Search results for "PHENYLENE"

showing 10 items of 457 documents

1986

The molecular order and mobility of two liquid-crystalline polyacrylates with phenyl benzoate moieties as mesogenic side groups and (CH2)m spacers (m = 2 and m = 6) were investigated by pulsed 2H NMR. The mesogenic side groups were isotopically labelled at the terminal phenylene ring. In the glassy state the orientational distribution function was characterized from the angular dependence of the 2H NMR line shape of samples macroscopically ordered in their nematic phase by the 8,4 T magnetic field of an NMR spectrometer. It was found to be Gaussian with widths of ± 18,5° and ± 10,5° for the m = 2 frozen nematic and m = 6 frozen smectic system, respectively. The phenylene rings undergo 180° …

CrystallographyNuclear magnetic resonanceChemistryLiquid crystalPhenyleneMesogenPhase (matter)Polymer chemistryRelaxation (NMR)Activation energyDielectricAmorphous solidDie Makromolekulare Chemie
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CCDC 815937: Experimental Crystal Structure Determination

2012

Related Article: S.Majumder, S.Dutta, L.M.Carrella, E.Rentschler, S.Mohanta|2011|J.Mol.Struct.|1006|216|doi:10.1016/j.molstruc.2011.09.011

Diaqua-(22'-(12-phenylenebis((nitrilo)methylylidene))bis(6-ethoxyphenolato)-NN'OO')-iron(iii) nitrate monohydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 770746: Experimental Crystal Structure Determination

2011

Related Article: E.Nauha, A.Ojala, M.Nissinen, H.Saxell|2011|CrystEngComm|13|4956|doi:10.1039/c1ce05077j

Diethyl (12-phenylenedicarbamothioyl)dicarbamate acetone solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 770750: Experimental Crystal Structure Determination

2011

Related Article: E.Nauha, A.Ojala, M.Nissinen, H.Saxell|2011|CrystEngComm|13|4956|doi:10.1039/c1ce05077j

Diethyl (12-phenylenedicarbamothioyl)dicarbamate pyridine solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 762570: Experimental Crystal Structure Determination

2010

Related Article: M.C.Munoz, G.Blay, I.Fernandez, J.R.Pedro, R.Carrasco, M.Castellano, R.Ruiz-Garcia, J.Cano|2010|CrystEngComm|12|2473|doi:10.1039/c001682a

Diethyl 22'-(12-phenylenediimino)bis(oxoacetate)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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[2,5-Bis(dipropylamino)-4-(hydroxymethyl)phenyl]methanol

2021

The centrosymmetric title compound, C22H36N2O2, was prepared in five steps from diethyl succinate. The dipropylamino groups are almost orthogonal to the central phenylenedimethanol ring [dihedral angle = 87.62 (9)°]. In the crystal, the molecules are connected by O—H...N hydrogen bonds, forming (101) layers separated by the propyl chains.

Diethyl succinatecrystal structurehydrogen bondCrystallographyChemistryHydrogen bondalcoholAlcoholCrystal structureDihedral angleRing (chemistry)Medicinal chemistryCrystalchemistry.chemical_compoundQD901-999phenylenediamineMethanolIUCrData
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CCDC 724464: Experimental Crystal Structure Determination

2010

Related Article: E.Nauha, H.Saxell, M.Nissinen, E.Kolehmainen, A.Schafer, R.Schlecker|2009|CrystEngComm|11|2536|doi:10.1039/b905511h

Dimethyl (12-phenylenedicarbamothioyl)bis(carbamate) 12-dichloroethane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 724470: Experimental Crystal Structure Determination

2010

Related Article: E.Nauha, H.Saxell, M.Nissinen, E.Kolehmainen, A.Schafer, R.Schlecker|2009|CrystEngComm|11|2536|doi:10.1039/b905511h

Dimethyl (12-phenylenedicarbamothioyl)bis(carbamate) chloroform solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 724466: Experimental Crystal Structure Determination

2010

Related Article: E.Nauha, H.Saxell, M.Nissinen, E.Kolehmainen, A.Schafer, R.Schlecker|2009|CrystEngComm|11|2536|doi:10.1039/b905511h

Dimethyl (12-phenylenedicarbamothioyl)bis(carbamate) ethanol solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Ethylene and phenylene bridged polysilsesquioxanes functionalized by amine and thiol groups as adsorbents of volatile organic compounds

2007

Abstract Ethylene and phenylene bridged polysilsesquioxane xerogels having amine and thiol groups attached to the surface have been obtained by the sol–gel method from 1,2-bis(triethoxysilyl)ethane or 1,4-bis(triethoxysilyl)benzene and functionalized silanes in the presence of an ammonium fluoride catalyst in an ethanol solution. The synthesized samples have a porous structure (700–850 m2/g) and a high content of functional groups (1.4–1.9 mmol/g). The obtained porous bridged polysilsesquioxanes exhibit a considerable affinity for adsorbing several organic compounds (n-hexane, n-heptane, benzene, cyclohexane, acetonitrile and triethylamine) from the gas phase. The sample with an ethylene br…

EthyleneMaterials scienceCyclohexaneGeneral Physics and AstronomyAmmonium fluorideSurfaces and InterfacesGeneral ChemistryCondensed Matter PhysicsSurfaces Coatings and Filmschemistry.chemical_compoundchemistryPhenylenePolymer chemistryOrganic chemistryAmine gas treatingHybrid materialTriethylamineOrganosiliconApplied Surface Science
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