Structure Determination

2015

Related Article: Zhanhu Sun, Markus Albrecht, Fangfang Pan, Michel Waringo|2015|Synthesis|47|861|doi:10.1055/s-0034-1379605

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersN-benzyl-8-((1H-indol-7-ylcarbamothioyl)amino)-4-isobutoxyquinoline-2-carboxamide dimethyl sulfoxide solvateExperimental 3D Coordinates
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CCDC 176085: Experimental Crystal Structure Determination

2003

Related Article: M.Albrecht, K.Witt, P.Weis, E.Wegelius, R.Frohlich|2002|Inorg.Chim.Acta|341|25|doi:10.1016/S0020-1693(02)01201-X

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-((mu~2~-N-Hexyl-8-oxyquinoline-7-carboxamide-NOO')-(N-hexyl-8-oxyquinoline-7-carboxamide-NO)-zinc(ii))Cell ParametersExperimental 3D Coordinates
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Organocatalytic Enantioselective Functionalization of Hydroxyquinolines through an Aza-Friedel-Crafts Alkylation with Isatin-derived Ketimines

2018

[EN] A highly enantioselective addition of hydroxyquinolines to isatin-derived ketimines has been realized using a quinine-derived thiourea organocatalyst. The reaction affords chiral 3-amino-2-oxindoles bearing a quinoline moiety with a quaternary stereocenter in high yields (up to 98%) and excellent enantioselectivities (up to 99%). Moreover, we can extend this methodology for the enantioselective functionalization of 5-hydroxyisoquinoline. This methodology represents, to the best of our knowledge, the first enantioselective addition of hydroxyquinolines to imines.

biology010405 organic chemistryIsatinIsatin-derived ketiminesQuinolineQuinolineThioureaEnantioselective synthesisGeneral Chemistry010402 general chemistrybiology.organism_classification01 natural sciencesReaccions químiques0104 chemical sciencesAsymmetric organocatalysischemistry.chemical_compoundCatàlisichemistryFISICA APLICADAOrganic chemistryHydroxyquinolinesFriedel-Crafts reactionValenciaFriedel–Crafts reactionAdvanced Synthesis & Catalysis
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Mono-aryltin(IV) and mono-benzyltin(IV) complexes with pyridine-2-carboxylic acid and 8-hydroxyquinoline. X-ray structure of p-chloro-phenyl-tris(8-q…

1999

Abstract Complexes RSn(O2CPy)3·2H2O and RSn(Ox)3, (PyCOOH=pyridine-2-carboxylic acid, HOx=8-hydroxyquinoline, R=o- and p-Tolyl, o- and p-ClC6H4=o- and p-ClPh, o-ClC6H4CH2=o-ClBenzyl; besides, R=Ph in RSn(Ox)3) have been synthesized and characterized by elemental analysis and determination of molecular weights in CHCl3 solutions. The structure of p-ClPhSn(Ox)3·2CHCl3 has been determined by X-ray diffractometry. The 7-coordinated tin atom of the monomeric compound is in the center of a pentagonal bipyramid formed by (p-ClPh)C and O and N atoms of the chelating Ox− ligands. The latter type of structure would hold for all complexes according to 119Sn Mossbauer (including the determination of th…

chemistry.chemical_classificationDenticityChemistryStereochemistryLigandCarboxylic acidOrganic ChemistryInfrared spectroscopy8-HydroxyquinolineBiochemistryInorganic ChemistryCrystallographychemistry.chemical_compoundPentagonal bipyramidal molecular geometryPyridineMaterials ChemistryChelationPhysical and Theoretical ChemistryJournal of Organometallic Chemistry
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Solid State Structures of Amide-Substituted 8-Hydroxyquinoline Derivatives

2000

Abstract The amide substituted 8-hydroxyquinoline derivatives 3 and 4 form, in the solid state, hydrogen bonded polymers. Polymeric 3 adopts a helical conformation while 4 forms a double-stranded ladder-type structure.

chemistry.chemical_classificationHydrogenHydrogen bondOrganic ChemistryLow-barrier hydrogen bondSolid-statechemistry.chemical_element8-HydroxyquinolinePolymerBiochemistrySolid state structurechemistry.chemical_compoundchemistryAmideDrug DiscoveryPolymer chemistryOrganic chemistryTetrahedron
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Effective Removal and Mineralization of 8-Hydroxyquinoline-5-sulfonic Acid through a Pressurized Electro-Fenton-like Process with Ni−Cu−Al Layered Do…

2020

Ni−Cu−Al layered double hydroxide (Ni−Cu−Al LDH) was proposed as an electro‐Fenton‐like catalyst for 8‐hydroxyquinoline‐5‐sulfonic acid (8‐HQS) removal in water. The properties of the prepared catalysts were characterized by using X‐ray, SEM and EDAX analyses. The effect of numerous operative parameters on the removal of 8‐HQS and total organic carbon (TOC) was studied. Very high level removal of both 8‐HQS and TOC (87 and 79 %, respectively) were obtained by using a pressurized electro‐Fenton‐like process (PrEFL‐LDH) at P=10 bars, using a Ti/IrO2‐Ta2O5 anode for 6 h. The process presented good performances in a large range of pH (3–10) and gave better removals of 8‐HQS and TOC with respect…

chemistry.chemical_classificationchemistry.chemical_compoundChemistry8-hydroxyquinoline-5-sulfonic acid heterogeneous catalysis Ni−Cu−Al layered double hydroxide nitrogen heterocycles pressurized-electro-FentonElectrochemistryHydroxide8-HydroxyquinolineMineralization (soil science)Sulfonic acidSettore ING-IND/27 - Chimica Industriale E TecnologicaHeterogeneous catalysisCatalysisNuclear chemistry
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