Search results for "PERTURBATION"
showing 10 items of 811 documents
Comments on `A new efficient method for calculating perturbation energies using functions which are not quadratically integrable'
1996
The recently proposed method of calculating perturbation energies using a non-normalizable wavefunction by Skala and Cizek is analysed and rigorously proved.
Why benchmark-quality computations are needed to reproduce 1-adamantyl cation NMR chemical shifts accurately.
2011
While the experimental (1)H NMR chemical shiftsof the 1-adamantyl cation can be computed within reasonably small error bounds, the usual Hartree-Fock and density functional quantum-chemical computations, as well as those based on rather elaborate second-order Møller-Plesset perturbation theory, fail to reproduce its experimental (13)C NMR chemical shifts satisfactorily. This also is true even if the NMR shielding calculations treat electron correlation adequately by the coupled-cluster singles and doubles model augmented by a perturbative correction for triple excitations (i.e., at the CCSD(T) level) with quadruple-ζ basis sets. We demonstrate that good agreement can be achieved if highly a…
Towards the Quantitative Prediction of the Phase Behavior of Polymer Solutions by Computer Simulation
2009
The phase diagram of polymer solutions (cf. e.g. alkanes dissolved in supercritical carbon dioxide) is complicated, since there are four control parameters (temperature, pressure, monomer volume fraction, chain length of the polymer) and due to the interplay of liquid-vapor transitions and fluid-fluid unmixing. As a result I very intricate phase diagram topologies can result. An attempt to develop coarse-1 grained models that can deal with this task will be described. As usual, the polymers I will be modelled as off-lattice bead-spring chains, where several chemical monomers I are integrated into one effective bond, torsional degrees of freedom being dis-I regarded. But also a coarse-graine…
QCD analysis of the tau hadronic width
1992
32 páginas, 1 figura, 4 tablas.-- CERN-TH-6070-91 ; NUHEP-TH-91-8 ; PM-91-8.
Test of chiral perturbation theory in η decays
1994
The decay of the η-meson into three pions plays an important role as a test of low-energy QCD calculations in the framework of chiral perturbation theory. Previous experiments show results that are inconclusive or even contradictory. The Crystal Barrel experiment at LEAR has determined the braching ratiosΓ(η→3π0)/Γ(η→π+π−π0)=1.47±0.09±0.15 andΓ(η→γγ)/Γ(η→π+π−π0)=1.88±0.10±0.17 using its unique features to detect charged particles as well as neutral particles. The value for the first ratio agrees nicely with the theoretical predictions and solves previous experimental uncertainties. The second value, which yields a partial width ofΓ(η→π+π−π0)=(0.24±0.03) keV, shows that the same next-to-lead…
Pion electroproduction, partially conserved axial-vector current, chiral Ward identities, and the axial form factor revisited
2003
We reinvestigate Adler's partially conserved axial-vector current relation in the presence of an external electromagnetic field within the framework of QCD coupled to external fields. We discuss pion electroproduction within a tree-level approximation to chiral perturbation theory and explicitly verify a chiral Ward identity referred to as the Adler-Gilman relation. We critically examine soft-momentum techniques and point out how inadmissable approximations may lead to results incompatible with chiral symmetry. As a result we confirm that threshold pion electroproduction is indeed a tool to obtain information on the axial form factor of the nucleon.
and the electroweak penguin contribution
2003
Abstract Our dispersive sum rule calculation of the electroweak penguin contribution to ϵ′ ϵ is reviewed. A more recent analysis based on the finite-energy sum rule approach is described. Finally, a new determination of the electroweak penguin contribution to ϵ′ ϵ is presented.
Strong CP-violation in an effective chiral lagrangian approach
1991
21 páginas, 2 figuras.-- CERN-TH-6071-91
Neutrinoless double beta decay and QCD running at low energy scales
2018
There is a common belief that the main uncertainties in the theoretical analysis of neutrinoless double beta ($0\nu\beta\beta$) decay originate from the nuclear matrix elements. Here, we uncover another previously overlooked source of potentially large uncertainties stemming from non-perturbative QCD effects. Recently perturbative QCD corrections have been calculated for all dimension 6 and 9 effective operators describing $0\nu\beta\beta$-decay and their importance for a reliable treatment of $0\nu\beta\beta$-decay has been demonstrated. However, these perturbative results are valid at energy scales above $\sim 1$ GeV, while the typical $0\nu\beta\beta$-scale is about $\sim 100$ MeV. In vi…
W+W−Production at Hadron Colliders in Next to Next to Leading Order QCD
2014
Charged gauge boson pair production at the Large Hadron Collider allows detailed probes of the fundamental structure of electroweak interactions. We present precise theoretical predictions for on-shell W+ W- production that include, for the first time, QCD effects up to next to next to leading order in perturbation theory. As compared to next to leading order, the inclusive W+ W- cross section is enhanced by 9% at 7 TeV and 12% at 14 TeV. The residual perturbative uncertainty is at the 3% level. The severe contamination of the W+ W- cross section due to top-quark resonances is discussed in detail. Comparing different definitions of top-free W+ W- production in the four and five flavor numbe…