Search results for "PAPER"
showing 10 items of 2166 documents
Methyl 4-[5-(4-fluorophenyl)-4-(pyridin-4-yl)-1H-imidazol-2-ylsulfanyl]butanoate
2008
The title compound, C19H18FN3O2S, was synthesized in the course of studies on 2-alkylsufanylimidazoles as p38 mitogen-activated protein kinase inhibitors. The synthesis was achieved by nucleophilic substitution of 4-(4-fluorophenyl)-5-(pyridin-4-yl)-1,3-dihydroimidazole-2-thione with methyl 4-bromobutanoate. The five-membered heterocycle makes dihedral angles of 32.4 (2) and 18.3 (2)° with the fluorophenyl and pyridinyl rings, respectively, indicating a low degree of conjugation between these rings. Intramolecular C—H...N and intermolecular N—H...N hydrogen bonds as well as C—H...π interactions seem to be effective in stabilization of the crystal stru…
N 2,N 2,N 6,N 6-Tetrakis(2,3,4,5,6-pentafluorobenzoyl)pyridine-2,6-diamine
2011
The title compound, C33H3F20N3O4, is a highly fluorinated organic imide that was isolated as an unexpected product from the reaction of 2,6-diaminopyridine with 2,3,4,5,6-pentafluorobenzoyl chloride in a 1:2 molar ratio. The molecule is located on a twofold axis and one of its symmetry-independent 2,3,4,5,6-pentafluorobenzoyl groups is disordered over two sets of sites, the occupancy of the major component being 0.773 (3). In the major component, the dihedral angle between the perfluorophenyl groups is 63.64 (10)°, and these groups form dihedral angles of 67.14 (7) and 21.1 (2)° with the pyridine core. Short intermolecular C&#821…
(E)-7-(Pyren-1-yl)hept-6-enoic acid
2010
The title compound, C23H20O2, is a precursor of a pyrene-based supramolecular element for non-covalent attachment to a carbon nanotube. The asymmetric unit contains three independent molecules. The carboxylic acid group in each of these molecules serves as an intermolecular hydrogen-bond donor and acceptor, generating the commonly observed double O—H...O hydrogen-bond motif in an eight-membered ring. Weaker C—H...O, π–π [centroid–centroid distance = 3.968 (4) Å] and C—H...π interactions are also found in the crystal structure.
1-[2-(2,4-Dichlorophenyl)pentyl]-1H-1,2,4-triazole
2009
The title compound, C13H15Cl2N3, also known as penconazole, crystallizes as a racemate. The dihedral angle between the benzene and triazole rings is 24.96 (13)°. In the crystal structure, molecules are linked into chains running parallel to the c axis by intermolecular C—H...N hydrogen-bonding interactions.
2-(2,3,5,6-Tetramethylbenzylsulfanyl)pyridine N-oxide
2008
In the title compound, C16H19NOS, the durene ring and the oxopyridyl ring form a dihedral angle of 82.26 (7)°. The crystal structure is stabilized by intermolecular C—H...O hydrogen bonds, weak C—H...π interactions and π–π interactions [centroid–centroid distance of 3.4432 (19) Å], together with intramolecular S...O [2.657 (2) Å] short contacts.
Tetrakis{2,4-bis[(1-oxo-2-pyridyl)sulfanylmethyl]mesitylene} acetone hemisolvate 11.5-hydrate
2009
In the crystal structure of the title compound, 4C21H22N2O2S2·0.5C3H6O·11.5H2O, there are four crystallographically independent molecules (A, B, C, D) with similar geometries, 11 water molecules and a solvent acetone molecule which is disordered with a water molecule with occupancy factors of 0.5:0.5. The dihedral angles formed by the mesitylene ring with the two pyridyl rings are 82.07 (3) and 78.39 (3)° in molecule A, 86.20 (3) and 82.29 (3)° in molecule B, 81.05 (3) and 76.0 (4)° in molecule C, 86.0 (3) and 80.9 (3)° in moleule D. The two pyridyl rings form dihedral angles of 41.17 (4), 64.01 (3), 8…
Structure of mammalian plasma fetuin-B and its mechanism of selective metallopeptidase inhibition
2018
The co-crystal structure of the metallopeptidase astacin with its specific protein inhibitor fetuin-B reveals a novel mechanism of inhibition.
Producción de personas, reproducción de representaciones. Reflexiones sobre dos programas de capacitación en liderazgo
2020
The present paper addresses the question of the role Executive Education performs in the strengthening and reproduction of neoliberal ideology. It aims to critically reflect on the way selected contents and teaching activities operate jointly enabling or inhibiting certain perspectives regarding work in organizations. Two Leadership training programs are analyzed in this article, currently delivered by the two most prestigious business schools in Argentina: IAE Business School, and Torcuato Di Tella Business School. I begin with a general description of each one and proceed analyzing their educational proposals. Finally, the critical review reveals their consistency with a set of social rep…
The definition of culture in culture-based urban development strategies: antagonisms in the construction of a culture-based development discourse
2013
Implementing culture-based development strategies is a recent trend in large and small cities all over Europe. The definition of culture and the objectives of cultural strategies are highly contested in the public debate. Analysing the newspaper debates on the establishment of the Cultiva foundation in Kristiansand, Norway, this article discusses how and why the discursive debate on the definition of culture creates different discursive positions in the public debate on culture-based development. In the different discourses on what these strategies should be, there are a number of antagonisms that contribute to defining the relationships and interfaces between the different discursive posit…
SMS Messages in a Daily Finnish Newspaper : The Contect of Proverb Performances
2017
The article focuses on Finnish proverbs as a part of contemporary colloquial written language in everyday use and context. The article offers a view on what is happening with proverbs in the vernacular in Finnish everyday life. Most traditional Finnish proverbs originate from an agrarian context and still use agrarian language, even if nowadays they live in a new context with a new meaning. As empirical material this article uses a special case that demonstrates the use of proverbs in one Finnish newspaper: proverbs in SMS messages published as a letter to the editor in a newspaper. *** Avtorica se osredinja na finske pregovore kot del sodobnega pogovornega pisnega jezika v vsakdanji rabi i…