Search results for "PHOTOEMISSION"
showing 10 items of 174 documents
Properties of the quaternary half-metal-type Heusler alloyCo2Mn1−xFexSi
2006
This paper reports on the bulk properties of the quaternary Heusler alloy Co2Mn1�xFexSi with the Fe concentration x =0,1/2,1. All samples, which were prepared by arc melting, exhibit L21 long-range order over the complete range of Fe concentration. The structural and magnetic properties of the Co2Mn1�xFexSi Heusler alloys were investigated by means of x-ray diffraction, high- and low-temperature magnetometry, Mossbauer spectroscopy, and differential scanning calorimetry. The electronic structure was explored by means of highenergy photoemission spectroscopy at about 8 keV photon energy. This ensures true bulk sensitivity of the measurements. The magnetization of the Fe-doped Heusler alloys …
Spin structure and spin Hall magnetoresistance of epitaxial thin films of the insulating non-collinear antiferromagnet SmFeO3
2019
We report a combined study of imaging the antiferromagnetic (AFM) spin structure and measuring the spin Hall magnetoresistance (SMR) in epitaxial thin films of the insulating non-collinear antiferromagnet SmFeO$_3$. X-ray magnetic linear dichroism photoemission electron microscopy measurements reveal that the AFM spins of the SmFeO$_3$(110) align in the plane of the film. Angularly dependent magnetoresistance measurements show that SmFeO$_3$/Ta bilayers exhibit a positive SMR, in contrast to the negative SMR expected in previously studied collinear AFMs. The SMR amplitude increases linearly with increasing external magnetic field at higher magnetic field, suggesting that field-induced canti…
Interface properties of magnetic tunnel junctionLa0.7Sr0.3MnO3/SrTiO3superlattices studied by standing-wave excited photoemission spectroscopy
2010
The chemical and electronic-structure profiles of magnetic tunnel junction (MTJ) La0.7Sr0.3MnO3/SrTiO3 (LSMO/STO) superlattices have been quantitatively determined via soft and hard x-ray standing-wave excited photoemission, x-ray absorption and x-ray reflectivity, in conjunction with x-ray optical and core-hole multiplet theoretical modeling. Epitaxial superlattice samples consisting of 48 and 120 bilayers of LSMO and STO, each nominally four unit cells thick, and still exhibiting LSMO ferromagnetism, were studied. By varying the incidence angle around the superlattice Bragg condition, the standing wave was moved vertically through the interfaces. By comparing experiment to x-ray optical c…
Soft X-ray photoelectron microscopy used for the characterization of diamond, a-C and CN , thin films
2002
Abstract This article gives an overview about the application of X-ray photoemission electron microscopy (X-PEEM) used for the analysis of carbon thin films. We present the results of an X-ray absorption near edge structure (XANES) study of CVD diamond, a-C and CNx films on Si (100) as well as a defect analysis of a hard disc scratch test. The sp2/sp3 ratio of the carbon films was determined and mapped in the electron micrographs, which show localized defects in the surface.
Momentum Distribution of Electrons Emitted from Resonantly Excited Individual Gold Nanorods.
2017
Electron emission by femtosecond laser pulses from individual Au nanorods is studied with a time-of-flight momentum resolving photoemission electron microscope (ToF k-PEEM). The Au nanorods adhere to a transparent indium–tin oxide substrate, allowing for illumination from the rear side at normal incidence. Localized plasmon polaritons are resonantly excited at 800 nm with 100 fs long pulses. The momentum distribution of emitted electrons reveals two distinct emission mechanisms: a coherent multiphoton photoemission process from the optically heated electron gas leads to an isotropic emission distribution. In contrast, an additional emission process resulting from the optical field enhanceme…
<title>Miniaturized objective lens for a photoelectron emission microscope</title>
2000
Photoemission electron microscopy (PEEM) has turned out to be one of the most promising methods for surface analysis in the recent years. It is a full field imaging technique based on the emission of secondary electrons by far ultraviolet light or X-rays. The emission intensity of secondary electrons is critically dependent upon the acceptance angle of the incident radiation. However, the size of the microscope restricts this angle substantially. Miniaturizing the objective lens of the microscope reduces the restriction of the acceptance angle and improves the performance of the PEEM considerably. We report on the fabrication of a miniaturized objective lens containing the extraction electr…
Cathodic electrodeposition of ZnCoO thin films
2008
We report on the characterization of ternary Zn1–xCoxO alloy crystalline films grown by electrodeposition onto FTO-coated substrates. The Zn1–xCoxO films have hexagonal wurtzite structure as shown by X-ray diffraction measurements. The Co incorporation into the ZnO lattice is confirmed by the presence of absorption peaks assigned to Co in trigonal crystal field. X-ray photoemission spectroscopy indicates that as-grown films have a considerable concentration of not-fully oxidized metallic Co in the surface that correlates with the O concentration in the surface. Finally, Raman measurements of as-grown films indicate that they are polycrystalline with grains of nanometric size showing short-r…
X-ray photoemission studies of the electronic structure of single-crystalline CdO(100)
2007
The electronic structure of single-crystalline CdO is investigated using X-ray photoemission spectroscopy. The surface is prepared by in situ Ar+ ion bombardment and annealing (IBA). The core level spectra before and after the IBA are presented, and reveal a dramatic reduction in the surface contamination. The semi-core Cd 4d level and valence band region following the IBA are also shown. The surface Fermi level is pinned 1.3 +/- 0.10 eV above the valence band maximum. (c) 2007 Elsevier Ltd. All rights reserved.
Refractory metal reactivity towards oxide surface : W/TiO2(1 1 0) case.
2006
International audience; Reactivity of deposited tungsten towards TiO2(1 1 0) surface was studied using synchrotron radiation photoemission spectroscopy (both core levels, valence band and resonant photoemission) on Materials Science Beamline at ELETTRA. W depositions carried out at room temperature on TiO2(1 1 0) surface give rise to an interfacial reaction which leads to a metastable situation due to kinetic limitations. Annealing induces chemical changes which are function of the initial coverage; for fractional coverage, annealing induces completion of oxidation of deposit whereas reduction to metallic tungsten occurs for highest coverage. These results demonstrate that interaction of W …
Inhibition of Cor-Ten steel corrosion by “green” extracts of Brassica campestris
2018
Abstract Extract of Brassica campestris was tested as potential corrosion inhibitor for Cor-Ten steel in NaCl and acidic solutions, simulating a marine and an urban-industrial environment, respectively. Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) were performed both in absence and in presence of the extract at room temperature. The surface chemical analysis was investigated by X-ray Photoemission Spectroscopy (XPS), before and after corrosion. Electrochemical results demonstrated that a very small concentration of Brassica campestris extracts can inhibit Cor-Ten corrosion in NaCl solution (inhibition efficiency of 80–84%) better than in acidic solutions. Su…