Search results for "Ozone"
showing 10 items of 300 documents
In situ observations of CH<sub>2</sub>Cl<sub>2</sub> and CHCl<sub>3</sub…
2021
Abstract. Efficient transport pathways for ozone-depleting very short-lived substances (VSLSs) from their source regions into the stratosphere are a matter of current scientific debate; however they have yet to be fully identified on an observational basis. Understanding the increasing impact of chlorine-containing VSLSs (Cl-VSLSs) on stratospheric ozone depletion is important in order to validate and improve model simulations and future predictions. We report on a transport study using airborne in situ measurements of the Cl-VSLSs dichloromethane (CH2Cl2) and trichloromethane (chloroform, CHCl3) to derive a detailed description of two transport pathways from (sub)tropical source regions in…
Seasonal cycles and variability of O<sub>3</sub> and H<sub>2</sub>O in the UT/LMS during SPURT
2005
Abstract. Airborne high resolution in situ measurements of a large set of trace gases including ozone (O3) and total water (H2O) in the upper troposphere and the lowermost stratosphere (UT/LMS) have been performed above Europe within the SPURT project. With its innovative campaign concept, SPURT provides an extensive data coverage of the UT/LMS in each season within the time period between November 2001 and July 2003. Ozone volume mixing ratios in the LMS show a distinct spring maximum and autumn minimum, whereas the O3 seasonal cycle in the UT is shifted by 2 to 3 month later towards the end of the year. The more variable H2O measurements reveal a maximum during spring/summer and a minimum…
Low-temperature molecular layer deposition using monifunctional aromatic precursors and ozone-based ring-opening reactions
2017
Molecular layer deposition (MLD) is an increasingly used deposition technique for producing thin coatings consisting of purely organic or hybrid inorganic-organic materials. When organic materials are prepared, low deposition temperatures are often required to avoid decomposition, thus causing problems with low vapor pressure precursors. Monofunctional compounds have higher vapor pressures than traditional bi- or trifunctional MLD precursors, but do not offer the required functional groups for continuing the MLD growth in subsequent deposition cycles. In this study, we have used high vapor pressure monofunctional aromatic precursors in combination with ozone-triggered ring-opening reactions…
Suitability of OMI aerosol index to reflect mineral dust surface conditions: preliminary application for studying the link with meningitis epidemics …
2013
12 pages; International audience; The aimof this study is to analyze the suitability of remotely-sensed aerosol retrievals to progress in the understanding of the influence of desert dust on health, and particularly on meningitis epidemics. In the Sahel, meningitis epidemics are a serious public health issue. Social factors are of prime importance in the dynamics of the epidemics, however climate and environmental factors are also suspected to play an important role. This study focuses on three Sahelian countries (Burkina Faso,Mali and Niger) which are among the most concerned in the "meningitis belt" and affected by strong dust events every year. It investigates the capability of the aeros…
Cross-hemispheric transport of central African biomass burning pollutants: implications for downwind ozone production
2010
Pollutant plumes with enhanced concentrations of trace gases and aerosols were observed over the southern coast of West Africa during August 2006 as part of the AMMA wet season field campaign. Plumes were observed both in the mid and upper troposphere. In this study we examined the origin of these pollutant plumes, and their potential to photochemically produce ozone (O<sub>3</sub>) downwind over the Atlantic Ocean. Their possible contribution to the Atlantic O<sub>3</sub> maximum is also discussed. Runs using the BOLAM mesoscale model including biomass burning carbon monoxide (CO) tracers were used to confirm an origin from central African biomass burning fires. The…
Fossil echinoid (Echinoidea, Echinodermata) diversity of the Early Cretaceous (Hauterivian) in the Paris Basin (France).
2013
11 pages; International audience; This dataset inventories occurrence records of fossil echinoid specimens collected in the Calcaires à Spatangues Formation (CSF) that crops out in the southeast of the Paris Basin (France), and is dated from the Acanthodiscus radiatus chronozone (ca. 132 Ma, early Hauterivian, Early Cretaceous). Fossil richness and abundance of the CSF has attracted the attention of palaeontologists since the middle of the nineteenth century. This dataset compiles occurrence data (referenced by locality names and geographic coordinates with decimal numbers) of fossil echinoids both collated from the literature published over a century and a half, and completed by data from …
On the radiative impact of aerosols on photolysis rates: comparison of simulations and observations in the Lampedusa island during the ChArMEx/ADRIME…
2016
The Mediterranean basin is characterized by large concentrations of aerosols from both natural and anthropogenic sources. These aerosols affect tropospheric photochemistry by modulating the photolytic rates. Three simulations of the atmospheric composition at basin scale have been performed with the CHIMERE chemistry-transport model for the period from 6 June to 15 July 2013 covered by the ADRIMED campaign, a campaign of intense measurements in the western Mediterranean basin. One simulation takes into account the radiative effect of the aerosols on photochemistry, the second one does not, and the third one is designed to quantify the model sensitivity to a bias in the ozone column. These s…
Quantum dynamics of the oxygen isotopic exchange : lifetimes of metastable states of the ozone intermediate complex
2021
This thesis aims to describe the ozone dynamics during the isotopic exchange reactions of oxygen of type xO + yO zO (xO yO zO)* xO yO + zO, where x, y and z are the atomic masses of the stable oxygen isotopes (16, 17, 18). Firstly, we analyze several methods of accurate description of the atom interactions and numerical schemes to obtain the observables for the collision. Then, in a full-quantum hyperspherical formalism, we study the actual dynamics of the reactive process O + O2 -> O3* -> O2 + O. The metastable ozone created can then either decompose into oxygen by the inverse reaction, or relax into stable ozone by exchanging energy with the environment, typically N2 or O2 molecules. Thes…
Performances comparées de données météorologiques issues de modèles et de mesures : application aux prévisions et à l'interpolation de concentrations…
2005
National audience; Performances comparées de données météorologiques issues de modèles et de mesures : application aux prévisions et à l'interpolation de concentrations d'ozone en Bourgogne
Analyse de la répartition spatiale des concentrations d'ozone en Bourgogne
2005
National audience; ABSTRACT : A series of measurements by passive tubes with diffusion were carried out in August 2000 on all the Burgundy area in order to try to better understand the spatial patterns of ozone at regional scale. As expected, the results showed difference between night and day. In addition ozone variability is associated to spatial and temporal scales. We assumed that ozone concentrations is the additive combination of two main sources: a "low frequency" signal due to external forcing and a high frequency signal from local origin. Spatial correlations were characterised by the experimental and the modelled semivariogram. Spatial correlations are strongly anisotropic. The an…