Search results for "PLASMONS"
showing 9 items of 29 documents
Direct interpretation of near-field optical images
2001
International audience; The interpretation of the detection process in near-field optical microscopy is reviewed on the basis of a discussion about the possibility of establishing direct comparisons between experimental images and the solutions of Maxwell equations or the electromagnetic local density of states. On the basis of simple physical arguments, it is expected that the solutions of Maxwell equations should agree with images obtained by collecting mode near-field microscopes, while the electromagnetic local density of states should be considered to provide a practical interpretation of illumination mode near-field microscopes. We review collecting mode near-field microscope images w…
Study of the dynamics of biomolecules by high speed atomic force microscopy and surface enhanced Raman spectroscopy
2015
This thesis focuses on the coupling of High–Speed Atomic Force Microscopy (HS-AFM) and Surface Enhanced Raman Spectroscopy (SERS) for biomolecule analysis. We have designed a fabrication protocol to manufacture “SERS-active” substrates. The efficacy of gold, silver and gold-silver bimetallic crystalline nanoparticle substrates were evaluated. We have investigated the impact of optical and morphological features of the substrates on Raman signal intensity by analyzing well-known samples such as bipyridine ethylene and methylene blue molecules. We took an interest in three distinct biological problematics with HS-AFM and SERS analyses. First, we have detected the chemical signature of cytochr…
Ultrathin high-index metasurfaces for shaping focused beams
2015
The volume size of a converging wave, which plays a relevant role in image resolution, is governed by the wavelength of the radiation and the numerical aperture (NA) of the wavefront. We designed an ultrathin (λ/8 width) curved metasurface that is able to transform a focused field into a high-NA optical architecture, thus boosting the transverse and (mainly) on-axis resolution. The elements of the metasurface are metal-insulator subwavelength gratings exhibiting extreme anisotropy with ultrahigh index of refraction for TM polarization. Our results can be applied to nanolithography and optical microscopy. Spanish Ministry of Economy and Competitiveness (MEC) (TEC2013-50416-EXP).
Applications of light-matter interaction in nanosciences
2009
In this thesis, light matter interaction in nanoscale has been studied from various aspects. The interaction between surface plasmon polaritons (SPPs) and optically active organic molecules (Rhodamine 6G, Sulforhodamine 101 and Coumarine 30) and semiconducting nanocrystals (quantum dots) is studied in the weak coupling regime. In particular, a photon-SPP-photon conversion with spatially separated inand outcoupling was demonstrated by using molecules. Also, a frequency downconversion for propagating SPPs was presented by utilization of vibrational relaxation of organic molecules. A strong coupling regime was reached for Rhodamine 6G (R6G) and SPP despite the broad absorption linewidth of R6G…
Synthesis of Yb nanoparticles by laser ablation of ytterbium target in sodium bis(2-ethylhexyl)sulfosuccinate reverse micellar solution
2010
Abstract Surfactant-coated ytterbium nanoparticles were produced by Nd:YAG laser ablation of a Yb bulk target immersed in sodium bis(2-ethylhexyl)sulfosuccinate (AOT)/ n -heptane micellar solution. In our experimental conditions, as highlighted by IR spectroscopy, AOT molecules are not decomposed by the intense laser pulses but play a pivotal role in the stabilisation of Yb nanoparticles. The formation of Yb nanoparticles in the liquid phase was monitored by UV–Vis spectroscopy whereas the Yb/AOT composites obtained by evaporation of the organic solvent were characterised by XPS and TEM. Data analysis consistently shows the presence of surfactant-coated, nearly spherical and non-interacting…
Analyse locale des sensibilités des lectures angulaires, spectroscopiques et ellipsométriques de la Résonance des Plasmons de Surface en vue de la mi…
2006
The fluorescence labelling, used by the fluorescence biochips, is known to change the charge distribution of the labelled molecules and then modify their biological activity. Among label free biosensors, we choose an optical detection, such as spectroscopic ellipsometry and/or surface plasmon resonance (SPR) of the biolayers.These optical techniques are based on the measurement of both thickness and optical index of the adsorbed biolayer. An AFM statistical measurement of the thickness of functionalized lithographed microstructures has been performed in order to determine the thickness of the biolayers.We have shown that the spectroscopic reading of the SPR phase shift is 100 times more sen…
Spatially resolved transmission through metal films by plasmon excitation
2007
International audience
Analysis of the Bloch mode spectra of surface polaritonic crystals in the weak and strong coupling regimes: grating-enhanced transmission at oblique …
2004
The Bloch mode spectrum of surface plasmon polaritons (SPPs) on a finite thickness metal film has been analyzed in the regimes of weak and strong coupling between SPP modes on the opposite film interfaces. The SPP mode dispersion and associated field distributions have been studied. The results have been applied to the description of the light transmission through thick and thin periodically structured metal films at oblique incidence. In contrast to normal incidence, all SPP Bloch modes on a grating structure participate in the resonant photon tunnelling leading to the transmission enhancement. However, at the angle of incidence corresponding to the crossing of different symmetry film SPP …
Plasmonic Stripes in Aqueous Environment Co-Integrated With Si3N4 Photonics
2018
We demonstrate the design, fabrication, and the experimental characterization of gold-based plasmonic stripes butt-coupled with low-pressure-chemical-vapor-deposition (LPCVD)-based Si3N4 waveguides for the excitation of surface-plasmon-polariton (SPP) modes in aqueous environment. Plasmonic gold stripes, in aqueous environment, with cross-sectional dimensions of 100 nm × 7 μm were interfaced with 360 nm × 800 nm Si3N4 waveguides cladded with low-temperature-oxide, exploiting linear photonic tapers with appropriate vertical (VO) and longitudinal (LO) offsets between the plasmonic and photonic waveguide facets. An interface insertion loss of 2.3 ± 0.3 dB and a plas…